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  • Chemistry  (25)
  • Analytical Chemistry and Spectroscopy  (3)
  • Nuclear Reactions  (3)
  • 2015-2019  (3)
  • 1975-1979  (25)
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 21 (1977), S. 3291-3309 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: By use of a mod with a film gate, two straight polypropylenes (PP) with different melt flow index (MFI) and a glass fiber-reinforced polypropylene (FRPP) were injection molded at various molded at various temperatures into square plates with orientational anisotropy. The anisotropies of tensile property, tensile impact strength, and flexural property were studied on the molded sample cut mainly in the machine direction (MD), 45°-direction (45°), and transverse direction (TD). Both the orders of the yield strength and tensile impact strength of the FRPP, and those of the necking stress and tensile impact strength of the straight PP, were MD 〉45° 〉TD, which are reasonable tendencies. The orders of the yield strength and flexural modulus of the straight PP were MD 〉 TD 〉 45°, which suggests the presence of shear deformation between the lamellae in the skin layer. The variation of the flexural modulus with the angle to the MD fitted well to Hearmon's equation. Generally, for straight PP, the anisotropy of various properties increased as the MFI and cylinder temperature became lower, or as the skin layer became thicker. For the FRPP, the anisotropy increased as the cylinder temperature became higher, or as the degree of the orientation of glass fibers became higher.
    Additional Material: 19 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 1225-1241 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of some molecular parameters on the mold shrinkage, annealing shrinkage, and melting shrinkage of injection-molded polypropylene was studied. The mold shrinkage in the machine direction (MD) became higher as the melt flow index (MFI) became lower and the molecular weight distribution became broader. On the other hand, the mold shrinkage in the transverse direction (TD) showed a similar value (about 1.6%), regardless of the kind of resin, except for a glass fiberreinforced polypropylene which showed a very low value. The annealing shrinkage and melting shrinkage showed similar tendencies as the modl shrinkage. The mold shrinkage and annealing shrinkage in the MD were in linear relationships with the thickness of the skin layer having positive slopes; the melting shrinkage in the MD was in a downward-curved relationship with the thickness of the skin layer having a positive slope, respectively, regardless of the cylinder temperature and the kind of resin.
    Additional Material: 17 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 615-622 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Characteristics of the gel layer were investigated by direct measurement of its concentration treating polyvinylalcohol and ovalbumin aqueous solutions, using cellulose acetate tubular ultrafiltration membranes. The concentration of the gel layer was not constant but a function of bulk concentration and feed velocity. The mass transfer coefficient obtained agreed with Deissler correlation. There was a definite correlation between the resistance of the gel layer and its concentration.
    Additional Material: 13 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 21 (1977), S. 2283-2288 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 7 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 563-569 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermal oxidation of fractionated polypropylene was carried out in trichlorobenzene under atmospheric oxygen at 125°C with conventional oxygen uptake. The oxidizability of the polymers is discussed on the basis of the oxygen uptake curves and the properties of the polymers. Fractions of atactic polypropylene oxidized easily at the initial stage of the oxidation and showed neither autoxidation phenomena nor the induction period observed in the isotactic polymer. Hydrogenation of the ether-soluble fraction by a Wilkinson catalyst gave a polymer which was, according to infrared spectrometry, free from impurity groups such as hydroperoxide, carbonyl, and unsaturation groups. The hydrogenated fraction was more stable to thermal oxidation than the unhydrogenated fraction and showed an induction period. The results indicate that the initiation process of the oxidation of polypropylene is apparently dependent on the impurities such as hydroperoxide, carbonyl, and unsaturation and that stereoregularity of the polymer affects the kinetic dependence of the oxidation.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 24 (1979), S. 923-930 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The stress relaxation of oriented and dried nylon 6 fibers was measured at temperatures ranging from room temperature to 423 K using a simple tensile method. After the reduction for temperature and crystallinity by Nagamatsu et al.'s procedure,2 the relaxation modulus curves were shifted along a time axis, and master curves were obtained. The Arrhenius plots of shift factor was represented by two straight lines having a break point, the temperature of which was in approximate agreement with those of the breakdown of hydrogen bonds in the amorphous region. The relationship between the breakdown of hydrogen bonds and the values of apparent activation energies for relaxation is discussed. It was found that the effects of hydrogen bonds on the relaxation behavior are similar to those of crosslinking points in crosslinked polymers. Moreover, from the constants C1 and C2 of the WLF equation, the free volume fraction at Tg(fg) and the expansion coefficient of free volume at Tg(fg) were estimated to be 0.013 and 4.2 × 10-5, respectively. Finally, through the use of the usual primary approximation method, the relaxation time spectra were obtained from the relaxation master curves. The obtained spectra showed two distributions of wedge type and box type. When the draw ratio increases, the height of distribution of the box type becomes higher and its position shifts to a longer time side, whereas those of the wedge type remain virtually unchanged.
    Additional Material: 7 Ill.
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  • 7
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die radikalisch durch verschiedene α,ω-Diaminoalkan-Kupfer(II)-Komplexe initiierte Polymerisation von Acrylnitril wurde in Dimethylsulfoxidlösung untersucht. Es ergab sich, daß stabile Komplexe, wie der Äthylendiamin-Kupfer(II)-Komplex, die Polymerisation fast nicht auslösen, während die instabilen Komplexe von 1,5-Diaminopentan, 1,6-Diaminohexan und n-Butylamin die Polymerisation gut auslösen konnten.Die Polymerisationsauslösung wurde ferner spektrophotometrisch untersucht. Die Reduktion der Kupfer(II)-Komplexe zu Kupfer(I)-Komplexen während der Polymerisation wurde durch sichtbare Spektroskopie sowie die Kuproin-Färbungsmethode bestätigt. Die Reduktionsgeschwindigkeit steht eng mit der Stabilität der Diamin-Kupfer(II)-Komplexe in Beziehung. Aus den Ergebnissen wird der Initiierungsmechanismus diskutiert.
