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  • Articles  (11)
  • Wiley-Blackwell  (6)
  • Mineralogical Society of Great Britain and Ireland  (3)
  • Schweizerbart  (2)
  • 2010-2014  (5)
  • 1980-1984  (3)
  • 1970-1974  (1)
  • 1960-1964  (2)
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  • Articles  (11)
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  • 1
    Electronic Resource
    Electronic Resource
    Die Abhängigkeit der interkristallinen Korrosion eines unstabilisierten 18/10-Chrom-Nickel-Stahles. von einigen Prüflösungen und vom Potential in siedender 2n H2SO4 (1964)
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 15 (1964), S. 621-631 
    Details
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The relationship of the intercrystalline corrosion of a non-stabilised 18/10-chromium-nickel steel with some test solutions and with the potential in boiling 2 n H2SO4Specimens of an austenitic 18/20 nickelchromium steel with about 0.06 pC C, quenched at 1300° C and annealed for different periods of time at 550 or 675° C were potentiostatically subjected to the attack of boiling 2n-H2SO4, of a nitric / hydrofluoric acid pickle at room temperature, and of boiling acids in accordance with the Strauss, Huey and Streicher test. Subsequently, the corrosion rates were determined by weighing and the corrosion examined by visual inspection and microscopically.In the active and passive condition grain boundary corrosion is only encountered after sensitizing annealing. In this connection, the potential merely determines the intensity of the grain boundary attack, but not its occurrence as such. The influence of the potential is more marked at higher than at lower sensitizing annealing temperatures. The test results can easily be interpreted with the aid of the chrome reduction theory.In the transition zone to the transpassive condition, and in the latter, an intercrystalline corrosion attack occurs which depends but little on the sensitizing annealing, and which also occurs with solution-annealed specimens. It is also in this zone of the potential that the non-potentiostatic tests according to Huey and Streicher are carried out.The test results show a specific reaction to chrome reduction of the corrosion attack in the active and passive condition, i.e. the attack in the hydrofluoric/nitric acid pickle and in the Strauss solution. In contrast, the Huey and Streicher tests additionally bring in other properties which, in the main, have an influence on the excess potential of the cathodic part-reaction. These testing agents cannot be regarded as specific criteria for the grain decomposition proneness.
    Notes: Proben eines austenitischen 18/10-Chrom-Nickel-Stahles mit etwa 0,06% C, die von 1300° C abgeschreckt und verschieden lange bei 550 und 675° C geglüht worden waren, wurden potentiostatisch dem Angriff siedender 2n-H2SO4, einer Salpetersäure-Flußsäure-Beize bei Raumtemperatur sowie dem Angriff siedender Säuren entsprechend dem Strauß, Huey- und Streicher-Test unterworfen. Anschließend werden die Korrosionsgeschwindigkeiten durch Wägung bestimmt und der Korrosionsangriff visuell und mikroskopisch im Schliffbild untersucht.Im Aktiv- und Passivzustand tritt Korngrenzenkorrosion nur nach einer Sensibilisierungsglühbehandlung auf. Das Potential bestimmt hierbei nur die Intensität des Korngrenzenangriffs und nicht das Auftreten desselben an sich. Der Einfluß des Potentials ist bei hohen Sensibilisierungslühtemperaturen stärker ausgeprägt, als bei niedrigen Temperaturen. Die Versuchsergebnisse lassen sich mit Hilfe der Chromverarmungstheorie zwanglos deuten.Im Übergangsbereich zum Transpassivzustand erfolgt ein interkristalliner Angriff, der nur wenig von der Sensibilisierungsglühbehandlung abhängt und auch bei lösungsgeglühten Proben auftritt. In diesem Potentialbereich erfolgen auch die nicht potentiostatischen Prüfungen nach Huey und Streicher.Die Versuchsergebnisse zeigen, daß der Angriff im Aktiv- und Passivzustand, also der Angriff in der Flußsäure-Salpeter- Beize und in der Straußschen Lösung, spezifisch auf Chromverarmung ansprechen. Beim Huey- und Streicher-Test werden dagegen zusätzlich noch Eigenschaften, die im wesentlichen die Überspannung der kathodischen Teilreaktion beeinflussen, miterfaßt. Diese Prüfmittel können nicht als spezifisch für die Kornzerfallsanfälligkeit angesehen werden.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/maco.19640150802
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  • 2
    Electronic Resource
    Electronic Resource
    Primäre Elementarprozesse an angeregten organischen Molekülen (1963)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 75 (1963), S. 872-873 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19630751829
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  • 3
    Electronic Resource
    Electronic Resource
    Die Massenspektren der Nikotin-N-Oxide und der mit Ihnen Verwandten Tetrahydrooxazine (1973)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 7 (1973), S. 839-843 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The mass spectra of the three nicotine-N-oxides are discussed, together with the spectra of tetrahydrooxazines. The compounds with an N-oxide function in the five membered ring partly rearrange thermally before electron-impact fragmentation.
