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  • Electronic structure and strongly correlated systems  (5)
  • Chemistry  (4)
  • Computer Systems  (4)
  • Computer Operations and Hardware
  • 2010-2014  (10)
  • 1965-1969  (4)
  • 1
    Electronic Resource
    Electronic Resource
    Ultrasonic degradation of macromolecules in solution. Study of degradation kinetics by estimation of free-radical scavenger DPPH and solution viscosity measurementsProd. No. 1357 (1966)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 10 (1966), S. 1089-1098 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics of degradation of butyl rubber in two solvents, cyclohexane and toluene, was studied by two independent techniques: viscosity measurements and free-radical estimation as a function of DPPH consumed. The general shape of the rate curves in the two cases is similar, but not identical. The rate given by estimation of DPPH is faster than that obtained from solution viscosity data. This has been attributed to the inherent limitations of the two methods for the quantitative determination of the number of breaks occurring in the polymer molecules. The rate is also reduced as the viscosity of the solution medium is increased, which may be correlated with the reduction of the cavitation effect responsible for degradation. The degradation rates in two solvent media initially having the same viscosity were unequal. This may be due to different solvent-solute characteristics, which means that the viscosity and cavitation change to different extents in the two cases throughout the course of degradation. The limiting degree of Polymerization (DP)∞ obtained after prolonged irradiation has been found to be dependent on parameters such as intensity of irradiation, solution viscosity, and initial DP of the molecules.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1966.070100801
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    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Rapid analysis of some coinage, jewellery, aluminium bronze and ternary alloys by the ring oven technique (1965)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 28 (1965), S. 137-140 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Schemes have been worked out for the quantitative separation and subsequent determination of the constituents in a number of alloys containing Au—Cu, Cu—Al, Fe—Au and Fe—Cu—Al by the ring oven technique. Gold is migrated to the ring zone by extraction with n-butanol at pH = 1.5 and iron or copper with acetylacetone. Aluminium is moved to the ring zone by acidified ethanol.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19650280306
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Polymerization of N-vinylearbazole with vanadium compounds. Part I. Polymerization with vanadium pentoxide and metal vanadates (1969)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 124 (1969), S. 263-273 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: In Gegenwart von Vanadiumpentoxid als heterogenern Katalysator Wurde N-Vinylcarbazol (NVC) in Substanz polymerisiert. Die Polymerisationsgeschwindigkeit hängt vom Verhältnis des Katalysators zum Monomeren ab. Es wurde ein kationischer Reaktionsmechanismus vorgeschlagen, und es wurde versucht, die Rolle der V2O5-Oberfläche bei der Polymerisation aufzuklären. Es wird vermutet, daß die π-Säureeigenschaft des V5⊕-Ions bei der Initiierung der Polymerisation miteinbezogen werden muß.Die Wirkung einer Anzahl von Zusätzen auf die Polymerisationsgeschwindigkeit wurde untersucht; das Ergebnis bekräftigt die Annahme eines kationischen Verlaufs.Es wurde auch die katalytische Wirksamkeit einer Anzahl von Metallvanadaten bei der Polymerisation von NVC untersucht. Es ergab sich eine hinreichend gute Bezichung zwischen der katalytischen Wirksamkeit und dem elektronegativen Charakter des metallischen Bestandteils.
