ALBERT

Description: High performance improvement (+88% in peak G m and 〉30% in linear and saturation region drain currents) was observed for N-MOSFETs with Oxygen-Inserted (OI) Si channel. From TCAD analysis of the C-V measurement data, the improvement was confirmed to be due to electron mobility enhancement of the OI Si channel (+75% at N inv  = 4.0 × 10 12  cm −2 and +25% at N inv  = 8.0 × 10 12  cm −2 ). Raman and high-resolution Rutherford backscattering measurements confirmed that negligible strain is induced in the OI Si layer, and hence, it cannot be used to explain the origin of mobility improvement. Poisson-Schrödinger based quantum mechanical simulation was performed, taking into account phonon, surface roughness and Coulomb scatterings. The OI layer was modeled as a “quasi barrier” region with reference to the Si conduction band edge to confine inversion electrons. Simulation explains the measured electron mobility enhancement as the confinement effect of inversion electrons while the formation of an super-steep retrograde well doping profile in the channel (as a result of dopant diffusion blocking effect accompanied by introduction of the OI layer) also contributes 50%–60% of the mobility improvement.

Description: Compact optical interconnects require efficient lasers and modulators compatible with silicon. Ab initio modeling of Ge 1−x C x (x = 0.78%) using density functional theory with HSE06 hybrid functionals predicts a splitting of the conduction band at Γ and a strongly direct bandgap, consistent with band anticrossing. Photoreflectance of Ge 0.998 C 0.002 shows a bandgap reduction supporting these results. Growth of Ge 0.998 C 0.002 using tetrakis(germyl)methane as the C source shows no signs of C-C bonds, C clusters, or extended defects, suggesting highly substitutional incorporation of C. Optical gain and modulation are predicted to rival III–V materials due to a larger electron population in the direct valley, reduced intervalley scattering, suppressed Auger recombination, and increased overlap integral for a stronger fundamental optical transition.

Description: 〈span〉〈div〉Abstract〈/div〉At the 2015 United Nations International Climate Change Conference in Paris (COP21), 197 national parties committed to limit global warming to well below 2°C. But current plans and pace of progress are still far from sufficient to achieve this objective. Here we review the role that geoscience and the subsurface could play in decarbonizing electricity production, industry, transport and heating to meet UK and international climate change targets, based on contributions to the 2019 Bryan Lovell meeting held at the Geological Society of London. Technologies discussed at the meeting involved decarbonization of electricity production via renewable sources of power generation, substitution of domestic heating using geothermal energy, use of carbon capture and storage (CCS), and more ambitious technologies such as bioenergy and carbon capture and storage (BECCS) that target negative emissions. It was noted also that growth in renewable energy supply will lead to increased demand for geological materials to sustain the electrification of the vehicle fleet and other low-carbon technologies. The overall conclusion reached at the 2019 Bryan Lovell meeting was that geoscience is critical to decarbonization, but that the geoscience community must influence decision-makers so that the value of the subsurface to decarbonization is understood.〈/span〉

Description: In this paper we describe a setup for x-ray scattering experiments on complex fluids using a liquid jet. The setup supports Small and Wide Angle X-ray Scattering (SAXS/WAXS) geometries. The jet is formed by a gas-dynamic virtual nozzle (GDVN) allowing for diameters ranging between 1 μ m and 20 μ m at a jet length of several hundred μ m. To control jet properties such as jet length, diameter, or flow rate, the instrument is equipped with several diagnostic tools. Three microscopes are installed to quantify jet dimensions and stability in situ . The setup has been used at several beamlines performing both SAXS and WAXS experiments. As a typical example we show an experiment on a colloidal dispersion in a liquid jet at the X-ray Correlation Spectroscopy instrument at the Linac Coherent Light Source free-electron laser.

Description: The Carboniferous Bowland Shale of northern England has drawn considerable attention because it has been estimated to have 1329 trillion cubic feet hydrocarbons in-place (gas and liquids) resource potential (Andrews 2013). Here we report on the oil and gas generation characteristics of three selected Bowland Shale whole-rock samples taken from cores and their respective kerogen concentrates. Compositional kinetics and phase properties of the primary and secondary fluids were calculated through the PhaseKinetics and GOR-Fit approaches and PVT modelling software. The three Bowland Shale samples contain immature, marine type II kerogen. Pyrolysate compositions imply primary generation of paraffinic–naphthenic–aromatic (PNA) oil with low contents of wax and sulphur. Bulk kinetic parameters have many similarities to those of productive American Palaeozoic marine shale plays. The secondary gas generation potential of Bowland Shale is greater than the primary gas potential although it requires a 10 kcal mol –1 higher activation energy to achieve peak production. Primary oil, primary gas and secondary gas reach their maximum generation at 137, 150 and 200°C respectively for a 3°C Ma –1 heating rate. Different driving forces of expulsion including the generation of hydrocarbon and overpressure caused by phase separation during sequential periods of subsidence and uplift could be inferred.

