ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
Filter
  • Meteorology and Climatology  (10)
  • Polymer and Materials Science  (4)
  • Caribbean  (3)
  • 2015-2019  (13)
  • 1965-1969  (4)
  • 1
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The ESR spectra of microcrystalline cellulose and purified cotton cellulose reacted with ceric ammonium nitrate in nitric acid were determined. The effects of the concentration of ceric ion, atmosphere, temperature, and graft copolymerization with acrylonitrile on the rates of formation and decay of radicals in the cellulose molecule were determined under both static and dynamic conditions. Under static conditions, after the desired conditions of reaction, the samples were frozen at -100 or -160°C., and then the concentration of free radicals was determined. Under dynamic conditions ceric ion solution was continuously flowed through the celluloses while these determinations were being made at 25°C. In the presence of oxygen the rate of decay of free radicals was decreased. On initiation of copolymerization reactions with acrylonitrile, there was an increase in radical concentration, then a decrease. Apparently, during graft copolymerization the radical site initially on the cellulose molecule was retained on the end of the growing polymer chain. Then additional ceric ion coordinated with the hydroxyl groups of the cellulose, leading to the formation of additional radical sites. An Arrhenius interpretation of the effect of temperature on the formation of these additional radical sites gave apparent activation energies for radical formation on cotton cellulose as 34 kcal./mole and on microcrystalline cellulose as 29 kcal./mole.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 12 (1968), S. 249-265 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The ESR spectra of complexes of fibrous cotton cellulose and cupriammonia dihydroxide or cupriethylene diamine dihydroxide under various experimental conditions were determined. The spectra of both complexes with cotton cellulose were almost identical at -100 and 25°C. The spectrum of the complex of cupriethylene diamine dihydroxide with cellulose was stable to temperatures as high as 100°C. The sum of the linewidths of the hyperfine components of the spectra for each complex was about 180 gauss. Cotton fibers were combed and aligned with their axes (lengths) parallel to the magnetic field (B∥); after formation of either of the complexes with cellulose a minumum of hyperfine structure of components centered at H∥ was observed. A maximum of hyperfine structure of these components was observed when the complexed fibers were aligned with their axes perpendicular to the magnetic field (B⊥). The opposite was true of components centered at H⊥. For a complex of cupriethylene diamine dihydroxide and cellulose at 25°C. and at high pH the g∥ was 2.2127 and the g∥ was 2.0476. It was suggested that the alignment of most of the complex was its axis of symmetry at a maximum angle to the axes of the cotton fiber, when the axes of the fibers were in the parallel alignment with the magnetic field. At high pH these observations were even more marked. When ramie was used with cupriethylene diamine dihydroxide at high pH, the contribution of components centered at H∥ to the spectra was zero. Spectra for the copper compounds alone and complexed with cellobiose are also reported.
    Zusätzliches Material: 16 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 11 (1967), S. 1139-1153 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: An ESR study of the free-radical mechanisms of the post-irradiation reactions of cotton cellulose with acrylonitrile is reported. The effects of atmosphere, moisture content, and solutions of acrylonitrile on the yield and stability of free-radical sites in irradiated cellulose were determined. On interaction of γ-radiation from a 60Co source with cotton cellulose, long-lived free-radical sites were found within the molecular lattice. Short-lived free-radical sites were apparently also formed on chain cleavage, gave strong singlet spectra, and were readily accessible to interaction with water. Other free-radical sites were formed within regions of the cellulosic fiber which were inaccessible to moisture or aqueous solutions even after contact times as long as three days. It was suggested that long-lived free-radical sites in cellulose I (containing regain moisture) resulted from dehydrogenation at C5, and in cellulose II (containing regain moisture) resulted from dehydrogenation at C5 and dehydrogenation of the OH group or dehydroxylation at C6. When irradiated cellulose was contacted with a solution of acrylonitrile (15%) in 75% aqueous zinc chloride, the initial rate of decrease in spin concentration was higher than the rate of decrease as the time of contact increased. The ESR spectrum of the reacted cellulose, observed at -100°C., as compared with the spectrum for the irradiated cellulose, had decreased in signal strength with increase in time of contact and changed from a three-line spectrum to an ill-defined spectrum. The free radical being observed was probably due to unreacted sites in the cellulose. The extent of the graft copolymerization reaction was directly related to the initial spin concentration in the irradiated cellulose.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 4
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 3 (1965), S. 411-413 
    ISSN: 0449-2951
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 5
    facet.materialart.
