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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 16 (1988), S. 423-425 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A rapid and reproducible procedure suitable for the analysis of polycyclic aromatic compounds (PACs) in sludges and soil samples has been developed. The PACs are isolated by ultrasonic extraction with methyl chloride, redissolution of the crude extract in isooctane and clean-up of the PAC-containing fraction by chromatography on alumina micro-columns. After separation and quantitative determination of the various PACs by capillary gas chromatography/mass spectrometry, more than 50 PAC compounds which cover a wide range of concentrations were detected in the sludge samples. The most abundant compounds were mono-, di- and trimethyl derivatives of naphthalene, phenanthrene, fluorene, dibenzethiophene and naphthothiophene. No accumulation of PAC in an agricultural soil after an experiment of compost application over three years was observed.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 12 (1985), S. 405-408 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electron impact induced fragmentations observed in the mass spectra of eight 1,4-diene-3-ketopregnane steroids are described. The effect of hydroxyl substituents in positions 11β, 17α and 21, on the typical fragmentation pattern is analysed; in particular the ‘long range’ effect of the 17α-hydroxy group on the relative abundance of the ions m/z 121 and 122 is confirmed using specific deuterium labelling.
    Additional Material: 2 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 20 (1985), S. 646-647 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 16 (1987), S. 143-146 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The influence of the photons emitted by a 241Am XRF excitation source below 59.6 keV on sample fluorescence production has been analysed. A general method for evaluating the contribution of the various lines from the source in specific equipment configurations is presented. The excitation was performed with 23 elemental targets and the measured experimental intensities were fitted by means of a minimization program which takes into account the most important transition groups observed in the spectrum of the excitation source. The program allows for attenuation of excitation and fluoresced photons in the target. Intensity data for the exciting beam were compared with the theoretical intensities of photons from 237Np, and it was concluded that these values are compatible with the Am and Al thicknesses of the excitation source. Correction factors considering low-energy transitions were calculated for several elements for both thick and thin targets. The over-excitation evaluated for Z = 34 reached values ranging between 180% and 550%.
    Additional Material: 1 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 26 (1988), S. 963-966 
    ISSN: 0749-1581
    Keywords: 20-Methylenepregnanes ; 3-Methylenepregnanes ; Synthesis ; 13C NMR Steroid hormones ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 20-Methylpregna-4,20-dien-3-one and the corresponding 17α-hydroxy, 20-hydroxymethyl and 17α-hydroxy-20-hydroxymethyl derivatives were prepared from the 20-keto compounds by Wittig reaction or a modified Simmons-Smith reaction. The 13C NMR spectra of these steroids and of 3-methylene derivatives are analysed. Solvent effects produced by addition of methanol-d4 in the spectra of the 20-methylene steroids are correlated with intramolecular hydrogen bonding in the corresponding 20-ketosteroids.
    Additional Material: 3 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 17 (1986), S. 173-175 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The νt(OH) and νt(OD) torsional modes in some chloro-substituted derivatives of phenol were assigned from their Raman spectra in CS2 solution. The corresponding rotation barriers were then calculated by means of a rigorous optimization method. Some theoretical calculations have allowed an extension of the discussion to the vapour phase.
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 20 (1989), S. 555-560 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A study of the electronic, infrared, Raman and pre-resonace Raman spectra of the solid complex tris(8-hydroxyquinolinato)vanadium(III) was performed. The excitation profiles of the vibrational modes that show preresonance on excitation with laser lines within the electronic bands in the visible region are reported and, on this basis and molecular orbital calculations, several vibrational and electronic absorption bands were assigned.
    Additional Material: 3 Ill.