Description: 〈span〉〈div〉Abstract〈/div〉At the 2015 United Nations international climate change conference in Paris (COP21), 197 national parties committed to limit global warming to well below 2°C. But current plans and pace of progress are still far from sufficient to achieve this objective. Here we review the role that geoscience and the subsurface could play in decarbonising electricity production, industry, transport, and heating, to meet UK and international climate change targets, based on contributions to the 2019 Bryan Lovell meeting held at the Geological Society of London. Technologies discussed at the meeting involved decarbonisation of electricity production via renewable sources of power generation, substitution of domestic heating using geothermal energy, use of carbon capture and storage (CCS), and more ambitious technologies such as bioenergy and carbon capture and storage (BECCS) that target negative emissions. It was noted also that growth in renewable energy supply will lead to increased demand for geological materials to sustain the electrification of the vehicle fleet and other low-carbon technologies. The overall conclusion reached at the 2019 Bryan Lovell meeting was that geoscience is critical to decarbonisation, but that the geoscience community must influence decision makers so that the value of the subsurface to decarbonisation is understood.〈/span〉

Description: 〈p〉This review of the role of the mantle lithosphere in plate tectonic processes collates a wide range of recent studies from seismology and numerical modelling. A continually growing catalogue of deep geophysical imaging has illuminated the mantle lithosphere and generated new interpretations of how the lithosphere evolves. We review current ideas about the role of continental mantle lithosphere in plate tectonic processes. Evidence seems to be growing that scarring in the continental mantle lithosphere is ubiquitous, which implies a reassessment of the widely held view that it is the inheritance of crustal structure only (rather than the lithosphere as a whole) that is most important in the conventional theory of plate tectonics (e.g. the Wilson cycle). Recent studies have interpreted mantle lithosphere heterogeneities to be pre-existing structures and, as such, linked to the Wilson cycle and inheritance. We consider the current fundamental questions in the role of the mantle lithosphere in causing tectonic deformation, reviewing recent results and highlighting the potential of the deep lithosphere in infiltrating every aspect of plate tectonics processes.〈/p〉

Description: The Carboniferous Bowland Shale of northern England has drawn considerable attention because it has been estimated to have 1329 trillion cubic feet hydrocarbons in-place (gas and liquids) resource potential (Andrews 2013). Here we report on the oil and gas generation characteristics of three selected Bowland Shale whole-rock samples taken from cores and their respective kerogen concentrates. Compositional kinetics and phase properties of the primary and secondary fluids were calculated through the PhaseKinetics and GOR-Fit approaches and PVT modelling software. The three Bowland Shale samples contain immature, marine type II kerogen. Pyrolysate compositions imply primary generation of paraffinic–naphthenic–aromatic (PNA) oil with low contents of wax and sulphur. Bulk kinetic parameters have many similarities to those of productive American Palaeozoic marine shale plays. The secondary gas generation potential of Bowland Shale is greater than the primary gas potential although it requires a 10 kcal mol –1 higher activation energy to achieve peak production. Primary oil, primary gas and secondary gas reach their maximum generation at 137, 150 and 200°C respectively for a 3°C Ma –1 heating rate. Different driving forces of expulsion including the generation of hydrocarbon and overpressure caused by phase separation during sequential periods of subsidence and uplift could be inferred.

Description: Murray's law states that the volumetric flow rate is proportional to the cube of the radius in a cylindrical channel optimized to require the minimum work to drive and maintain the fluid. However, application of this principle to the biomimetic design of micro/nano fabricated networks requires optimization of channels with arbitrary cross-sectional shape (not just circular) and smaller than is valid for Murray's original assumptions. We present a generalized law for symmetric branching that (a) is valid for any cross-sectional shape, providing that the shape is constant through the network; (b) is valid for slip flow and plug flow occurring at very small scales; and (c) is valid for networks with a constant depth, which is often a requirement for lab-on-a-chip fabrication procedures. By considering limits of the generalized law, we show that the optimum daughter-parent area ratio Γ, for symmetric branching into N daughter channels of any constant cross-sectional shape, is Γ = N − 2 / 3 for large-scale channels, and Γ = N − 4 / 5 for channels with a characteristic length scale much smaller than the slip length. Our analytical results are verified by comparison with a numerical optimization of a two-level network model based on flow rate data obtained from a variety of sources, including Navier-Stokes slip calculations, kinetic theory data, and stochastic particle simulations.

Description: 〈span〉〈div〉Abstract〈/div〉Elevated topography is evident across the continental margins of the Atlantic. The Cumberland Peninsula, Baffin Island, formed as the result of rifting along the Labrador-Baffin margins in the late Mesozoic and is dominated by low relief high elevation topography. Apatite fission track (AFT) analysis of the landscape previously concluded that the area has experienced a differential protracted cooling regime since the Devonian; however, defined periods of cooling and the direct causes of exhumation were unresolved. This work combines the original AFT data with 98 apatite new (U-Th)/He ages from 16 samples and applies the newly developed ‘broken crystals’ technique to provide a greater number of thermal constraints for thermal history modelling to better constrain the topographic evolution. The spatial distribution of AFT and AHe ages implies exhumation has been significant toward the SE (Labrador) coastline, while results of thermal modelling outline three notable periods of cooling in the pre-rift (460 Ma – 200 Ma), from syn-rift to present (120 Ma – 0 Ma) and within post-rift (30 Ma – 0 Ma) stages. Pre-rift cooling is interpreted as the result of exhumation of Laurentia, syn-rift cooling as the result of rift flank uplift to the SE and differential erosion of landscape, while the final post-rift period is likely an artefact of the modelling process. These results suggest the source of the Cumberland Peninsula's modern-day elevated topography is uplift during rifting in the Cretaceous and the isostatic compensation following continuous Mesozoic and Cenozoic differential erosion. This work highlights the how interaction of rift tectonics and isostasy can be the principal source for modern elevated continental margins, while also providing insight into the pre-rift exhumational history of central Laurentia.〈strong〉Supplementary material:〈/strong〉〈a href="https://doi.org/10.6084/m9.figshare.c.4528409"〉https://doi.org/10.6084/m9.figshare.c.4528409〈/a〉〈/span〉