Publication Date:
2015-08-12
Description:
Article Understanding the catalytic mechanism of redox-active hydrogenases is a key to efficient hydrogen production and consumption. Here, the authors use nuclear resonance vibrational spectroscopy to study [NiFe]-hydrogenase, and observe a bridging hydride structure in an EPR silent intermediate. Nature Communications doi: 10.1038/ncomms8890 Authors: Hideaki Ogata, Tobias Krämer, Hongxin Wang, David Schilter, Vladimir Pelmenschikov, Maurice van Gastel, Frank Neese, Thomas B. Rauchfuss, Leland B. Gee, Aubrey D. Scott, Yoshitaka Yoda, Yoshihito Tanaka, Wolfgang Lubitz, Stephen P. Cramer
Electronic ISSN:
2041-1723
Topics:
Biology
,
Chemistry and Pharmacology
,
Natural Sciences in General
,
Physics
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