ISSN:
1572-8927
Keywords:
Conductance
;
divalent salts
;
H2O
;
D2O
;
ionic association
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Precise conductance measurements are reported for potassiumm-benzenedisulfonate and ferricyanide, for calcium, strontium, barium, and manganese chloride, and for manganese and potassium sulfate in D2O at 25°C. Measurements were also carried out in water at 10 and 25°C for all the salts with the exception of K3Fe(CN)6 at 10°C. Two runs are reported for sodium sulfate in water at 25°C. Limiting conductances of these ions are discussed in terms of solvent structural effects. The association constant for MnSO4 is found to be the same in H2O and D2O.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00955708
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