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  • Selenium  (1)
  • Wiley-Blackwell  (1)
  • 2015-2019
  • 1980-1984  (1)
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  • 2015-2019
  • 1980-1984  (1)
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    Electronic Resource
    Electronic Resource
    Stabilization of Unusual Oxidation and Coordination States by the Ligands OSF5, OSeF5, and OTeF5 (1982)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 21 (1982), S. 877-888 
    Details
    ISSN: 0570-0833
    Keywords: Coordination modes ; Ligands ; Tellurium ; Fluorine ; Selenium ; Sulfur ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Compounds with the ligands OSF5, OSeF5, and OTeF5 are now known for most of the chemical elements. The ability of these ligands to stabilize the highest valency levels of the central atoms to which they are bound is unsurpassed by any other polyatomic ligand. Examples are Xe(OTeF5)6, Te(OTeF5)6, W(OTeF5)6, and U(OTeF5)6 or I(OTeF5)5 and Br(OSeF5)3. Because of the ligands' size and internal bonding they hardly ever form bridges, and in this respect they differ from fluorine, although they do share the latter's high electronegativity.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.198208773
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