    Notes: Die massenspektren der drei Nikotin-N-oxide werden zusammen mit den Spektren von Tetrahydrooxazinen diskutiert. Die Verbindungen mit N-Oxide-Ffunktion im 5-gliedrigen Ring lagern sich vor der Fragmentierung durch Elektronenstoß z.T. thermisch um.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210070708
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  • 4
    Electronic Resource
    Electronic Resource
    Struktureller Zusammenhang von [(C6H5)4As]NdCl4·8H2O und NdCl3·6H2O: übergang vom Raumnetz zur Schicht (1983)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 95 (1983), S. 1031-1032 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19830951239
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  • 5
    Electronic Resource
    Electronic Resource
    Structural Relationship of [(C6H5)4As]NdCl4·8H2O and NdCl3·6H2O: Transition from a Three-Dimensional to a Layer Structure (1983)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 22 (1983), S. 1009-1010 
    Details
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: No Abstract.The complete manuscript of this communication appears in: Angew. Chem. Suppl. 1983, 1399. DOI:10.1002/anie.198313990
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.198310091
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  • 6
    Electronic Resource
    Electronic Resource
    Struktureller Zusammenhang von [(C6H5)4As] NdCl4·8H2O und NdCl3·6H2O: Übergang vom Raumnetz zur Schicht (1983)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 22 (1983), S. 1399-1408 
    Details
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.198313990
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  • 7
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    Unknown
    Lileyite, Ba2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2, a new lamprophyllite-group mineral from the Eifel volcanic area, Germany (2012)
    Schweizerbart
    Details
    Publication Date: 2012-01-01
    Description: The new Mg- and F-dominant lamprophyllite-group mineral lileyite (IMA 2011-021) was found at the Löhley quarry, Üdersdorf, near Daun, Eifel Mountains, Rhineland-Palatinate (Rheinland-Pfalz), Germany, and named for the old name of the type locality, Liley. Associated minerals are nepheline, leucite, augite, magnetite, fluorapatite, perovskite, götzenite. Lileyite is brown, translucent; streak is white. It forms platy crystals up to 0.1 × 0.3 × 0.5 mm in size and their clusters up to 1 mm across on the walls of cavities in an alkaline basalt. Lileyite is brittle, with Mohs hardness of 3–4 and perfect cleavage on (001). Dcalc is 3.776 g/cm3. The new mineral is biaxial (+), a = 1.718(5), ß = 1.735(5), ? = 1.755(5), 2V (meas.) = 75(15)°, 2V (calc.) = 86°. The IR spectrum is given. The chemical composition is (EDS-mode electron microprobe, mean of 5 analyses, wt%): SiO2 28.05, BaO 26.39, TiO2 18.53, Na2O 6.75, MgO 4.58, FeO 4.48, CaO 2.30, SrO 2.23, MnO 1.44, K2O 1.41, Nb2O5 0.95, F 3.88, –O=F2 -1.63; total 99.36. The empirical formula based on 18 anions is: Ba1.50Sr0.19K0.26Na1.89Ca0.36Mn0.18Mg0.99Fe0.54Ti2.01Nb0.06Si4.06O16.23F1.77. The simplified formula is: Ba2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2. The crystal structure was solved using single-crystal X-ray diffraction data (R = 0.024). Lileyite is monoclinic, space group C2/m, a = 19.905(1), b = 7.098(1), c = 5.405(1) Å, ß = 96.349(5)°, V = 758.93(6) Å3, Z = 2. The strongest lines of the powder diffraction pattern [d, Å (I, %) (hkl)] are: 3.749 (45) (31–1), 3.464 (76) (510, 311, 401), 3.045 (37) (51–1), 2.792 (100) (221, 511), 2.672 (54) (002, 601, 20-2), 2.624 (43) (710, 42–1). Type material is deposited in the collections of the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia, registration number 4106/1.
