ALBERT

Beschreibung: Recent developments in high resolution, time-of-flight chemical ionization mass spectrometry (HR-ToF-CIMS) have made possible the direct detection of atmospheric organic compounds in real-time with high sensitivity and with little or no fragmentation, including low volatility, highly oxygenated organic vapors that are precursors to secondary organic aerosol formation. Here, for the first time, we examine gas-phase O3 and OH oxidation products of α-pinene and naphthalene formed in the PAM flow reactor with an HR-ToF-CIMS using acetate reagent ion chemistry. Integrated OH exposures ranged from 1.2 × 1011 to 9.7 × 1011 molec cm−3 s, corresponding to approximately 1.0 to 7.5 days of equivalent atmospheric oxidation. Measured gas-phase organic acids are similar to those previously observed in environmental chamber studies. For both precursors, we find that acetate-CIMS spectra capture both functionalization (oxygen addition) and fragmentation (carbon loss) as a function of OH exposure. The level of fragmentation is observed to increase with increased oxidation. We present a method that estimates vapor pressures of organic molecules using the measured O/C ratio, H/C ratio, and carbon number for each compound detected by the CIMS. The predicted condensed-phase SOA average acid yields and O/C and H/C ratios agree within uncertainties with previous AMS measurements and ambient CIMS results. While acetate reagent ion chemistry is used to selectively measure organic acids, in principle this method can be applied to additional reagent ion chemistries depending on the application.

Beschreibung: We present an overview of the background, scientific goals, and execution of the Aerosol, Radiation, and Cloud Processes affecting Arctic Climate (ARCPAC) project of April 2008. We then summarize airborne measurements, made in the troposphere of the Alaskan Arctic, of aerosol particle size distributions, composition, and optical properties and discuss the sources and transport of the aerosols. The aerosol data were grouped into four categories based on gas-phase composition. First, the background troposphere contained a relatively diffuse, sulfate-rich aerosol extending from the top of the sea-ice inversion layer to 7.4 km altitude. Second, a region of depleted (relative to the background) aerosol was present within the surface inversion layer over sea-ice. Third, layers of dense, organic-rich smoke from open biomass fires in southern Russia and southeastern Siberia were frequently encountered at all altitudes from the top of the inversion layer to 7.1 km. Finally, some aerosol layers were dominated by components originating from fossil fuel combustion. Of these four categories measured during ARCPAC, the diffuse background aerosol was most similar to the average springtime aerosol properties observed at a long-term monitoring site at Barrow, Alaska. The biomass burning (BB) and fossil fuel layers were present above the sea-ice inversion layer and did not reach the sea-ice surface during the course of the ARCPAC measurements. The BB aerosol layers were highly scattering and were moderately hygroscopic. On average, the layers produced a noontime net heating of ~0.1 K day−1 between 3 and 7 km and a slight cooling at the surface. The ratios of particle mass to carbon monoxide (CO) in the BB plumes, which had been transported over distances 〉5000 km, were comparable to the high end of literature values derived from previous measurements in wildfire smoke. These ratios suggest minimal precipitation scavenging and removal of the BB particles between the time they were emitted and the time they were observed in dense layers above the sea-ice inversion layer.

Beschreibung: In situ measurements of ozone, photochemically active bromine compounds, and other trace gases over the Arctic Ocean in April 2008 are used to examine the chemistry and geographical extent of ozone depletion in the arctic marine boundary layer (MBL). Data were obtained from the NOAA WP-3D aircraft during the Aerosol, Radiation, and Cloud Processes affecting Arctic Climate (ARCPAC) study and the NASA DC-8 aircraft during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) study. Fast (1 s) and sensitive (detection limits at the low pptv level) measurements of BrCl and BrO were obtained from three different chemical ionization mass spectrometer (CIMS) instruments, and soluble bromide was measured with a mist chamber. The CIMS instruments also detected Br2. Subsequent laboratory studies showed that HOBr rapidly converts to Br2 on the Teflon instrument inlets. This detected Br2 is identified as active bromine and represents a lower limit of the sum HOBr+Br2. The measured active bromine is shown to likely be HOBr during daytime flights in the arctic. In the MBL over the Arctic Ocean, soluble bromide and active bromine were consistently elevated and ozone was depleted. Ozone depletion and active bromine enhancement were confined to the MBL that was capped by a temperature inversion at 200–500 m altitude. In ozone-depleted air, BrO rarely exceeded 10 pptv and was always substantially lower than soluble bromide that was as high as 40 pptv. BrCl was rarely enhanced above the 2-pptv detection limit, either in the MBL, over Alaska, or in the arctic free troposphere.

