Publication Date:
2020-01-18
Description:
Ni-base superalloys have a long history of use in jet turbine engines, and efforts to improve their performance in that application are ongoing. It is known that the precipitation of the Ni3Al ' phase within the disordered FCC phase strengthens the overall material. However, in the high-temperature environment found inside a turbine engine during operation, creep can cause the ' phase to transform to different, weaker phases along stacking faults, leading to a deterioration of performance. In the ' phase one mode of creep deformation is the formation of stacking fault ribbons, which consist of intrinsic stacking faults further shearing into antiphase boundaries (APBs). It is also known that certain alloying additions exhibit segregation to stacking faults. If segregating elements could be identified which segregate to the intrinsic stacking fault, but not to the APB, the inclusion of such elements could lead to improved creep strength in these alloys. To investigate this possibility, a density functional investigation of the segregation of W, Mo and Cr to both a superlattice intrinsic stacking fault (SISF) and an APB was performed. It was found that W, Mo and Cr all exhibit segregation to the SISF. In contrast, for the APB, Cr was either energy-neutral, or segregates, depending on the presence of additional nearby Cr, or on the specific lattice site upon which it was placed, while Mo and W did not segregate. Because W and Mo segregate to the SISF but not to the APB, the inclusion of these elements could provide a degree of protection against creep-related deterioration.
Keywords:
Metals and Metallic Materials
Type:
GRC-E-DAA-TN75689
,
Materials Research Society Fall Meeting; Dec 01, 2019 - Dec 06, 2019; Boston, MA; United States
Format:
application/pdf
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