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  • 2015-2019  (2)
  • 1990-1994  (5)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 38 (1992), S. 45-72 
    ISSN: 1573-4889
    Keywords: intermetallic-matrix composites ; oxidation ; NiAl ; fiber/matrix interfaces
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The 1200°C and 1300°C isothermal and cyclic oxidation behavior of Al2O3 continuous fiber (Saphikon™)-reinforced/ NiAl composites were studied. Oxidation resulted in formation of Al2O3 external scales in a similar manner as scales formed on monolithic NiAl. The isothermal oxidation of an Al2O3/NiAl composite resulted in oxidation of the matrix along the fiber/matrix interface near the fiber ends. This oxide acted as a wedge between the fiber and matrix, and, under cyclic oxidation conditions, led to further oxidation along the fiber lengths and eventual cracking of the composite. The oxidation behavior of composites in which the Al2O3 fibers were sputter coated with nickel prior to processing was much more severe. This was attributed to open channels around the fibers which formed during processing most likely as a result of the diffusion of the nickel coating into the matrix.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2017-10-16
    Print ISSN: 1059-9495
    Electronic ISSN: 1544-1024
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Springer
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  • 3
    Publication Date: 2011-08-24
    Description: Nickel aluminides (NiAl) containing 40-50 at. percent Al and up to 0.1 at. percent Zr have been studied following cyclic oxidation at 1200, 1300, 1350 and 1400 C. The selective oxidation of aluminum resulted in the formation of protective Al2O3 scales on each alloy composition at each temperature. However, repeated cycling eventually resulted in the gradual formation of less protective NiAl2O4. The appearance of the NiAl2O4, signaling the end of the protective scale-forming capability of the alloy, was related to the presence of gamma-prime-(Ni3Al) which formed as a result of the loss of aluminum from the sample. A simple methodology is presented to predict the protective life of beta-NiAl alloys. This method predicts the oxidative lifetime due to aluminum depletion when the aluminum concentration decreases to a critical concentration. The time interval preceding NiAl2O4 formation (i.e., the lifetime based on protective Al2O3 formation) and predicted lifetimes are compared and discussed. Use of the method to predict the maximum use temperature for NiAl-Zr alloys is also discussed.
    Keywords: METALLIC MATERIALS
    Type: Materials Science and Engineering, Part A -Structural Materials: Properties, Microstructure, Microstructure and Processing (ISSN 0921-5093); p. 561-566.
    Format: text
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  • 4
    Publication Date: 2011-08-24
    Description: Nickel aluminides containing 40 to 50 at. pct Al and 0.1 at. pct Zr were studied following cyclic oxidation at 1400 C. The selective oxidation of Al resulted in the formation of protective Al2O3 scales on each alloy composition. However, repeated cycling eventually resulted in the gradual formation of less-protective NiAl2O4, first appearing on the 40Al alloys followed at longer times on the 45Al alloys. The appearance of the NiAl2O4, signaling the end of the protective scale-forming capability of the alloy, was related to the presence of gamma-prime (Ni3Al) which formed as a result of the loss of Al from the sample. A diffusion model, based on finite-difference techniques, was developed to predict the protective life of beta Ni-Al alloys. This model predicts Ni and Al concentration profiles after various oxidation exposures. The model can predict the oxidative lifetime due to Al depletion when the Al concentration decreases to a critical concentration. Measured Al concentration profiles on two alloys after various oxidation exposures are compared to those predicted by the diffusion model. The time to the appearance of the NiAl2O4 and that predicted by the diffusion model are compared and discussed.
    Keywords: METALLIC MATERIALS
    Type: In: Damage and oxidation protection in high temperature composites. Vol. 1; Proceedings of the Symposium, 112th ASME Winter Annual Meeting, Atlanta, GA, Dec. 1-6, 1991 (A93-53937 23-24); p. 9-22.
    Format: text
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  • 5
    Publication Date: 2011-08-24
    Description: The 1200 C and 1300 C isothermal and cyclic oxidation behavior of Al2O3 continuous fiber-reinforced/NiAl composites were studied. Oxidation resulted in formation of Al2O3 external scales in a similar manner as scales formed on monolithic NiAl. The isothermal oxidation of an Al2O3/NiAl composite resulted in oxidation of the matrix along the fiber/matrix interface near the fiber ends. This oxide acted as a wedge between the fiber and the matrix, and, under cyclic oxidation conditions, led to further oxidation along the fiber lengths and eventual cracking of the composite. The oxidation behavior of composites in which the Al2O3 fibers were sputter coated with nickel prior to processing was much more severe. This was attributed to open channels around the fibers which formed during processing, most likely as a result of the diffusion of the nickel coating into the matrix.
    Keywords: COMPOSITE MATERIALS
    Type: Oxidation of Metals (ISSN 0030-770X); 38; 1-2,
    Format: text
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  • 6
    Publication Date: 2019-07-20
    Description: No abstract available
    Keywords: Metals and Metallic Materials
    Type: GRC-E-DAA-TN61362 , Materials Science & Technology Conference & Exhibition - MS&T 2018; Oct 14, 2018 - Oct 18, 2018; Columbius, OH; United States
    Format: application/pdf
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  • 7
    Publication Date: 2019-07-13
    Description: Traditional APS ZrO2-Y2O3 thermal barrier coatings (TBCs) formed by air plasma spraying and low pressure and air plasma sprayed ZrO2-Y2O3/NiCrAlY cermet coatings were tested in an H2-O2 rocket engine. The test cycle was approximately 1.2 s at 1400 C in a hydrogen-rich environment. During testing, the maximum metal temperature without a coating was 1310 C. The traditional ZrO2-Y2O3 TBCs with a 100-125 micron thick ceramic layer reduced the maximum metal temperature by approximately 350 C. Increasing the ceramic layer thickness to 200-225 microns resulted in an additional metal temperature reduction of 100 C. However, the cermet coatings, consisting of a ceramic and metal mixture, exhibited a much lower thermal protection capability by reducing the maximum metal temperature by approximately 100 C. It was also found that the surface roughness of the traditional TBCs had little effect on the thermal response.
    Keywords: METALLIC MATERIALS
    Type: International Conference on Metallurgical Coatings; Apr 02, 1990 - Apr 06, 1990; San Diego, CA; United States
    Format: text
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