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  • Chemical Engineering  (32)
  • Engineering  (15)
  • Wiley-Blackwell  (47)
  • Institute of Physics
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  • 1980-1984  (17)
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  • Wiley-Blackwell  (47)
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 37 (1991), S. 1789-1800 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The finite element method was used to model microwave thawing of pure-water and 0.1-M NaCl cylinders. The electromagnetic field was described by Maxwell's equations with temperature-dependent dielectric properties, while the heat equation, coupled with the Stefan and Robin conditions, was used to describe the thawing process. An additional equation for the frozen volume fraction was used, when necessary, to account for the presence of a mushy region. Two microwave frequencies, 915 MHz and 2,450 MHz, were examined and the microwave radiation was assumed to be radially isotropic and normal to the surface of the cylinder. Results show that a two-phase mushy region may exist, and an additional thawing front may appear at the center of the cylinder. Salt cylinders have a higher dielectric loss than pure-water cylinders and therefore thaw more quickly. Internal resonance occurs when the wavelength of the radiation is a harmonic of the cylinder radius. Resonance increases power deposition and expedites the thawing process. The onset of resonance alters thawing times and complicates the development of heuristic rules for microwave thawing.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1433-1439 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is generally believed that oil samples heat faster in a microwave oven than do water samples of the same mass. For sufficiently large and thich samples this conventional wisdom is indeed correct, but this trend can be far from true in smaller samples. In a commercially-made home microwave oven, we observed that with decreasing sample size the heating rate of a water sample increases much faster than that of an oil sample. At 50 g the heating rate of a water sample is several times greater than that of an oil sample. Additionally, in studies of cylindrical samples in a customized oven having a unidirectional microwave source, the heating rate of water samples smaller than 2.4 cm in radius is greater than that of oil samples and is a strongly oscillatory increasing function of decreasing sample radius. Combining Maxwell's theory of microwave penetration and the heat conduction equation, we show that this previously unreported oscillatory heating behavior results from the added power absorbed by samples due to resonant absorption of microwaves. The added power arises from standing waves produced by internally reflected microwaves. This effect is small for oil because only 3% of the microwave power is reflected at an oil-air interface. On the other hand, 64% is reflected at a water-air interface, which causes strong resonant heating. Our findings might prove to be useful for future consumer food product development or oven design.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 37 (1991), S. 313-322 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Transient temperature profiles in multilayer slabs are predicted, by simultaneously solving Maxwell's equations with the heat conduction equation, using Galerkin finite elements. It is assumed that the medium is homogeneous and has temperature-dependent dielectric and thermal properties. The method is illustrated with applications involving the heating of food and polymers with microwaves. The temperature dependence of dielectric properties affects the heating appreciably, as is shown by comparison with a constant property model.
    Additional Material: 7 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 1577-1592 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Transient temperature profiles for long rods of lossy dielectric materials with thermally-dependent dielectric properties exposed to uniform plane waves are obtained. Maxwell's equation and the heat equation are simultaneously solved using the finite element method to predict the power absorbed and the resulting temperature rise in samples of square and circular cross-section. Following the method introduced recently, we derive an exact radiation boundary condition which is independent of the rod cross-section. For a cylindrical sample, the boundary condition is imposed on the cylinder itself. For a square rod, the boundary condition is imposed on a cylinder containing the rod. The temperature dependence of dielectric properties and sample dimensions appreciably influence heating patterns. For square samples, the edges focus radiation, causing preferential heating at the edges. This effect is pronounced for larger samples. In addition, the incident wave polarization influences the heating of the rod. For waves where the electric field is polarized along the long axis of the sample (TMz polarization) the power absorbed is higher than when the electric field is perpendicular to the axis (TEz polarization). A case involving runaway heating is also investigated.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1268-1272 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 15 (1980), S. 867-888 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Univariate minimization is considered for constrained optimization with the Kavlie-Moe extended interior penalty. An algorithm is derived using a linear-plus-hyperbolic fit suggested by R. L. Fox for interior penalties. A linear extension to the linear-plus-hyperbolic permits rapid convergence with extended interior alties. However, constraint deletion and approximation of remaining constraints before each minimization also characterize the environment. These and other complexities impede accurate fitting of larger intervals. Thus, following Murray, a mixed strategy is adopted with function comparison reductions of interval size to supplement curve fitting.Analysis shows how quadratic and cubic fit searches break down under certain limiting conditions of interior, extended and exterior penalties. A quadratic-extended linear curve derived for exterior penalties and the linear-plus-hyperbolic similarly fail on extended interior penalties. Examples of constrained optimization with extended interior penalties were run on the Stanford IBM 370/168 computer. A stiffened two-panel box provides eight optimization variables with many constraints on demensions and against failure. The extended linear-plus-hyperbolic surpasses cubic and linear-plus hyperbolic fitting, especially when the Fiacco-McCormick multiplier for the penalty becomes small. The value of feedback from curve fitting to decide function comparison use is also illustrated.
    Additional Material: 5 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 37 (1991), S. 1905-1905 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 1135-1145 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In this work, the separation of carbon dioxide from methane by reactive liquid membranes consisting of the secondary amines, diethanolamine, and diisopropanolamine in polyethylene glycol with an average molecular weight of 400 was studied. A mathematical model was developed to describe the transport process. This model employs the zwitterion mechanism for the CO2 amine reaction kinetics. Membrane flux experiments utilizing a flat plate device were carried out to verify the model predictions. It was found that large permeabilities and separations were achieved for low CO2 feed concentrations. The results also show that DEA based solutions give better separation than DIPA based solutions.
    Additional Material: 12 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 1335-1341 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Equations introduced here identify measurement biases and process leaks, when gross errors exist in measured process variables and the variance-covariance matrix of the measurements, Σ, is unknown. Σ is estimated by the sample variance, S, using process data.For an unknown Σ, the global test statistic is the well-known Hotelling T2 statistic. Its power function has a noncentral F-distribution. For component tests used for specific identification of measurement biases and nodal leaks, two tests are presented with Σ unknown. The first test is independent of the number of component tests, k, and is given by a statistic with an F-distribution. The second test depends on k and has a student t-distribution. The power functions for both component tests are provided. Process examples and a Monte Carlo simulation study presented demonstrate the use and performance of these statistical equations in identifying biases and process leaks.
    Additional Material: 1 Ill.
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  • 10
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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