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  • Articles  (315)
  • Wiley  (157)
  • Springer  (137)
  • American Meteorological Society  (21)
  • American Geophysical Union (AGU)
  • 2015-2019  (209)
  • 1985-1989  (106)
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  • 1
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 28 (2015): 8289–8318, doi:10.1175/JCLI-D-14-00555.1.
    Description: This study quantifies mean annual and monthly fluxes of Earth’s water cycle over continents and ocean basins during the first decade of the millennium. To the extent possible, the flux estimates are based on satellite measurements first and data-integrating models second. A careful accounting of uncertainty in the estimates is included. It is applied within a routine that enforces multiple water and energy budget constraints simultaneously in a variational framework in order to produce objectively determined optimized flux estimates. In the majority of cases, the observed annual surface and atmospheric water budgets over the continents and oceans close with much less than 10% residual. Observed residuals and optimized uncertainty estimates are considerably larger for monthly surface and atmospheric water budget closure, often nearing or exceeding 20% in North America, Eurasia, Australia and neighboring islands, and the Arctic and South Atlantic Oceans. The residuals in South America and Africa tend to be smaller, possibly because cold land processes are negligible. Fluxes were poorly observed over the Arctic Ocean, certain seas, Antarctica, and the Australasian and Indonesian islands, leading to reliance on atmospheric analysis estimates. Many of the satellite systems that contributed data have been or will soon be lost or replaced. Models that integrate ground-based and remote observations will be critical for ameliorating gaps and discontinuities in the data records caused by these transitions. Continued development of such models is essential for maximizing the value of the observations. Next-generation observing systems are the best hope for significantly improving global water budget accounting.
    Description: This research was funded by multiple grants from NASA’s Energy and Water Cycle Study (NEWS) program.
    Description: 2016-05-01
    Keywords: Physical Meteorology and Climatology ; Water budget ; Observational techniques and algorithms ; Remote sensing ; Mathematical and statistical techniques ; Numerical analysis/modeling
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 28 (2015): 8319-8346, doi:10.1175/JCLI-D-14-00556.1.
    Description: New objectively balanced observation-based reconstructions of global and continental energy budgets and their seasonal variability are presented that span the golden decade of Earth-observing satellites at the start of the twenty-first century. In the absence of balance constraints, various combinations of modern flux datasets reveal that current estimates of net radiation into Earth’s surface exceed corresponding turbulent heat fluxes by 13–24 W m−2. The largest imbalances occur over oceanic regions where the component algorithms operate independent of closure constraints. Recent uncertainty assessments suggest that these imbalances fall within anticipated error bounds for each dataset, but the systematic nature of required adjustments across different regions confirm the existence of biases in the component fluxes. To reintroduce energy and water cycle closure information lost in the development of independent flux datasets, a variational method is introduced that explicitly accounts for the relative accuracies in all component fluxes. Applying the technique to a 10-yr record of satellite observations yields new energy budget estimates that simultaneously satisfy all energy and water cycle balance constraints. Globally, 180 W m−2 of atmospheric longwave cooling is balanced by 74 W m−2 of shortwave absorption and 106 W m−2 of latent and sensible heat release. At the surface, 106 W m−2 of downwelling radiation is balanced by turbulent heat transfer to within a residual heat flux into the oceans of 0.45 W m−2, consistent with recent observations of changes in ocean heat content. Annual mean energy budgets and their seasonal cycles for each of seven continents and nine ocean basins are also presented.
    Description: This study is the result of a collaboration of multiple investigators each supported by the NEWS program.
    Keywords: Climatology ; Energy budget/balance ; Heat budgets/fluxes ; Radiative fluxes ; Surface fluxes ; Satellite observations
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Agriculture and human values 3 (1986), S. 26-32 
    ISSN: 1572-8366
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
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  • 4
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The hydrogen bond patterns ofo-alkoxybenzoic acids have been shown previously to involve intramolecular hydrogen bonds. In this paper we show thato-methoxybenzoic acid (I) and o-ethoxybenzoic acid (II) both exist as monomers with intramolecular hydrogen bonds in solution but that, in the solid-state,I crystallizes as hydrogen-bonded dimers whileII crystallizes with an intramolecular hydrogen bond. The correlation between solution and solid-state hydrogen bond patterns is made using solution and solid-state IR and NMR methods and by correlating the solid-state patterns with known X-ray crystal structures. The crystal structure ofI is reported here. Crystal data: monoclinicP21/n;a=7.002(2),b=14.945(9),c=7.719(4) Å,β=115.44(3)°,Z=4,V=729.4 Å3, andR=0.046 (1660 reflections).