    Notes: Bulk polymerization of N-Vinylcarbazole (NVC) has been carried out using vanadium pentoxide as the contact catalyst. The rate of polymerizatlon has been found to depend upon catalyst to monomer ratio. A cationic mechanism has been suggested and the role of V2O5 surface in the polymerization has been tentatively analyzed. The π-acid characteristies of V5⊕ ion is believed to be involved in initiating the polymerization. The effect of a number of additives on the polymerization rate has been studied, which endorses the cationic mechanism. The catalytic efficiency of a number of metal vanadates for the polymerization of NVC has also been studied. A fairly good correlation between the activity and electronegativity of the metallic moiety has been established.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1969.021240127
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Interaction of polylysine with phosvitin and nucleic acids (1969)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 124 (1969), S. 113-117 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die DNS-abhängige RNS-Synthese wird durch basische Proteine, wie Histone oder Polylysin, gehmmt: es wurde gefunden, daß dieser Hemmungseffekt durch Phosvitin, ein phosphoprotein, aufgehoben wird. Turbidimetrische Untersuchungen ergaben, daß Polylysin mit DNS iind RNS in stöchiometrischem Verhältnis reagiert.Es wird angenommen, daß diese Reaktion mit DNS die Ursache des Hemmungseffektes ist. Noch wirksamer als DNS reagiert Phosvitin mit Polylysin. Phosvitin kann in viel geringerer als der stöchiometrischen Menge mit DNS um Polylysin konkurrieren, also DNS freisetzen und als Matrize für die RNS-Synthese verfügbar machen. Phosphoserin ist, im Gegensatz zu Phosvitin, unwirksam bei der Aufhebung des Hemmungseffektes von Polylysin.
    Notes: DNA dependent RNA asynthesis in inhibited by basic proteins like histones or polylysine This inhibitory effect is found to be suppressed by phosvitin, which is a phosphoprotein. Turbidometric studies indicate that polylysine interacts with DNA and RNA stoichiometrically. This interaction with DNA has been thought to be the cause of this inhibitory effect. Phovitin also interacts with polylysine more effectively than DNA. Phosvitin in quantities much less than the stoichionietric amount can compete with DNA for the polylysine and can thus make DNA free and available as template for the RNA synthesis. Phosphoserine, unlike pbosvitin, is ineffective in suppressing the inhibitory effect of polylysine.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1969.021240112
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    Paper (German National Licenses)
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  • 5
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    Surface and bulk electronic structure of the strongly correlated system SmB_{6} and implications for a topological Kondo insulator (2013)
    American Physical Society (APS)
    Details
    Publication Date: 2013-09-11
    Description: Author(s): N. Xu, X. Shi, P. K. Biswas, C. E. Matt, R. S. Dhaka, Y. Huang, N. C. Plumb, M. Radović, J. H. Dil, E. Pomjakushina, K. Conder, A. Amato, Z. Salman, D. McK. Paul, J. Mesot, H. Ding, and M. Shi Recent theoretical calculations and experimental results suggest that the strongly correlated material SmB 6 may be a realization of a topological Kondo insulator. We have performed an angle-resolved photoemission spectroscopy study on SmB 6 in order to elucidate elements of the electronic structure r... [Phys. Rev. B 88, 121102] Published Tue Sep 10, 2013
    Keywords: Electronic structure and strongly correlated systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
    Published by American Physical Society (APS)
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  • 6
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    SU(2)-invariant spin liquids on the triangular lattice with spinful Majorana excitations (2011)
    American Physical Society (APS)
    Details
    Publication Date: 2011-06-29
    Description: Author(s): Rudro R. Biswas, Liang Fu, Chris R. Laumann, and Subir Sachdev We describe a new class of spin liquids with global SU(2) spin-rotation symmetry in spin-1/2 systems on the triangular lattice, which have real Majorana fermion excitations carrying spin S =1 . The simplest translationally invariant mean-field state on the triangular lattice breaks time-reversal symme... [Phys. Rev. B 83, 245131] Published Tue Jun 28, 2011
    Keywords: Electronic structure and strongly correlated systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
    Published by American Physical Society (APS)
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  • 7
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    Valence-band study of Sm0.1Ca0.9−xSrxMnO3 using high-resolution ultraviolet photoelectron spectroscopy (2014)
    American Physical Society (APS)
    Details
    Publication Date: 2014-06-25
