ALBERT

Description: Rift-related magmatism in the Guaymas Basin, Gulf of California induces hydrothermal activity within the basin sediments. Mobilized fluids migrate to the seafloor where they are emitted into the water column changing ocean chemistry and fuelling chemosynthetic ecosystems. New seismic and geochemical data from the northern rift arm of the Guaymas Basin document the variety of fluid expulsion phenomena from large-scale subsurface sediment mobilization related to contact metamorphosis to focused small-scale structures. The geochemical composition of emitted fluids depends largely on the age of the fluid escape structures with respect to the underlying intrusions. Whereas, old structures are dominated by methane emission, young vent sites are characterized by hot fluids that carry a wide range of minerals in solution. The overall high geothermal gradient within the basin (mainly between 160 and 260 °C/km) leads to a thin gas hydrate stability zone. Thus, deep hydrothermal fluid advection affects the gas hydrate system and makes it more dynamic than in colder sedimentary basins.

Description: Acoustic imaging has revealed more than 7000 pockmarks on the seafloor above the Troll East gas field in the Norwegian North Sea. We present the first comprehensive study conducted on one of the World's largest pockmark fields complementing the acoustic data with extensive sampling, geochemical and petrographical studies. Specifically, we aimed at detecting possible active seepage still present over this vast area. The pockmarks are present as isolated structures, on average ~ 35 m wide and up to 100 m in size. In addition, smaller satellite pockmarks surround some of the pockmarks. In contrast to the muddy surroundings, parts of the investigated pockmarks contain laterally extensive carbonate deposits or meter sized carbonate blocks. These blocks provide shelter to abundant colonies of benthic megafauna. The carbonate blocks are comprised of micritic Mg-calcite and calcite, micritic aragonite, and botryoidal aragonite. Framboidal pyrite is also commonly present. Carbon isotopic values of the carbonates are 13C-depleted (δ13C as low as − 59.7‰) and with δ18O up to 4.5‰, indicating a methanogenic origin, possibly linked to gas hydrate dissociation. Pore water extracted from shallow cores from the centre and the flanks of the pockmarks show similar Cl and SO4 profiles as the reference cores outside the pockmarks, ruling out active methane seepage. This conclusion is also supported by seafloor video observations that did not reveal any evidence of visual fluid seepage, and by the absence of microbial mats and by the fact that the carbonate blocks are exposed on the seafloor and party oxidized on the surface. We conclude that methane seepage formed this extensive gas field following to gas hydrate dissociation.

Description: Highlights • Sub-basalt imaging improvement on the Vøring Margin • Definition of a new seismic facies unit: the Lower Series Flows • Significant organic carbon content within the melting crustal segment • Apectodinium augustum marker for the PETM is reworked into the Lower Series Flows • The Lower Series Flows, early Eocene in age, predate the Vøring Margin breakup Abstract Improvements in sub-basalt imaging combined with petrological and geochemical observations from the Ocean Drilling Program (ODP) Hole 642E core provide new constraints on the initial breakup processes at the Vøring Margin. New and reprocessed high quality seismic data allow us to identify a new seismic facies unit which we define as the Lower Series Flows. This facies unit is seismically characterized by wavy to continuous subparallel reflections with an internal disrupted and hummocky shape. Drilled lithologies, which we correlate to this facies unit, have been interpreted as subaqueous flows extruding and intruding into wet sediments. Locally, the top boundary of this facies unit is defined as a negative in polarity reflection, and referred as the K-Reflection. This reflection can be correlated with the spatial extent of pyroclastic deposits, emplaced during transitional shallow marine to subaerial volcanic activities during the rift to drift transition. The drilled Lower Series Flows consist of peraluminous, cordierite bearing peperitic basaltic andesitic to dacitic flows interbedded with thick volcano-sedimentary deposits and intruded sills. The peraluminous geochemistry combined with available C (from calcite which fills vesicles and fractures), Sr, Nd, and Pb isotopes data point towards upper crustal rock-mantle magma interactions with a significant contribution of organic carbon rich pelagic sedimentary material during crustal anatexis. From biostratigraphic analyses, Apectodinium augustum was found in the The Lower Series Flows. This species is a marker for the Paleocene – Eocene Thermal Maximum (PETM). However, the absence of very low carbon isotope values (from bulk organic matter), that characterize the PETM, imply that A.augustum was reworked into the early Eocene sediments of this facies unit which predate the breakup time of the Vøring Margin. Finally, a plausible conceptual emplacement model for the Lower Series Flows facies unit is proposed. This model comprises several stages: (1) the emplacement of subaqueous peperitic basaltic andesitic flows intruding and/or extruding wet sediments; (2) a subaerial to shallow marine volcanism and extrusion of dacitic flows; (3) a proto-breakup phase with intense shallow marine to subaerial explosive volcanism responsible for pyroclastic flow deposits which can be correlated with the seismic K-Reflection and (4) the main breakup stage with intense transitional tholeiitic MORB-type volcanism and large subsidence concomitant with the buildup of the Seaward Dipping Reflector wedge.