    Print ISSN: 0935-1221
    Electronic ISSN: 1617-4011
    Topics: Geosciences
    Published by Schweizerbart
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  • 8
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    The sulfite anion in ettringite-group minerals: a new mineral species hielscherite, Ca3Si(OH)6(SO4)(SO3)·11H2O, and the thaumasite–hielscherite solid-solution series (2012)
    Mineralogical Society of Great Britain and Ireland
    Details
    Publication Date: 2012-10-08
    Description: Hielscherite, ideally Ca3Si(OH)6(SO4)(SO3)·11H2O, (IMA 2011-037) is the first ettringite-group mineral with essential sulfite. We have identified a continuous natural solid-solution series from endmember thaumasite, Ca3Si(OH)6(SO4)(CO3)·12H2O, to a composition with at least 77 mol.% endmember hielscherite. In this series, the SO3:CO3 ratio is variable, whereas the SO4 content remains constant. Compositions with more than 50 mol.% endmember hielscherite have only been found at Graulay quarry near Hillesheim in the western Eifel Mountains, Rhineland-Palatinate, where they occur with phillipsite-K, chabazite-Ca and gypsum in cavities in alkaline basalt. Sulfite-rich thaumasite has been found in hydrothermal assemblages in young alkaline basalts in two volcanic regions of Germany: it is widespread at Graulay quarry and occurs at Rother Kopf, Schellkopf and Bellerberg quarries in Eifel district; it has also been found at Zeilberg quarry, Franconia, Bavaria. Hielscherite forms matted fibrous aggregates up to 1 cm across and groups of acicular to prismatic hexagonal crystals up to 0.3 × 0.3 × 1.5 mm. Individual crystals are colourless and transparent with a vitreous lustre and crystal aggregates are white with a silky lustre. The Mohs hardness is 2–2½. Measured and calculated densities are Dmeans = 1.82(3) and Dcalc = 1.79 g cm−3. Hielscherite is optically uniaxial (−), ω = 1.494(2), ε = 1.476(2). The mean chemical composition of holotype material (determined by electron microprobe for Ca, Al, Si, and S and gas chromatography for C, H and N, with the S4+:S6+ ratio from the crystal-structure data) is CaO 27.15, Al2O3 2.33, SiO2 7.04, CO2 2.71, SO2 6.40, SO3 12.91, N2O5 0.42, H2O 39.22, total 98.18 wt.%. The empirical formula on the basis of 3 Ca atoms per formula unit is Ca3(Si0.73Al0.28)Σ1.01(OH)5.71(SO4)1.00(SO3)0.62(CO3)0.38(NO3)0.05·10.63H2O. The presence of sulfite was confirmed by crystal-structure analysis and infrared and X-ray absorption near edge structure spectra. The crystal structure of sulfite-rich thaumasite from Zeilberg quarry was solved by direct methods based on single-crystal X-ray diffraction data (R1 = 0.064). The structure of hielscherite was refined using the Rietveld method (Rwp = 0.0317). Hielscherite is hexagonal, P63, a = 11.1178(2), c = 10.5381(2) Å, V = 1128.06(4) Å3 and Z = 2. The strongest reflections in the X-ray powder pattern [(d,Å(I)(hkl)] are: 9.62(100)(010,100); 5.551(50)(110); 4.616(37)(012,102); 3.823(64)(112); 3.436(25)(211), 2.742(38)(032,302), 2.528(37)(123,213), 2.180(35)(042,402;223). In both hielscherite and sulfite-rich thaumasite, pyramidal sulfite groups occupy the same site as trigonal carbonate groups, with analogous O sites, whereas tetrahedral sulfate groups occupy separate positions. Hielscherite is named in honour of the German mineral collector Klaus Hielscher (b. 1957).
