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  • Articles  (26)
  • 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters  (17)
  • 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations
  • J24
  • Lunar and Planetary Science and Exploration
  • 2010-2014  (26)
  • 1995-1999
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  • 1
    Publication Date: 2021-06-15
    Description: Twenty-two gas samples were collected in August 2012 in the area of Amik basin (Turkey). Two samples were collected from gas seeps, one was a bubbling gas in a thermal spring, while the remaining were dissolved gases from cold and thermal groundwaters (T 16-43 °C). All gases were analysed for their chemical composition (He, H2, O2, N2, CH4 and CO2) and for their He isotopic composition. Dissolved gases were also analysed for the carbon isotopic composition of the total dissolved carbon (TDC), while free gases also for their higher hydrocarbon (C1 – C5) content and for D of H2 and CH4, 13C of CH4 Basing on their chemical composition, the gases can be roughly subdivided in three groups. Most of the dissolved gases (16) belonging to the first group were collected from springs or shallow wells (〈 150 m depth). All these samples contain mainly atmospheric gasses with very limited H2 (〈 80 ppm) and CH4 (1 – 2700 ppm) contents and minor concentrations of CO2 (0.5 – 11.2 %). The isotopic composition of TDC evidences an almost organic contribution. The only exception is represented by the CO2-richest sample where a small but significant mantle contribution is found. Such contribution can also be evidenced in its 3He rich isotopic composition. Further three samples of this group evidence a small mantle contribution. These samples were collected in the northern part of the basin along the main tectonic structures delimiting the basin and close to areas with quaternary volcanic activity. A second group is composed by two dissolved gases collected from deep boreholes (〉 1200 m depth). Their composition is typical of hydrocarbon reservoirs being very rich in CH4 (〉 78 %) and N2 (〉 13%). Also the water composition is typical of saline connate waters (Cl- and B-rich, SO4-poor). C-isotopic composition of methane ( 13C -65% ) points to a biogenic origin while He-isotopic composition indicates a prevailing crustal signature for one (R/Ra 0.16) of the sites and small mantle contribution for the other (R/Ra 0.98). To the last group belong four gas samples taken at two sites within the ophiolitic basement that crops out west of the basin. These gases have the characteristic composition of gas generated by low temperature serpentinisation processes with high hydrogen (37 – 50 %) and methane (10 – 61 %) concentrations. While all gases show an almost identical D-H2 of -750h those of one of the two sites display an isotopic composition of methane ( 13C -5h D -105% ) and a C1/[C2+C3] ( 100) ratio typical of abiogenic hydrocarbons and mantle-type helium (R/Ra: 1.33), while those of the other site evidence a contribution of a crustal (thermogenic) component ( 13C-CH4 -30h D -325h C1/[C2+C3] 3000). Such crustal contribution is also supported by higher N2 contents (40% instead of 2%) and lower He-isotopic composition (R/Ra 0.07). The preliminary results highlight contributions of mantle-derived volatiles to the fluids vented along the Amik Basin. The main tectonic structure of the area, the Death Sea Fault, and other parallel structures crossing the basin seem to be the responsible for deep-originated volatiles drainage towards shallow levels.
    Description: Submitted
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: gas geochemistry ; water chemistry ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 2
    Publication Date: 2020-11-10
    Description: Istituto Nazionale di Geofisica e Vulcanologia - Sezione di Napoli Osservatorio Vesuviano
    Description: Published
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: open
    Keywords: Rete gravimetrica ; Schede monografiche ; Misure gravimetriche ; Pantelleria ; 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: report
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  • 3
    Publication Date: 2021-06-15
    Description: We investigated the geochemical features of the fluids circulating over the Amik Basin (SE Turkey–Syria border), which is crossed by the Northern extension of theDSF (Dead Sea Fault) and represents the boundary area of three tectonic plates (Anatolian, Arabian and African plates). We collected 34 water samples (thermal and cold from natural springs and boreholes) as well as 8 gas samples (bubbling and gas seepage) besides the gases dissolved in the sampled waters. The results show that the dissolved gas phase is a mixture of shallow (atmospheric) and deep components either of mantle and crustal origin. Coherently the sampled waters are variable mixtures of shallow and deep ground waters, the latter being characterised by higher salinity and longer residence times. The deep groundwaters (fromboreholes deeper than 1000 m)have a CH4-dominated dissolved gas phase related to the presence of hydrocarbon reservoirs. The very unique tectonic setting of the area includes the presence of an ophiolitic block outcropping in the westernmost area on the African Plate, as well as basalts located to the North and East on the Arabic Plate. The diffuse presence of CO2-enriched gases, although diluted by the huge groundwater circulation, testifies a regional degassing activity. Fluids circulating over the ophiolitic block are marked by H2-dominated gases with abiogenic methane and high-pH waters. The measured 3He/4He isotopic ratios display contributions from both crustal and mantle-derived sources over both sides of the DSF. Although the serpentinization process is generally independent from mantle-type contribution, the recorded helium isotopic ratios highlight variable contents of mantle-derived fluids. Due to the absence of recent volcanism over the western side of the basin (African Plate), we argue that CO2-rich volatiles carrying mantle-type helium and enriched in heavy carbon, are degassed by deep-rooted regional faults rather than from volcanic sources.