    Unbekannt
    Biological and Chemical Oceanography Data Management Office (BCO-DMO). Contact: bco-dmo-data@whoi.edu
    Publikationsdatum: 2022-10-31
    Beschreibung: Dataset: yawzi point and tektite
    Beschreibung: These files contain data that support an analysis of the effects of two major hurricanes on coral reefs that have been extensively studied for more than three decades. Major tropical storms are destructive phenomena with large effects on the community dynamics of multiple biomes. On coral reefs, their impacts have been described for decades, leading to the expectation that future storms should have effects similar to those recorded in the past. This expectation relies on the assumption that storm intensities will remain unchanged, and the impacted coral reef communities are similar to those of the recent past; neither assumption is correct. These data support a study quantifying the effects of two category five hurricanes on the reefs of St. John, US Virgin Islands, where 31 y of time-series analyses reveal chronic coral mortality, increasing macroalgal abundance, and five major hurricanes that caused acute coral mortality. Contextualized by these trends, the effects of the most recent storms, Hurricanes Irma and Maria (September 2017), on coral cover were modest. While mean absolute coral cover declined 1–4% depending on site, these effects were not statistically discernable. Following decades of increasing abundance of macroalgae, this functional group responded to the recent hurricanes with large increases in abundance on both absolute and relative scales. Decades of chronic mortality have changed the coral assemblages of St. John to create degraded communities that are resistant to severe storms. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/750060
    Beschreibung: National Science Foundation (NSF) DEB-0841441, National Science Foundation (NSF) DEB-0343570, NSF Division of Environmental Biology (NSF DEB) DEB-1350146, NSF Division of Ocean Sciences (NSF OCE) OCE-1801335
    Schlagwort(e): Coral ; Caribbean ; Coral reef ; LTREB ; Hurricanes
    Repository-Name: Woods Hole Open Access Server
    Materialart: Dataset
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 6
    facet.materialart.
    Unbekannt
    Biological and Chemical Oceanography Data Management Office (BCO-DMO). Contact: bco-dmo-data@whoi.edu
    Publikationsdatum: 2022-10-31
    Beschreibung: Dataset: accessory transects
    Beschreibung: These files contain data that support an analysis of the effects of two major hurricanes on coral reefs that have been extensively studied for more than three decades. Major tropical storms are destructive phenomena with large effects on the community dynamics of multiple biomes. On coral reefs, their impacts have been described for decades, leading to the expectation that future storms should have effects similar to those recorded in the past. This expectation relies on the assumption that storm intensities will remain unchanged, and the impacted coral reef communities are similar to those of the recent past; neither assumption is correct. These data support a study quantifying the effects of two category five hurricanes on the reefs of St. John, US Virgin Islands, where 31 y of time-series analyses reveal chronic coral mortality, increasing macroalgal abundance, and five major hurricanes that caused acute coral mortality. Contextualized by these trends, the effects of the most recent storms, Hurricanes Irma and Maria (September 2017), on coral cover were modest. While mean absolute coral cover declined 1–4% depending on site, these effects were not statistically discernable. Following decades of increasing abundance of macroalgae, this functional group responded to the recent hurricanes with large increases in abundance on both absolute and relative scales. Decades of chronic mortality have changed the coral assemblages of St. John to create degraded communities that are resistant to severe storms. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/750265
    Beschreibung: National Science Foundation (NSF) DEB-0841441, National Science Foundation (NSF) DEB-0343570, NSF Division of Environmental Biology (NSF DEB) DEB-1350146, NSF Division of Ocean Sciences (NSF OCE) OCE-1801335
    Schlagwort(e): Coral ; Caribbean ; Coral reef ; LTREB ; Hurricanes
    Repository-Name: Woods Hole Open Access Server
    Materialart: Dataset
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 7
    facet.materialart.