Beschreibung: A new technique for determining the depth of expendable bathythermographs (XBTs) is developed. This new method combines a forward-stepping calculation which incorporates all of the forces on the XBT devices during their descent. Of particular note are drag forces which are calculated using a new drag coefficient expression. That expression, obtained entirely from computational fluid dynamic modeling, accounts for local variations in the ocean environment. Consequently, the method allows for accurate determination of depths for any local temperature environment. The results, which are entirely based on numerical simulation, are compared with an experimental descent of an LM-Sippican T-5 XBT. It is found that the calculated depths differ by less than 3 % from depth estimates using the industry standard FRE. Furthermore, the differences decrease with depth. The computational model allows an investigation of the fluid patterns along the outer surface of the probe as well as in the interior channel. The simulations take account of complex flow phenomena such as laminar-turbulent transition and flow separation.

Beschreibung: A new technique for determining the depth of expendable bathythermographs (XBTs) is developed. This new method uses a forward-stepping calculation which incorporates all of the forces on the XBT devices during their descent. Of particular note are drag forces which are calculated using a new drag coefficient expression. That expression, obtained entirely from computational fluid dynamic modeling, accounts for local variations in the ocean environment. Consequently, the method allows for accurate determination of depths for any local temperature environment. The results, which are entirely based on numerical simulation, are compared with the experiments of LM Sippican T-5 XBT probes. It is found that the calculated depths differ by less than 3% from depth estimates using the standard fall-rate equation (FRE). Furthermore, the differences decrease with depth. The computational model allows an investigation of the fluid flow patterns along the outer surface of the probe as well as in the interior channel. The simulations take account of complex flow phenomena such as laminar-turbulent transition and flow separation.

Beschreibung: We carry out a combined analysis of the short- and long-period seismic signals generated by the devastating Oso-Steelhead landslide that occurred on 22 March 2014. The seismic records show that the Oso-Steelhead landslide was not a single slope failure, but a succession of multiple failures distinguished by two major collapses that occurred approximately three minutes apart. The first generated long-period surface waves that were recorded at several proximal stations. We invert these long-period signals for the forces acting at the source, and obtain estimates of the first failure runout and kinematics, as well as its mass after calibration against the mass-center displacement estimated from remote-sensing imagery. Short-period analysis of both events suggests that the source dynamics of the second are more complex than the first. No distinct long-period surface waves were recorded for the second failure, which prevents inversion for its source parameters. However, by comparing the seismic energy of the short-period waves generated by both events we are able to estimate the volume of the second. Our analysis suggests that the volume of the second failure is about 15–30% of the total landslide volume, which is in agreement with ground observations.

Beschreibung: The impact of particle shape on the friction angle, and the resulting critical shear stress on sediment dynamics, is still poorly understood. In areas characterized by sediments of specific shape, particularly non-rounded particles, this can lead to large departures from the expected sediment dynamics. The steep slope (1:10) of the mixed sand-gravel beach at Advocate Harbour was found stable in large-scale morphology over decades, despite a high tidal range of ten meters or more, and strong shorebreak action during storms. The Advocate sand (d 〈 2 mm) was found to have an elliptic, plate-like shape. Exceptionally high friction angles of the material were determined using direct shear, ranging from φ ≈ 41–46°, while the round to angular gravel was characterized by φ = 33°. The addition of 25% of the elliptic sand to the gravel led to an immediate increase of the friction angle to φ = 38°. Furthermore, re-organization of the particles occurred during shearing, being characterized by a short phase of settling and compaction, followed by a pronounced strong dilatory behavior and an accompanying strong increase of shear stress. Long-term shearing (24 h) using a ring shear apparatus led to destruction of the particles without re-compaction. Finally, submerged particle mobilization was simulated using a tilted tray in a tank. Despite a smooth tray surface, particle motion was not initiated until reaching tray tilt angles of 31° and more, being 7° steeper than the latest gravel motion initiation. In conclusion, geotechnical laboratory experiments quantified the important impact of the elliptic, plate-like shape of Advocate Beach sand on the friction angles of both pure sand and sand-gravel mixtures. The resulting effect on initiation of particle motion was confirmed in tilting tray experiments. This makes it a vivid example of how particle shape can contribute to the stabilization of the beachface.