    Print ISSN: 0026-461X
    Electronic ISSN: 1471-8022
    Topics: Geosciences
    Published by Mineralogical Society of Great Britain and Ireland
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  • 9
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    The sulfite anion in ettringite-group minerals: a new mineral species hielscherite, Ca3Si(OH)6(SO4)(SO3)·11H2O, and the thaumasite–hielscherite solid-solution series (2012)
    Mineralogical Society of Great Britain and Ireland
    Details
    Publication Date: 2012-10-01
    Description: Hielscherite, ideally Ca3Si(OH)6(SO4)(SO3)·11H2O, (IMA 2011-037) is the first ettringite-group mineral with essential sulfite. We have identified a continuous natural solid-solution series from endmember thaumasite, Ca3Si(OH)6(SO4)(CO3)·12H2O, to a composition with at least 77 mol.% endmember hielscherite. In this series, the SO3:CO3 ratio is variable, whereas the SO4 content remains constant. Compositions with more than 50 mol.% endmember hielscherite have only been found at Graulay quarry near Hillesheim in the western Eifel Mountains, Rhineland-Palatinate, where they occur with phillipsite-K, chabazite-Ca and gypsum in cavities in alkaline basalt. Sulfite-rich thaumasite has been found in hydrothermal assemblages in young alkaline basalts in two volcanic regions of Germany: it is widespread at Graulay quarry and occurs at Rother Kopf, Schellkopf and Bellerberg quarries in Eifel district; it has also been found at Zeilberg quarry, Franconia, Bavaria. Hielscherite forms matted fibrous aggregates up to 1 cm across and groups of acicular to prismatic hexagonal crystals up to 0.3 × 0.3 × 1.5 mm. Individual crystals are colourless and transparent with a vitreous lustre and crystal aggregates are white with a silky lustre. The Mohs hardness is 2–2½. Measured and calculated densities are Dmeans = 1.82(3) and Dcalc = 1.79 g cm−3. Hielscherite is optically uniaxial (−), ω = 1.494(2), ε = 1.476(2). The mean chemical composition of holotype material (determined by electron microprobe for Ca, Al, Si, and S and gas chromatography for C, H and N, with the S4+:S6+ ratio from the crystal-structure data) is CaO 27.15, Al2O3 2.33, SiO2 7.04, CO2 2.71, SO2 6.40, SO3 12.91, N2O5 0.42, H2O 39.22, total 98.18 wt.%. The empirical formula on the basis of 3 Ca atoms per formula unit is Ca3(Si0.73Al0.28)Σ1.01(OH)5.71(SO4)1.00(SO3)0.62(CO3)0.38(NO3)0.05·10.63H2O. The presence of sulfite was confirmed by crystal-structure analysis and infrared and X-ray absorption near edge structure spectra. The crystal structure of sulfite-rich thaumasite from Zeilberg quarry was solved by direct methods based on single-crystal X-ray diffraction data (R1 = 0.064). The structure of hielscherite was refined using the Rietveld method (Rwp = 0.0317). Hielscherite is hexagonal, P63, a = 11.1178(2), c = 10.5381(2) Å, V = 1128.06(4) Å3 and Z = 2. The strongest reflections in the X-ray powder pattern [(d,Å(I)(hkl)] are: 9.62(100)(010,100); 5.551(50)(110); 4.616(37)(012,102); 3.823(64)(112); 3.436(25)(211), 2.742(38)(032,302), 2.528(37)(123,213), 2.180(35)(042,402;223). In both hielscherite and sulfite-rich thaumasite, pyramidal sulfite groups occupy the same site as trigonal carbonate groups, with analogous O sites, whereas tetrahedral sulfate groups occupy separate positions. Hielscherite is named in honour of the German mineral collector Klaus Hielscher (b. 1957).
