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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 16 (1987), S. 985-997 
    ISSN: 1572-8927
    Keywords: Aqueous solution ; cell constant ; conductance ; electrolytic conductivity ; potassium chloride ; primary ; resistance ; resistivity, secondary, standards, and temperature scale
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Measurements of aqueous electrolytic conductance are performed routinely in a variety of disciplines and industries. Conductivity is a measure of the ionic content in solution and thus has applications in pharmaceuticals, power plants, rainwater, lake surveys, and oceanography, to name a few. A thorough review of the measurement of and standards for aqueous electrolytic conductance is herein presented. At present, the most precise and accurate standards have been set forth by the International Organization of Legal Metrology (OIML), and have been adopted by most other standards organizations. However, the uncertainty assigned to these standards, especially the secondary standards, is somewhat larger than would be expected from the physical aspects of the measurement. Several changes in the units and measurement scales, including temperature, volume, molar mass, resistance, and concentration obfuscate the accuracy of these standards. In addition to the review, research is proposed, using a conductance cell with variable length, to establish new standards for aqueous electrolytic conductance.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 18 (1989), S. 515-528 
    ISSN: 1572-8927
    Keywords: Absolute standard ; conductivity cell ; demal ; electrolyte ; molality ; potassium chloride ; primary standard ; specific conductance
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A determination of the absolute specific conductance of KCl solutions is demonstrated. The measurement is based on the conductance cell with a well defined geometry, having a difference in the removable center tube of accurately measured dimensions. The specific conductance of the solution is obtained from the measured resistances of the cell with and without the center tube and the measured l/A ratio of the center tube. Specific conductances obtained using the cell agree with the previously accepted standards for 0.1 demal and 0.01 demal solutions within 0.02%. Results are also presented for solutions based on molality. The temperature control, bridge, and detector technology used to obtain results of this accuracy are described.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 15 (1986), S. 675-692 
    ISSN: 1572-8927
    Keywords: Deuterium chloride ; deuterium oxide ; electrochemical cell ; emf ; enthalpy ; entropy ; free energy ; heat capacity ; isotope effect ; standard potential ; thermodynamics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The themodynamic properties of solutions of deuterium chloride (DCl) in deuterium oxide (D2O) have been determined from emf measurements of the electrochemical cell without transference from 5 to 50°C, and from 0.002 to 1.0 mol-kg−1. The standard potential of the silver/silver chloride electrode relative to the platinum/deuterium electrode has been determined. An equation for the Gibbs energy as a function of temperature has been derived from which the enthalpy, entropy, and heat capacity have been computed. Equations for the activity coefficient and the osmotic coefficient of DCl in D2O have been developed. The excess Gibbs energy of the solution and the excess partial molar free energy as a function of temperature have been calculated, from which the other excess thermodynamic properties have been computed. The values for the heat capacity and the apparent molar heat capacity have been compared with calorimetric data in the literature. The relative partial molar enthalpy has been calculated. The solvent isotope effect on the excess thermodynamic functions is discussed.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 113 (1938), S. 356-356 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Acta mechanica 59 (1986), S. 11-29 
    ISSN: 1619-6937
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary This paper deals with possible modal degeneracies between spatial Orr-Sommerfeld model in plane Poiseuille and boundary-layer type mean flows. In analogy to the Benney-Gustavsson resonance mechanism exact modal coalescences can be observed for three-dimensional disturbances. At these direct resonances linear theory implies a locally algebraic growth and the corresponding potentially, large amplitudes may initiate the nonlinear state.
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  • 6
    ISSN: 1617-7134
    Source: Springer Online Journal Archives 1860-2000
    Topics: Economics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of pest science 12 (1936), S. 98-98 
    ISSN: 1612-4766
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The orientation of the easy magnetization axis of magnetic particles is a key parameter of the recording performance of magnetic recording media. Usually the orientation is measured by magnetic methods, but the applicability of the Mössbauer Spectroscopy has also been shown in the past. We show up and discuss the correlations between the results obtained by magnetic and Mössbauer measurements for the example of several magnetic tapes. We demonstrate that by a combination of both methods we are even able to estimate the mean canting angles distribution width of the easy axis of magnetization.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Hyperfine interactions 33 (1987), S. 293-313 
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Mössbauer radiation from a copper foil doped with57Co is resonantly absorbed in a stationary Be∶57Fe absorber. Experiments were performed with the source immersed in liquid He at 4.2K, He gas from 4.2 to 78 K, and in liquid HeII to 2 K. Radio-frequency current pulses through the source cause large increases in transmission, mainly after the end of the pulse. These increases are associated with heat transfer instabilities (Taconis oscillations) at the He-metal interface.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 117 (1939), S. 205-212 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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