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Entomologia experimentalis et applicata 47 (1988), S. 167-172 
    ISSN: 1570-7458
    Keywords: feeding behavior ; leaf center or edge feeders ; chemical signals ; trial design ; Plagiodera versicolora ; Populus deltoides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Description / Table of Contents: Résumé Plagiodera versicolora Laich (Coléo., Chrysomelidae) a préféré significativement consommer les grandes rondelles (diamètre 17 mm) de Populus deltoides préalablement exposées à l'ozone ambiant, aux témoins exposés à de l'air filtré sur charbon de bois. Cependant, quand le diamètre a été réduit à 10 mm, les insectes n'ont plus préféré les feuilles soumises à l'ozone. Les préférences alimentaires de cet insecte consommant le centre des feuilles ont probablement changé parceque les signaux chimiques de la coupure ont surpassé ou masqué ceux des petits disques. Ainsi, le rapport périmètre sur surface du disque est un critère important de la procédure expérimentale. L'influence de la taille du disque dépend vraisemblablement du fait que l'insecte consomme le centre ou la pourtour de la feuille, de la taille de l'insecte et du type d'expérience. Nous en avons déduit que l'effet de la taille du disque est fréquent particulièrement chez les insectes consommant le centre des feuilles. Les modificatons du choix des insectes lorsque les plantes avaient été présentées sous forme de rondelles au lieu de feuilles ou plantes entières, peuvent être expliqués aussi par le changement des signaux provoqué par le découpage des rondelles, plutôt que par l'induction de modifications chimiques dues à la cueillette, comme cela a été précédemment indiqué par différents auteurs. Par ailleurs, dans les conditions naturelles, des changements dans les signaux chimiques des feuilles dus à une consommation antérieure par des insectes, peuvent être aussi importants dans le comportement alimentaire des insectes que n'importe quel changement chimique induit dans les feuilles par les dégâts.
    Notes: Abstract The size of cottonwood (Populus deltoides L. Bartr.) leaf discs used in insect feeding preference trials with the chrysomelid beetle, Plagiodera versicoloraLaich., was shown to affect behavior, and the outcome of the feeding trial. It is suggested that disc size has an effect because it alters the ratio of chemical signals from the cut leaf edge to those of the intact leaf center. The implications of this finding to the design of bioassays; to previously noted differences in feeding behavior for insects on discs versus leaves; and to the study of feeding preference and induction of plant defense are discussed.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of environmental contamination and toxicology 36 (1986), S. 548-555 
    ISSN: 1432-0800
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Microchimica acta 94 (1988), S. 441-444 
    ISSN: 1436-5073
    Keywords: infrared ; reflection ; silicon dioxide ; silicon
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract We report the FTIR spectra as a function of incident angle and polarization of a 307 Å layer of silicon dioxide on silicon substrate. Bands normally obscured in transmission spectra are revealed and can dominate the reflection spectra at incident angles away from normal. Strong band distortions were observed as the incident angle and polarization were varied. Our experimental results are in excellent agreement with calculations based on published optical constants. Thus, quantitative interpretations of IR spectra of silicon dioxide on silicon should be made with caution.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1436-5073
    Keywords: interferometry ; radiometry ; near millimetre wavelengths
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A near millimetre wavelength radiometer has been constructed, based on a rapid scan polarising interferometer. The design and procedure are described, and some results are presented.
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  • 9
    ISSN: 1432-0703
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Abstract Urine samples from 197 Arkansas children were analyzed for eight chlorinated phenols and four chlorinated phenoxy herbicides by using a new procedure that combined gas chromatography with tandem mass spectrometry. With the detection limit of 1 part per billion (ppb), six of these pesticides were detected in more than 10% of the samples. 2,5-Dichlorophenol (a metabolite ofp-dichlorobenzene), and pentachlorophenol were detected in 96% and 100%, respectively, of the children's urine at median concentrations of 9 ppb and 14 ppb, respectively. 2,4,5-Trichlorophenol was detected in 54% of the children's urine at a median concentration of 1 ppb. One trichlorophenol and three other dichlorophenols were found in 3% to 27% of the samples. The herbicide 2,4-dichlorophenoxyacetic acid was observed in 20% of all samples. The concentrations of all analytes are reported as background or reference levels for use in future studies. The finding of 2,5-dichlorophenol as a ubiquitous contaminant merits further study.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Physics and chemistry of minerals 13 (1986), S. 411-414 
    ISSN: 1432-2021
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract Beckerite, a minor component of the amber fossil resins of northern Europe, has previously been classified as being mineralogically distinct from common Baltic amber or succinite on the basis of physical properties such as density and chemical properties such as saponification number. We show that beckerite and succinite are spectroscopically identical, according to infrared and carbon-13 nuclear magnetic resonance methods. Following the suggestion of Schubert, we attribute the deviations of beckerite to the presence of low levels of contaminants, such as decomposed wood and insect excrement.
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