    Print ISSN: 0026-461X
    Electronic ISSN: 1471-8022
    Topics: Geosciences
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  • 10
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    The sulfite anion in ettringite-group minerals: a new mineral species hielscherite, Ca3Si(OH)6(SO4)(SO3)·11H2O, and the thaumasite–hielscherite solid-solution series (2012)
    Mineralogical Society of Great Britain and Ireland
    Details
    Publication Date: 2012-10-01
    Description: Hielscherite, ideally Ca3Si(OH)6(SO4)(SO3)·11H2O, (IMA 2011-037) is the first ettringite-group mineral with essential sulfite. We have identified a continuous natural solid-solution series from endmember thaumasite, Ca3Si(OH)6(SO4)(CO3)·12H2O, to a composition with at least 77 mol.% endmember hielscherite. In this series, the SO3:CO3 ratio is variable, whereas the SO4 content remains constant. Compositions with more than 50 mol.% endmember hielscherite have only been found at Graulay quarry near Hillesheim in the western Eifel Mountains, Rhineland-Palatinate, where they occur with phillipsite-K, chabazite-Ca and gypsum in cavities in alkaline basalt. Sulfite-rich thaumasite has been found in hydrothermal assemblages in young alkaline basalts in two volcanic regions of Germany: it is widespread at Graulay quarry and occurs at Rother Kopf, Schellkopf and Bellerberg quarries in Eifel district; it has also been found at Zeilberg quarry, Franconia, Bavaria. Hielscherite forms matted fibrous aggregates up to 1 cm across and groups of acicular to prismatic hexagonal crystals up to 0.3 × 0.3 × 1.5 mm. Individual crystals are colourless and transparent with a vitreous lustre and crystal aggregates are white with a silky lustre. The Mohs hardness is 2–2½. Measured and calculated densities are Dmeas = 1.82(3) and Dcalc = 1.79 g cm–3. Hielscherite is optically uniaxial (–), ω = 1.494(2), ε = 1.476(2). The mean chemical composition of holotype material (determined by electron microprobe for Ca, Al, Si, and S and gas chromatography for C, H and N, with the S4+:S6+ ratio from the crystal-structure data) is CaO 27.15, Al2O3 2.33, SiO2 7.04, CO2 2.71, SO2 6.40, SO3 12.91, N2O5 0.42, H2O 39.22, total 98.18 wt.%. The empirical formula on the basis of 3 Ca atoms per formula unit is Ca3(Si0.73Al0.28)Σ1.01(OH)5.71(SO4)1.00(SO3)0.62(CO3)0.38(NO3)0.05·10.63H2O. The presence of sulfite was confirmed by crystal-structure analysis and infrared and X-ray absorption near edge structure spectra. The crystal structure of sulfite-rich thaumasite from Zeilberg quarry was solved by direct methods based on single-crystal X-ray diffraction data (R1 = 0.064). The structure of hielscherite was refined using the Rietveld method (Rwp = 0.0317). Hielscherite is hexagonal, P63, a = 11.1178(2), c = 10.5381(2) Å, V = 1128.06(4) Å3 and Z = 2. The strongest reflections in the X-ray powder pattern [(d, Å (I)(hkl)] are: 9.62(100)(010,100); 5.551(50)(110); 4.616(37)(012,102); 3.823(64)(112); 3.436(25)(211), 2.742(38)(032,302), 2.528(37)(123,213), 2.180(35)(042,402;223). In both hielscherite and sulfite-rich thaumasite, pyramidal sulfite groups occupy the same site as trigonal carbonate groups, with analogous O sites, whereas tetrahedral sulfate groups occupy separate positions. Hielscherite is named in honour of the German mineral collector Klaus Hielscher (b. 1957).
    Print ISSN: 0026-461X
    Electronic ISSN: 1471-8022
    Topics: Geosciences
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