ISSN:
1573-9171
Keywords:
2-methylcyclohexanone
;
aromatic and heterocyclic aldehydes
;
Claisen—Schmidt reaction
;
C-methylation
;
Corey—Chaykovsky reaction
;
spirooxiranes
;
substituted hexahydroisobenzofurans
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The reaction of dimethylsulfonium methylide with the carbonyl function of 2-arylidene-cyclohexanones obtained from 2-methylcyclohexanone affords the corresponding spirooxiranes. The application of this reaction to 2,2-dimethyl-6-(5-methylfurfurylidene)cyclohexanone and 2,2-dimethyl-6-(5-chlorofurfurylidene)cyclohexanone leads to substituted 4,4-dimethyl-1-furyl-1,-3,4,5,6,7-hexahydroisobenzofurans.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00703695
Permalink