    Description: Author(s): M. K. Dalai, B. R. Sekhar, D. Biswas, S. Thakur, T.-C. Chiang, D. Samal, C. Martin, and K. Maiti We have studied the concentration-dependent near-Fermi-level valence-band electronic structure of Sm0.1Ca0.9−xSrxMnO3 (x=0, 0.1, 0.3, and 0.6) using high-resolution ultraviolet photoelectron spectroscopy (HRUPS) across the metal insulator transition. At low temperatures (50 and 100 K), a transformat... [Phys. Rev. B 89, 245131] Published Tue Jun 24, 2014
    Keywords: Electronic structure and strongly correlated systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
    Published by American Physical Society (APS)
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  • 8
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    Exotic Kondo crossover in a wide temperature region in the topological Kondo insulator SmB6 revealed by high-resolution ARPES (2014)
    American Physical Society (APS)
    Details
    Publication Date: 2014-08-29
    Description: Author(s): N. Xu, C. E. Matt, E. Pomjakushina, X. Shi, R. S. Dhaka, N. C. Plumb, M. Radović, P. K. Biswas, D. Evtushinsky, V. Zabolotnyy, J. H. Dil, K. Conder, J. Mesot, H. Ding, and M. Shi Temperature dependence of the electronic structure of SmB6 is studied by high-resolution angle-resolved photoemission spectroscopy (ARPES) down to 1 K. We demonstrate that there is no essential difference for the dispersions of the surface states below and above the resistivity saturating anomaly (∼... [Phys. Rev. B 90, 085148] Published Thu Aug 28, 2014
    Keywords: Electronic structure and strongly correlated systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
    Published by American Physical Society (APS)
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  • 9
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    Low-temperature magnetic fluctuations in the Kondo insulator SmB6 (2014)
    American Physical Society (APS)
    Details
    Publication Date: 2014-04-15
    Description: Author(s): P. K. Biswas, Z. Salman, T. Neupert, E. Morenzoni, E. Pomjakushina, F. von Rohr, K. Conder, G. Balakrishnan, M. Ciomaga Hatnean, M. R. Lees, D. McK. Paul, A. Schilling, C. Baines, H. Luetkens, R. Khasanov, and A. Amato We present the results of a systematic investigation of the magnetic properties of the three-dimensional Kondo topological insulator SmB6 using magnetization and muon-spin relaxation/rotation (μSR) measurements. The μSR measurements exhibit magnetic field fluctuations in SmB6 below ∼15 K due to elec... [Phys. Rev. B 89, 161107] Published Mon Apr 14, 2014
    Keywords: Electronic structure and strongly correlated systems
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
    Published by American Physical Society (APS)
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  • 10
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    I/O Performance Characterization of Lustre and NASA Applications on Pleiades (2012)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: In this paper we study the performance of the Lustre file system using five scientific and engineering applications representative of NASA workload on large-scale supercomputing systems such as NASA s Pleiades. In order to facilitate the collection of Lustre performance metrics, we have developed a software tool that exports a wide variety of client and server-side metrics using SGI's Performance Co-Pilot (PCP), and generates a human readable report on key metrics at the end of a batch job. These performance metrics are (a) amount of data read and written, (b) number of files opened and closed, and (c) remote procedure call (RPC) size distribution (4 KB to 1024 KB, in powers of 2) for I/O operations. RPC size distribution measures the efficiency of the Lustre client and can pinpoint problems such as small write sizes, disk fragmentation, etc. These extracted statistics are useful in determining the I/O pattern of the application and can assist in identifying possible improvements for users applications. Information on the number of file operations enables a scientist to optimize the I/O performance of their applications. Amount of I/O data helps users choose the optimal stripe size and stripe count to enhance I/O performance. In this paper, we demonstrate the usefulness of this tool on Pleiades for five production quality NASA scientific and engineering applications. We compare the latency of read and write operations under Lustre to that with NFS by tracing system calls and signals. We also investigate the read and write policies and study the effect of page cache size on I/O operations. We examine the performance impact of Lustre stripe size and stripe count along with performance evaluation of file per process and single shared file accessed by all the processes for NASA workload using parameterized IOR benchmark.
    Keywords: Computer Systems
    Type: ARC-E-DAA-TN6025 , HiPC 2012; Dec 18, 2012 - Dec 21, 2012; Pune; India
    Format: application/pdf
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    NASA TECHNICAL REPORTS
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