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  • 8
    Publication Date: 2014-01-09
    Description: Author(s): Ramón Bécar, P. A. González, and Y. Vásquez We study Chern-Simons black holes in d dimensions and we calculate analytically the quasinormal modes of fermionic perturbations. Also, we consider as background the five-dimensional Chern-Simons black hole with torsion and the BTZ black hole with torsion. We have found that the quasinormal modes de... [Phys. Rev. D 89, 023001] Published Wed Jan 08, 2014
    Keywords: Astrophysics
    Print ISSN: 0556-2821
    Electronic ISSN: 1089-4918
    Topics: Physics
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  • 9
    Publication Date: 2019-07-13
    Description: We report the results from a systematic search for molecular (OH 119 micron) outflows with Herschel/PACS in a sample of 43 nearby (z 〈 0.3) galaxy mergers, mostly ultraluminous infrared galaxies (ULIRGs) and QSOs. We find that the character of the OH feature (strength of the absorption relative to the emission) correlates with that of the 9.7 micron silicate feature, a measure of obscuration in ULIRGs. Unambiguous evidence for molecular outflows, based on the detection of OH absorption profiles with median velocities more blueshifted than50 km/s, is seen in 26 (70%) of the 37 OH-detected targets, suggesting a wide-angle (approx. 145 deg.) outflow geometry. Conversely, unambiguous evidence for molecular inflows, based on the detection of OH absorption profiles with median velocities more redshifted than +50 km/s is seen in only four objects, suggesting a planar or filamentary geometry for the inflowing gas. Terminal outflow velocities of approx. 1000 km/s are measured in several objects, but median outflow velocities are typically approx.200 km/s1. While the outflow velocities show no statistically significant dependence on the star formation rate, they are distinctly more blueshifted among systems with large active galactic nucleus (AGN) fractions and luminosities [log (L(sub AGN)/L(sub solar)) =〉 11.8 +/- 0.3]. The quasars in these systems play a dominant role in driving the molecular outflows. However, the most AGN dominated systems, where OH is seen purely in emission, show relatively modest OH line widths, despite their large AGN luminosities, perhaps indicating that molecular outflows subside once the quasar has cleared a path through the obscuring material.
    Keywords: Astrophysics
    Type: GSFC-E-DAA-TN12514 , The Astrophysical Journal (ISSN 0004-637X); 776; 1; 27
    Format: application/pdf
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  • 10
    Publication Date: 2019-07-13
    Description: The Cygnus region is a very bright and complex portion of the TeV sky, host to unidentified sources and a diffuse excess with respect to conventional cosmic-ray propagation models. Two of the brightest TeV sources, MGRO J2019+37 and MGRO J2031+41, are analyzed using Milagro data with a new technique, and their emission is tested under two different spectral assumptions: a power law and a power law with an exponential cutoff. The new analysis technique is based on an energy estimator that uses the fraction of photomultiplier tubes in the observatory that detect the extensive air shower. The photon spectrum is measured in the range 1-100 TeV using the last three years of Milagro data (2005-2008), with the detector in its final configuration. An F-test indicates that MGRO J2019+37 is better fit by a power law with an exponential cutoff than by a simple power law. The best-fitting parameters for the power law with exponential cutoff model are a normalization at 10 TeV of 7(sup +5 sub 2) 10(exp 10)/ s /sq m/ TeV, a spectral index of 2.0(sup +0.5 sub -10), and a cutoff energy of 29(sup +50 sub 16) TeV. MGRO J2031+41 shows no evidence of a cutoff. The best-fitting parameters for a power law are a normalization of 2.1(sup +0.6 sub 0.6) 10(exp 10)/ s/sq m/ TeV and a spectral index of 3.22(sup +0.23 sub 0.18. The overall flux is subject to a approx.. 30% systematic uncertainty. The systematic uncertainty on the power-law indices is approx. 0.1. Both uncertainties have been verified with cosmic-ray data. A comparison with previous results from TeV J2032+4130, MGRO J2031+41, and MGRO J2019+37 is also presented.
    Keywords: Astrophysics
    Type: GSFC-E-DAA-TN9514 , The Astrophysical Journal; 753; 2; 159
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