    Notes: Free radical polymerization of acrylonitrile initiated by various α,ω-diaminoalkane-copper(II) complexes was studied in dimethyl sulfoxide solution. It was found that the stable copper(II) complexes, like ethylenediamine copper(II) complex, could hardly initiate the polymerization, while the unstable copper(II) complexes, such as 1,5-diaminopentane, 1,6-diaminohexane and n-butylamine complexes could initiate the polymerization.Initiation was further studied spectrophotometrically. Reduction of the copper(II) to the copper(I) complexes was ascertained to occur during the polymerization by visible spectroscopy and cuproin coloration method. The rate of reduction was related closely to the stability of the diamine-copper(II) complexes. From the results the initiation mechanism was discussed.
    Additional Material: 10 Ill.
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  • 8
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die durch Kupfer(II)-chelate von Polyvinylamin, Polyvinylacetamid und Vinylamin-Vinylacetamid-Copolymeren initiierte Polymerisation von Acrylnitril wurde in Dimethylsulfoxidlösung untersucht. Es ergab sich, daß die Kupfer(II)-chelate der Vinylamin-Vinylacetamid-Copolymeren die Polymerisation von Acrylnitril sogar in Abwesenheit von Tetrachlorkohlenstoff glatt auslösen können, während die Kupfer(II)-chelate von Polyvinylamin und Polyvinylacetamid die Polymerisation erst in Anwesenheit von Tetrachlorkohlenst off auslösen. Die Polymerisationsaktivität scheint in Beziehung mit der Stabilität dieser Copolymer-Kupfer(II)-chelate zu stehen. Aus den Ergebnissen der Polymerisation und sichtbarer Spektroskopie wurde der Auslösungsmechanismus diskutiert.
    Notes: The polymerization of acrylonitrile initiated by copper(II) chelates of polyvinylamine, polyvinylacetamide and vinylamine-vinylacetamide copolymers was studied in dimethyl sulfoxide solution. The copper(II) chelates of vinylamine-vinylacetamide copolymers were found to initiate the polymerization of acrylonitrile effectively, even in the absence of carbon tetrachloride, while those of polyvinylamine and polyvinylacetamide initiate only in the presence of carbon tetrachloride. The polymerization activity was assumed to be closely related to the stability of these copolymer-copper(II) chelates. From the results of the polymerization and the visible spectroscopy, an initiation mechanism is discussed.
    Additional Material: 9 Ill.
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  • 9
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die durch Polyvinylamin-Kupfer(II)chelat initiierte Polymerisation von Acrylnitril und Methylmethacrylat wurde in Dimethylsulfoxidlösung in Gegenwart sowie Abwesenheit von Tetrachlorkohlenstoff untersucht. Zum Vergleich damit wurde auch ein dimeres Chelat, d. h., 1,3-Diaminopropan-Kupfer(II)chelat als Starter gewählt. Es ergab sich, daß die Startfähigkeit dieses dimeren Chelats in Dimethylsulfoxid im Gegensatz zu derjenigen in Wasser höher als die des polymeren Chelats war. Das dimere Kupferchelat konnte die Polymerisation von Acrylnitril sogar in Abwesenheit von Tetrachlorkohlenstoff auslösen.
    Notes: The polymerization of acrylonitrile and methyl methacrylate initiated by polyvinylamine-copper(II) chelate was studied in dimethylsulfoxide solution, in the presence and absence of carbon tetrachloride. For comparison, the dimeric chelate(1,3-diaminopropane-copper(II) chelate) was also chosen as an initiator. The initiation activity of the dimeric chelate was found to be higher than that of the polymeric chelate in dimethylsulfoxide solution, different from the cases in aqueous media. The dimeric chelate could initiate the polymerization of acrylonitrile effectively, even in the absence of carbon tetrachloride.
    Additional Material: 8 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 176 (1975), S. 3425-3431 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Verdünnungsenthalpien für Poly(1-vinyl-2-pyrrolidon), (Poly[1-(2-oxopyrrolidin-1-yl)-ethylene]), in wäßrigen Methanollösungen von unterschiedlichem Methanolgehalt, wurden bei 298 K gemessen. Das Molekulargewicht des Polymeren betrug 10000 bzw. 40000.Die experimentellen Ergebnisse wurden nach einer modifizierten Tompa-Gleichung mit konzentrationsabhängigem Wechselwirkungsparameter analysiert und so der Wechselwirkungsparameter zwischen dem Polymeren und dem Mischlösungsmittel für unendliche Verdünnung erhalten.Der Einfluß von Methanol auf die Wechselwirkung zwischen dem Polymeren und Wasser wurde aufgrund der Änderungen des Wechselwirkungsparameters bei unendlicher Verdünnung für die Überführung des Polymeren von Wasser in wäßriges Methanol diskutiert.
    Notes: Enthalpies of dilution of poly(1-vinyl-2-pyrrolidone), (poly[1-(2-oxopyrrolidin-1-yl)ethylene]), in aqueous methanol solutions of different methanol contents were measured at 298 K. The molecular weight of the polymer was 10000 and 40000, respectively.The experimental results were analysed with a modified Tompa formula containing an interaction parameter dependent on concentration; so the interaction parameter at infinite dilution between the polymer and the mixed solvent was derived.The influence of methanol on the interaction between polymer and water molecules was discussed from the change of the interaction parameter at infinite dilution for the transfer process from water to aqueous methanol solvent.
    Additional Material: 3 Ill.
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