    Description: Published
    Description: 23–39
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Dead Sea Fault ; Hydrogeochemistry ; Gas geochemistry ; He isotopes ; C isotopes ; Ophiolites ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2017-04-04
    Description: Etna volcano, Italy, hosts one of the major groundwater systems of the island of Sicily. Waters circulate within highly permeable fractured, mainly hawaiitic, volcanic rocks. Aquifers are limited downwards by the underlying impermeable sedimentary terrains. Thickness of the volcanic rocks generally does not exceed some 300 m, preventing the waters to reach great depths. This is faced by short travel times (years to tens of years) and low thermalisation of the Etnean groundwaters. Measured temperatures are, in fact, generally lower than 25 °C. But the huge annual meteoric recharge (about 0.97 kmˆ3) with a high actual infiltration coefficient (0.75) implies a great underground circulation. During their travel from the summit area to the periphery of the volcano, waters acquire magmatic heat together with volcanic gases and solutes through water-rock interaction processes. In the last 20 years the Etnean aquifers has been extensively studied. Their waters were analysed for dissolved major, minor and trace element, O, H, C, S, B, Sr and He isotopes, and dissolved gas composition. These data have been published in several articles. Here, after a summary of the obtained results, the estimation of the magmatic heat flux through the aquifer will be discussed. To calculate heat uptake during subsurface circulation, for each sampling point (spring, well or drainage gallery) the following data have been considered: flow rate, water temperature, and oxygen isotopic composition. The latter was used to calculate the mean recharge altitude through the measured local isotopic lapse rate. Mean recharge temperatures, weighted for rain amount throughout the year, were obtained from the local weather station network. Calculations were made for a representative number of sampling points (216) including all major issues and corresponding to a total water flow of about 0.315 kmˆ3/a, which is 40% of the effective meteoric recharge. Results gave a total energy output of about 140 MW/a the half of which is ascribable to only 13 sampling points. These correspond to the highest flow drainage galleries with fluxes ranging from 50 to 1000 l/s and wells with pumping rates from 70 to 250 l/s. Geographical distribution indicates that, like magmatic gas leakage, heat flow is influenced by structural features of the volcanic edifice. The major heat discharge through groundwater are all tightly connected either to the major regional tectonic systems or to the major volcanic rift zones along which the most important flank eruptions take place. But rift zones are much more important for heat upraise due to the frequent dikes injection than for gas escape because generally when dikes have been emplaced the structure is no more permeable to gases because it becomes sealed by the cooling magma.
    Description: Published
    Description: Vienna, Austria
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: groundwaters ; volcanic surveillance ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 5
    Publication Date: 2017-04-04
    Description: Nel corso del 2008 sono state eseguite due campagne gravimetriche nell’area vesuviana; la prima nel mese di aprile, la seconda a cavallo dei mesi di novembre e dicembre. In entrambe le campagne, i dati sono stati rilevati su 31 dei 32 vertici costituenti la rete in quanto la stazione “Baracche Forestali”, ubicata lungo la linea che corre all’interno della Forestale, è andata distrutta nel 2007 a causa di lavori di ripristino nell’area.
    Description: Istituto Nazionale di Geofisica e Vulcanologia
    Description: Published
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: open
    Keywords: MISURE GRAVIMETRICHE ; VESUVIO ; 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: report
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  • 6
    Publication Date: 2017-04-04
    Description: Nel 2008 sono state effettuate due campagne gravimetriche ai Campi Flegrei; la prima nel mese di febbraio, la seconda dal 20 ottobre al 11 novembre. In entrambre le campagne le misure sono state rilevate sull’intera rete che, nel corso della secondo rilevamento, è stata amplianta con l’istituzione di due nuovi vertici posizionati lungo la linea costiera, e precisamente tra le stazioni di Bagnoli e La Pietra.
    Description: Istituto Nazionale di Geofisica e Vulcanologia
    Description: Published
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: open
    Keywords: MISURE GRAVIMETRICHE ; CAMPI FLEGREI ; 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: report
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  • 7
    Publication Date: 2017-04-04
    Description: Gas and water samples were collected at CO2-rich wells in the plain of Florina (N. Greece). Chemical and isotopic composition of the analysed gases reveals their main crustal origin even if a small but significant contribution of mantle derived gases can be recognized. As a consequence of CO2 dissolution, HCO3- is always the main dissolved anion while cationic composition allows us to distinguish at least two main groups characterized by Na or Ca as dominant dissolved cations. The water-rock interaction is strongly enhanced by the dissolution of CO2 and the consequent lowering of pH. Such a process increases the mobility of some trace elements whose concentrations very often exceed UE drinking water limits. This study confirms that the Florina basin represents a good natural analogue of carbon storage systems and underscores the fact that possible deterioration of water quality due to CO2 leaks of the reservoirs must be carefully taken in account.