Beschreibung: The 1-D saltation-abrasion model of channel bedrock incision of Sklar and Dietrich, in which the erosion rate is buffered by the surface area fraction of bedrock covered by alluvium, was a major advance over models that treat river erosion as a function of bed slope and drainage area. Their model is, however, limited because it calculates bed cover in terms of bedload sediment supply rather than local bedload transport. It implicitly assumes that as sediment supply from upstream changes, the transport rate adjusts instantaneously everywhere downstream to match. This assumption is not valid in general, and thus can give rise unphysical consequences. Here we present a unified morphodynamic formulation of both channel incision and alluviation which specifically tracks the spatiotemporal variation of both bedload transport and alluvial thickness. It does so by relating the cover fraction not to a ratio of bedload supply rate to capacity bedload transport, but rather to the ratio of alluvium thickness to a macro-roughness characterizing the bedrock surface. The new formulation predicts waves of alluviation and rarification, in addition to bedrock erosion. Embedded in it are three physical processes: alluvial diffusion, fast downstream advection of alluvial disturbances and slow upstream migration of incisional disturbances. Solutions of this formulation over a fixed bed are used to demonstrate the stripping of an initial alluvial cover, the emplacement of alluvial cover over an initially bare bed and the advection–diffusion of a sediment pulse over an alluvial bed. A solution for alluvial-incisional interaction in a channel with a basement undergoing net rock uplift shows how an impulsive increase in sediment supply can quickly and completely bury the bedrock under thick alluvium, so blocking bedrock erosion. As the river responds to rock uplift or base level fall, the transition point separating an alluvial reach upstream from an alluvial-bedrock reach downstream migrates upstream in the form of a "hidden knickpoint". A solution for the case of a zone of rock subsidence (graben) bounded upstream and downstream by zones of rock uplift (horsts) yields a steady-state solution that is unattainable with the original saltation-abrasion model. A solution for the case of bedrock-alluvial coevolution upstream of an alluviated river mouth illustrates how the bedrock surface can be progressive buried not far below the alluvium. Because the model tracks the spatiotemporal variation of both bedload transport and alluvial thickness, it is applicable to the study of the incisional response of a river subject to temporally varying sediment supply. It thus has the potential to capture the response of an alluvial-bedrock river to massive impulsive sediment inputs associated with landslides or debris flows.

Beschreibung: Results are presented from a pilot study of shoreface sediment dynamics on a steep, poorly sorted, coarse-grained, mega-tidal beach at the head of the Bay of Fundy, Nova Scotia, Canada. The experiment involved the first field deployment of a prototype wide- band, pulse-coherent, bistatic acoustic Doppler profiling system. Measurements of the vertical structure of flow and turbulence above a sloping bed, as well as bed material velocity, demonstrate the capabilities of this instrument vis-a-vis studies of nearshore sediment dynamics at the field scale. The second focus of the paper is the surprising observation that the surficial sediment median diameter, across the lower two-thirds of the intertidal zone, underwent a pronounced decrease when wave forcing was more energetic, compared to values observed during calmer conditions. The explanation for this result appears to involve the formation – in wave-dominated conditions – of O(1 m)-wavelength, 20 cm high ripples on the rising tide, which are then planed flat by the swash and/or the shorebreak on the subsequent ebb.

Beschreibung: Results are presented from a pilot study of shore-face sediment dynamics on a steep, poorly sorted, coarse-grained, megatidal beach at the head of the Bay of Fundy, Nova Scotia, Canada. The experiment involved the first field deployment of a prototype wideband, pulse-coherent, bistatic acoustic Doppler profiling system. Measurements of the vertical structure of flow and turbulence above a sloping bed, as well as bed material velocity, demonstrate the capabilities of this instrument vis-à-vis studies of nearshore sediment dynamics at the field scale. The second focus of the paper is the unexpected observation that the surficial sediment median diameter, across the lower two-thirds of the intertidal zone, underwent a pronounced decrease when wave forcing was more energetic, compared to values observed during calmer conditions. The explanation for this result appears to involve the formation – in wave-dominated conditions – of metre-scale wavelength, 20 cm high ripples on the rising tide, which are then planed flat by the swash and/or the shore break on the subsequent ebb.