    Unbekannt
    Biological and Chemical Oceanography Data Management Office (BCO-DMO). Contact: bco-dmo-data@whoi.edu
    Publikationsdatum: 2022-10-31
    Beschreibung: Dataset: pooled random sites (PRS)
    Beschreibung: These files contain data that support an analysis of the effects of two major hurricanes on coral reefs that have been extensively studied for more than three decades. Major tropical storms are destructive phenomena with large effects on the community dynamics of multiple biomes. On coral reefs, their impacts have been described for decades, leading to the expectation that future storms should have effects similar to those recorded in the past. This expectation relies on the assumption that storm intensities will remain unchanged, and the impacted coral reef communities are similar to those of the recent past; neither assumption is correct. These data support a study quantifying the effects of two category five hurricanes on the reefs of St. John, US Virgin Islands, where 31 y of time-series analyses reveal chronic coral mortality, increasing macroalgal abundance, and five major hurricanes that caused acute coral mortality. Contextualized by these trends, the effects of the most recent storms, Hurricanes Irma and Maria (September 2017), on coral cover were modest. While mean absolute coral cover declined 1–4% depending on site, these effects were not statistically discernable. Following decades of increasing abundance of macroalgae, this functional group responded to the recent hurricanes with large increases in abundance on both absolute and relative scales. Decades of chronic mortality have changed the coral assemblages of St. John to create degraded communities that are resistant to severe storms. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/750092
    Beschreibung: National Science Foundation (NSF) DEB-0841441, National Science Foundation (NSF) DEB-0343570, NSF Division of Environmental Biology (NSF DEB) DEB-1350146, NSF Division of Ocean Sciences (NSF OCE) OCE-1801335
    Schlagwort(e): Coral ; Caribbean ; Coral reef ; LTREB ; Hurricanes
    Repository-Name: Woods Hole Open Access Server
    Materialart: Dataset
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 8
    Publikationsdatum: 2019-07-13
    Beschreibung: The GOES-R flight project has developed the Image Navigation and Registration (INR) Performance Assessment Tool Set (IPATS) to perform independent INR evaluations of the optical instruments on the GOES-R series spacecraft. In this paper, we document the development of navigation (NAV) evaluation capabilities within IPATS for the Geostationary Lightning Mapper (GLM). We also discuss the post-processing quality filtering developed for GLM NAV, and present example results for several GLM datasets. Initial results suggest that GOES-16 GLM is compliant with navigation requirements.
    Schlagwort(e): Meteorology and Climatology
    Materialart: GSFC-E-DAA-TN59289 , 2018 EUMETSAT Meteorological Satellite Conference; Sep 17, 2018 - Sep 21, 2018; Tallinn; Estonia
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 9
    Publikationsdatum: 2019-07-13
    Beschreibung: The GOES-R flight project has developed the Image Navigation and Registration (INR) Performance Assessment Tool Set (IPATS) to perform independent INR evaluations of the optical instruments on the GOES-R series spacecraft. In this presentation, we document the development of navigation (NAV) evaluation capabilities within IPATS for the Geostationary Lightning Mapper (GLM). We also discuss the post-processing quality filtering developed for GLM NAV, and present example results for several GLM background image datasets. Initial results suggest that GOES-16 GLM is compliant with navigation requirements.
    Schlagwort(e): Meteorology and Climatology
    Materialart: GSFC-E-DAA-TN58945 , EUMETSAT Meteorological Satellite Conference 2018; Sep 17, 2018 - Sep 21, 2018; Tallinn; Estonia
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 10
    Publikationsdatum: 2019-07-13
    Beschreibung: Earth system models are complex and represent a large number of processes, resulting in a persistent spread across climate projections for a given future scenario. Owing to different model performances against observations and the lack of independence among models, there is now evidence that giving equal weight to each available model projection is suboptimal. This Perspective discusses newly developed tools that facilitate a more rapid and comprehensive evaluation of model simulations with observations, process-based emergent constraints that are a promising way to focus evaluation on the observations most relevant to climate projections, and advanced methods for model weighting. These approaches are needed to distil the most credible information on regional climate changes, impacts, and risks for stakeholders and policy-makers.
    Schlagwort(e): Meteorology and Climatology
    Materialart: GSFC-E-DAA-TN65080 , Nature Climate Change (ISSN 1758-678X) (e-ISSN 1758-6798); 9; 102-110
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...