    Description: Published
    Description: 135-143
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: reserved
    Keywords: Groundwater ; Water quality ; carbon dioxide ; trace elements ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 8
    Publication Date: 2017-04-03
    Description: Water samples collected from public drinking-water supplies in Sicily were analysed for electric conductivity and for their chloride, sulphate and nitrate contents. The samples were collected as uniformly as possible from throughout the Sicilian territory, with an average sampling density of about 1 sample for every 7600 inhabitants. Chloride contents that ranged from 5.53 to 1302 mg/l were correlated strongly with the electric conductivity, a parameter used as a proxy for water salinity. The highest values are attributable to seawater contamination along the coasts of the island. High chloride and sulphate values attributable to evaporitic rock dissolution were found in the central part of Sicily. The nitrate concentrations ranged from 0.05 to 296 mg/l, with 31 samples (4.7% of the total) exceeding the maximum admissible concentration of 50 mg/l. Anomalous samples always came from areas of intensive agricultural usage, indicating a clear anthropogenic origin. The same parameters were also measured in bottled water sold in Sicily, and they all were within the ranges for public drinking-water supplies. The calculated mean nitrate intake from consuming public water supplies (16.1 mg/l) did not differ significantly from that of bottled water (15.2 mg/l). Although the quality of public water supplies needs to be improved by eliminating those that do not comply with the current drinking-water limits, at present it does not justify the high consumption of bottled water (at least for nitrate contents).
    Description: Published
    Description: 2845–2855
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: restricted
    Keywords: public water supplies ; nitrate ; sulphate ; chloride ; Sicily ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2017-04-04
    Description: Since 1982, high precision gravity measurements have been routinely carried out on Mt. Vesuvius. The gravity network consists of selected sites most of them coinciding with, or very close to, leveling benchmarks to remove the effect of the elevation changes from gravity variations. The reference station is located in Napoli, outside the volcanic area. Since 1986, absolute gravity measurements have been periodically made on a station on Mt. Vesuvius, close to a permanent gravity station established in 1987, and at the reference in Napoli. The results of the gravity measurements since 1982 are presented and discussed. Moderate gravity changes on short-time were generally observed. On long-term significant gravity changes occurred and the overall fields displayed well defined patterns. Several periods of evolution may be recognized. Gravity changes revealed by the relative surveys have been confirmed by repeated absolute measurements, which also confirmed the long-term stability of the reference site. The gravity changes over the recognized periods appear correlated with the seismic crises and with changes of the tidal parameters obtained by continuous measurements. The absence of significant ground deformation implies masses redistribution, essentially density changes without significant volume changes, such as fluids migration at the depth of the seismic foci, i.e. at a few kilometers. The fluid migration may occur through pre-existing geological structures, as also suggested by hydrological studies, and/or through new fractures generated by seismic activity. This interpretation is supported by the analyses of the spatial gravity changes overlapping the most significant and recent seismic crises.
    Description: Published
    Description: S0436
    Description: 2.6. TTC - Laboratorio di gravimetria, magnetismo ed elettromagnetismo in aree attive
    Description: JCR Journal
    Description: open
    Keywords: Gravity variations ; Volcano monitoring ; Vesuvio ; 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2017-04-04
    Description: The Florina basin, being the main commercial source of CO2 in Greece, represents a good natural analogue for the study of the impact of geologic carbon storage. It is part of a NNW-SSE trending graben filled with ~600 m Plio-Pleistocene fluvial and lacustrine deposits. The area is characterized by the upflow of great quantities of geogenic CO2 probably associated to presently extinct Quaternary volcanic activity. The gas originates mainly from crustal sources but has also a minor (~10%) mantle contribution. This strong upflow of nearly pure CO2 can be recognized in industrially exploitable gas reservoirs, high pCO2 shallow groundwaters and surface gas manifestations. But the increased CO2 content has a deleterious impact on groundwater quality. Due to the increased aggressiveness of the low-pH CO2-rich waters with respect to the aquifer rocks, EU drinking water limits are exceed for many parameters (e.g. Electric conductivity, pH, Na+, SO42-, F-, Al, B, Ba, Fe, Mn and Ni). Considering the additional impact of widespread agricultural activities, which is recognizable in sometimes elevated NO3- contents, only few of the sampled waters (4 out of 40) could be used for potable purposes. Aquifer waters are also characterized by high REE contents with ΣREE up to ~12 µg/l. Shale-normalized profiles show positive La and Y anomalies and Ce negative anomalies probably indicating a main derivation from iron oxyhydroxide dissolution. The positive Eu anomaly evidences also carbonate dissolution while the enrichment in HREE is probably due to the abundant presence of HCO3-, which increases HREE solubility through complexation. Future developments of carbon capture and storage programs in the nearby sedimentary basin of Ptolemais and Servia have to carefully take in account the possible deterioration of their groundwater resources due to CO2 leaks from the storage reservoirs.
    Description: Published
    Description: Bari, Italy
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Trace elements ; REE ; CCS natural analogues ; Florina ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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