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  • Chemistry
  • GEOPHYSICS
  • Geophysics
  • METEOROLOGY AND CLIMATOLOGY
  • 2010-2014  (5)
  • 1960-1964  (7)
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 2 (1962), S. 101-102 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 42 (1960), S. 578-579 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 47 (1960), S. 498-498 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 57 (1962), S. 993-1007 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A degradative etching technique has been employed with polyethylene terephthalate films to demonstrate the existence of several different structures, the size of which vary from hundreds of microns to hundreds of Angstroms. The micron-sized structures are a function of the processing and orientation of the film and occur in regular geometric patterns. Thus, parallel stretch-direction lines are etched into one-way stretched film, the number of lines being dependent upon film history. Etched, two-way stretched films reveal a lamellate composition, each layer possessing a brick wall-like structure. This general structural pattern has been found in other types of film by similar methods. Examination of the etched areas by electron microscopy demonstrates that the micron-sized blocks are composed of spheres, 700 A. in diameter, which are aligned over moderate distances.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Letters 2 (1964), S. 163-168 
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 1 (1963), S. 655-670 
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Allene has been polymerized to a high molecular weight by several transition metal salts reduced by aluminum triisobutyl. The polymer contained three types of unsaturation: vinylidene, vinyl, and cis; no trans unsaturation was found. A hypothesized mechanism accounted for these facts by two competitive rates: reaction of a linear intermediate with monomer to form again the linear intermediate plus one vinylidene unit, and isomerization of the linear intermediate to a cyclic intermediate which ultimately yielded one vinylidene and one vinyl or cis unit after reaction with monomer. Thus, the ratio of the two rates was controlled by the concentration of allene. The suggested mechanism proved to predict accurately the effect of the conditions of polymerization upon the structures of the resulting polymers. The nature of the transition metal also proved of importance in determining the path of polymerization as did temperature, solvent, degree of agitation, and copolymerization. Polyallene was found to exist in three crystalline forms as well as an amorphous form.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Publication Date: 2019-05-21
    Description: Thermal conductivities of water vapor, deuterium oxide vapor and equimolar mixture of water and deuterium oxide
    Keywords: GEOPHYSICS
    Type: NASA-RP-176
    Format: application/pdf
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  • 8
    Publication Date: 2019-07-13
    Description: Six flux transfer events (FTEs) were encountered during MESSENGER's first two flybys of Mercury (MI and M2). For MI the interplanetary magnetic field (IMF) was predominantly northward and four FTEs with durations of 1 to 6 s were observed in the magnetosheath following southward 1M F turnings. The IMF was steadily southward during M2, and an FTE 4 s in duration was observed just inside the dawn magnetopause followed approx.32 s later by a 7-s FTE in the magnetosheath. Flux rope models were fit to the magnetic field data to detem11ne PTE dimensions and flux content The largest FTE observed by MESSENGER had a diameter of approx. 1 R(sub M) (where R(sub M) is Mercury's radius), and its open magnetic field increased the fraction of the surface exposed to the solar wind by 10 - 20 percent and contributed up to approx.30 kV to the cross-magnetospheric electric potential.
    Keywords: Geophysics
    Type: GSFC.JA.4591.2011 , Geophysical Research Letters; 37
    Format: text
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  • 9
    Publication Date: 2019-07-12
    Description: Convection plays an important role in the transport of heat, moisture and trace gases. In this study, we simulated CO2 concentrations with an atmospheric general circulation model (GCM). Three different convective transport algorithms were used. One is a modified Arakawa-Shubert scheme that was native to the GCM; two others used in two off-line chemical transport models (CTMs) were added to the GCM here for comparison purposes. Advanced CO2 surfaced fluxes were used for the simulations. The results were compared to a large quantity of CO2 observation data. We find that the simulation results are sensitive to the convective transport algorithms. Overall, the three simulations are quite realistic and similar to each other in the remote marine regions, but are significantly different in some land regions with strong fluxes such as Amazon and Siberia during the convection seasons. Large biases against CO2 measurements are found in these regions in the control run, which uses the original GCM. The simulation with the simple diffusive algorithm is better. The difference of the two simulations is related to the very different convective transport speed.
    Keywords: Geophysics
    Type: GSFC-E-DAA-TN13279
    Format: application/pdf
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  • 10
    Publication Date: 2019-07-13
    Description: The El Nino Southern Oscillation is the dominant year-to-year mode of global climate variability. El Nino effects on terrestrial carbon cycling are mediated by associated climate anomalies, primarily drought, influencing fire emissions and biotic net ecosystem exchange (NEE). Here we evaluate whether El Nino produces a consistent response from the global carbon cycle. We apply a novel bottom-up approach to estimating global NEE anomalies based on FLUXNET data using land cover maps and weather reanalysis. We analyze 13 years (1997-2009) of globally gridded observational NEE anomalies derived from eddy covariance flux data, remotely-sensed fire emissions at the monthly time step, and NEE estimated from an atmospheric transport inversion. We evaluate the overall consistency of biospheric response to El Nino and, more generally, the link between global CO2 flux anomalies and El Nino-induced drought. Our findings, which are robust relative to uncertainty in both methods and time-lags in response, indicate that each event has a different spatial signature with only limited spatial coherence in Amazonia, Australia and southern Africa. For most regions, the sign of response changed across El Nino events. Biotic NEE anomalies, across 5 El Nino events, ranged from -1.34 to +0.98 Pg Cyr(exp -1, whereas fire emissions anomalies were generally smaller in magnitude (ranging from -0.49 to +0.53 Pg C yr(exp -1). Overall drought does not appear to impose consistent terrestrial CO2 flux anomalies during El Ninos, finding large variation in globally integrated responses from 11.15 to +0.49 Pg Cyr(exp -1). Despite the significant correlation between the CO2 flux and El Nino indices, we find that El Nino events have, when globally integrated, both enhanced and weakened terrestrial sink strength, with no consistent response across events
    Keywords: Geophysics
    Type: GSFC.JA.6430.2012 , Biogeosciences; 8; 2493-2506
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