Description: During opening of a new ocean magma intrudes into the surrounding sedimentary basins. Heat provided by the intrusions matures the host rock creating metamorphic aureoles potentially releasing large amounts of hydrocarbons. These hydrocarbons may migrate to the seafloor in hydrothermal vent complexes in sufficient volumes to trigger global warming, e.g. during the Paleocene Eocene Thermal Maximum (PETM). Mound structures at the top of buried hydrothermal vent complexes observed in seismic data off Norway were previously interpreted as mud volcanoes and the amount of released hydrocarbon was estimated based on this interpretation. Here, we present new geophysical and geochemical data from the Gulf of California suggesting that such mound structures could in fact be edifices constructed by the growth of black-smoker type chimneys rather than mud volcanoes. We have evidence for two buried and one active hydrothermal vent system outside the rift axis. The vent releases several hundred degrees Celsius hot fluids containing abundant methane, mid-ocean-ridge-basalt (MORB)-type helium, and precipitating solids up to 300 m high into the water column. Our observations challenge the idea that methane is emitted slowly from rift-related vents. The association of large amounts of methane with hydrothermal fluids that enter the water column at high pressure and temperature provides an efficient mechanism to transport hydrocarbons into the water column and atmosphere, lending support to the hypothesis that rapid climate change such as during the PETM can be triggered by magmatic intrusions into organic-rich sedimentary basins.

Description: Injection of CO2 in subsurface reservoirs may cause overburden deformation and CO2 leakage. The aim of this study is to apply technologies for detection and monitoring of CO2 leakage and deformation above the injection reservoirs. The examples of this study include data from the Vestnesa Ridge natural seep site, the Snøhvit gas field and CO2 storage site region, and the Gemini North gas reservoir. Reprocessing of existing 3D high-resolution seismic data allows resolving features with a vertical and lateral resolution down to c. 1 m and c. 5 m respectively. The current acquisition systems could be modified to image structures down to one meter in both the vertical and horizontal directions. We suggest a monitoring workflow that includes baseline and time-lapse acquisition of high-resolution 3D seismic data, integrated with geochemical, geophysical, and geotechnical seabed core and water-column measurements. The outcome of such a workflow can deliver reliable quantitative property volumes of the subsurface and will be able to image meter-sized anomalies of fluid leakage and deformation in the overburden.

Description: Highlights • Determination of the tectonomagmatic evolution of the NW Atlantic • Mapping of the breakup-related magmatism using the vocanostratigraphy concept • Mapping of the magnetic and gravimetric crustal domain patterns and their boundaries using integrated SGM method • Analyses of seabed and onshore samples and field analogues work • New plate tectonic reconstruction for the NW Atlantic Abstract Passive margins are the locus of tectonic and magmatic processes leading to the formation of highly variable along-strike and conjugate margins structures. Using extensive new seismic, gravity, and magnetic datasets, complemented by seabed samples and field work, we investigate the tectonomagmatic evolution of the northwest (NW) Atlantic where breakup-related igneous rocks were emplaced during several Paleogene events associated with lithospheric stretching, continental breakup, and the formation of new oceanic basins. Interpretational methods include integrated seismic-gravity-magnetic (SGM) interpretation and seismic volcanostratigraphy. In addition, seabed and field samples were collected and analyzed to constrain the basin stratigraphy, hydrocarbon potential, and the geochronology and geochemistry of the volcanic sequences. Offshore, 2D seismic data reveal several Seaward Dipping Reflector (SDR) wedges and escarpments in the Labrador Sea, Davis Strait, and Baffin Bay. Onshore, eastward prograding foreset-bedded hyaloclastite delta deposits and overlying horizontal lava successions outcrop on Nuussuaq. These hyaloclastites and lava successions are world class analogues to the Lava Delta and Landward Flows volcanic seismic facies units identified offshore. Our mapping results document an aerial extent of the Paleogene breakup-related volcanics of 0.3 × 106 km2, with an estimated volume of 0.5–0.6 × 106 km3. Basalt samples recovered by dredging the Upernavik Escarpment have late Paleocene to/early Eocene ages, whereas the sedimentary samples provide an excellent seismic tie with the stratigraphy and the geology in this frontier area. From the integrated SGM interpretation, we identify a rapidly thinning crust and changes in top and intra-basement seismic reflection characteristics in the oceanic domain correlated with transition between different magnetic domains. The mapping results were subsequently integrated in a plate tectonic model. The plate tectonic reconstruction and basalt geochronology suggest that the majority of the volcanism in the NW Atlantic occurred between ~62 and ~58 Ma, associated with an increased spreading rate in the Labrador Sea, starting from the onset of the Selandian (~61.6 Ma). A change in the spreading direction during the Eocene (~56 Ma), synchronously with a shift of volcanic activity from the NW to the NE Atlantic, correspond to a northward drift of Greenland and the initiation of the Eurekan Orogeny. Finally, our interpretations reveal a complex rift configuration along the NW Atlantic conjugate margins both prior to and during breakup.