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  • American Institute of Physics (AIP)  (83)
  • American Physical Society (APS)  (61)
  • Cell Press  (32)
  • PANGAEA  (20)
  • 2015-2019  (129)
  • 1995-1999  (67)
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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 102 (1995), S. 7902-7909 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The unimolecular dissociation of trichloroethylene in its electronic ground state has been investigated using an infrared multiphoton dissociation combined with photofragmentation translational spectroscopy to measure product translational energies. The main reaction channel was found to be HCl elimination on the basis of observed product time-of-flight (TOF) spectra. A center-of-mass translational energy distribution for this channel provides direct evidence for competition between two channels, three- and four-centered HCl eliminations. Cl elimination was found to be a minor but significant channel from observed Cl+ and C2HCl+TOF spectra. The branching ratios were determined as 0.28, 0.55, and 0.17 for the three- and four-centered HCl eliminations and the Cl elimination, respectively. The three-centered channel exhibits a "statistical'' translational energy distribution which is typical for a reaction with no potential energy barrier in the reverse reaction, that is to say, no exit barrier reaction. In contrast, the four-centered channel exhibits a "nonstatistical'' translational energy distribution having a peak at around 2 kcal/mol in energy, indicating that a significant exit barrier exists in the channel. The fraction of potential energy converted to translational energy was estimated to be around 10%. Ab initio calculations at the QCISD(T)/6-311+G**//MP2(FC)/6-31G* level were employed to confirm the reaction mechanism. The agreement in the energetics is quite good. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2015-02-20
    Description: We have realized ultrathin body GaSb-on-insulator (GaSb-OI) on Si wafers by direct wafer bonding technology using atomic-layer deposition (ALD) Al 2 O 3 and have demonstrated GaSb-OI p-channel metal-oxide-semiconductor field-effect transistors (p-MOSFETs) on Si. A 23-nm-thick GaSb-OI p-MOSFET exhibits the peak effective mobility of ∼76 cm 2 /V s. We have found that the effective hole mobility of the thin-body GaSb-OI p-MOSFETs decreases with a decrease in the GaSb-OI thickness or with an increase in Al 2 O 3 ALD temperature. The InAs passivation of GaSb-OI MOS interfaces can enhance the peak effective mobility up to 159 cm 2 /V s for GaSb-OI p-MOSFETs with the 20-nm-thick GaSb layer.
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 3
    Publication Date: 2015-03-25
    Description: We have systematically studied the impact of interfacial InAs layers on Al 2 O 3 /GaSb metal-oxide-semiconductor (MOS) interface properties. The interfacial InAs layers improved the capacitance versus voltage ( C-V ) curves of the Al 2 O 3 /GaSb MOS capacitors (MOSCAPs) fabricated by an ex-situ process. The minimum interface-trap density ( D it ) value of an Al 2 O 3 /1.5-nm-thick InAs/p-GaSb MOSCAP is ∼6.6 × 10 12  cm −2 eV −1 , which is reduced by ∼50% from that of ∼1.4 × 10 13  cm −2 eV −1 in an Al 2 O 3 /p-GaSb MOSCAP. Also, the interfacial InAs layers significantly improved the C-V curves of the Al 2 O 3 /n-GaSb MOSCAPs. The InAs layer can improve the Al 2 O 3 /GaSb MOS interface properties both in valence band side and in conduction band side.
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 4
    Publication Date: 2016-11-24
    Description: We demonstrate a single channel III–V complementary metal-oxide-semiconductor (CMOS) transistors by ultrathin body InAs/GaSb-on-insulator (-OI) channels on Si. The ultrathin InAs layers with the quantum confinement and tight gate-control of the identical InAs/GaSb-OI channel can realize III–V CMOS operation. The quantum well InAs/GaSb-OI on Si structures with the proper thickness of the InAs and GaSb layers can allow us to operate both n-channel and p-channel metal-oxide-semiconductor field-effect transistors (n-MOSFETs and p-MOSFETs) with high channel mobilities in an identical InAs/GaSb-OI transistor. The InAs thickness needs to be ≲2.5 nm for CMOS operation in the single channel InAs/GaSb-OI structure.
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 5
  • 6
    Publication Date: 2023-06-27
    Keywords: Baikal Drilling Project; BDP; BDP1993; BDP93-1; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; DRILL; Drilling/drill rig; Magnetometer, cryogenic; NRM, Inclination; NRM, Inclination after demagnetization; NRM, Intensity; NRM, Intensity after demagnetization; Sampling/drilling in lake; Single sample demagnetization
    Type: Dataset
    Format: text/tab-separated-values, 192 data points
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  • 7
    Publication Date: 2023-07-22
    Description: Lake Nyos is located at the summit of a stratovolcano in the Oku Volcanic Group (OVG) along the Cameroon Volcanic Line. The sudden release of magmatic CO2 trapped at the bottom of Lake Nyos in August 1986 caused historical casualties of 1750 people and over 3000 cattle. New geochemical data of volcanic rocks from the Nyos volcano and the first available data for volcanic rocks from other maar-bearing volcanoes (Lakes Elum, Wum and Oku) in the OVG are presented and compared. Lavas from the Nyos, Elum and Wum volcanoes show similarities in major and trace elements and Sr?Nd?Pb isotopes, suggestive of a similar mantle source. However, this source is slightly different from that of the Oku volcano. The samples from Lake Oku have lower alkali, higher TiO2 and more depletion and enrichment in most incompatible trace elements than those from the Nyos, Elum and Wum volcanoes. These differences and those observed in the Sr?Nd?Pb results are consistent with a heterogeneous source for lavas in the OVG. Trace element compositions suggested the presence of garnet in the source (〈 6% garnet) and modelled melting results indicate 〈 2% partial melting of the source material. Isotope data plot within the focal zone, extending towards enriched mantle 1 (EM1; e.g. Lakes Oku and Nyos samples). This indicates the involvement of at least three mantle components: depleted mid-ocean ridge basalt mantle, high-µ and EM1 components in the magmatism of the lavas studied. The contributions of these components in different proportions, originating from asthenospheric and subcontinental lithospheric mantle sources, can account for the observed variations in geochemical characteristics. The geochemical characteristics of the studied lavas indicate that the magma source need not necessarily have an abnormal CO2 concentration to pose a potential threat. Degassing of an ordinary magma chamber and the migration of gas to the bottom of the lakes through cracks and faults can lead to the accumulation of CO2 in lake bottoms. This is controlled by tectonic parameters (fractures and faults) that enhance degassing from the magma chamber to the lake bottom and physical parameters of the lake (e.g. size, depth, temperature and solubility) that control CO2 stability.
    Keywords: Aluminium oxide; Barium; Caesium; Calcium oxide; Cameroon; Cerium; Chromium; Cobalt; Copper; Dysprosium; Erbium; Europium; Event label; Gadolinium; Hafnium; HAND; Holmium; Iron oxide, Fe2O3; Lanthanum; Latitude of event; Lead; Lead-206/Lead-204 ratio; Lead-207/Lead-204 ratio; Lead-208/Lead-204 ratio; Longitude of event; Loss on ignition; Lutetium; Magnesium; Magnesium oxide; Manganese oxide; Neodymium; Neodymium-143/Neodymium-144 ratio; Nickel; Niobium; OVG_Lake_Elum; OVG_Lake_Nyos; OVG_Lake_Oku; OVG_Lake_Wum; Phosphorus pentoxide; Potassium oxide; Praseodymium; Rubidium; Samarium; Sample ID; Sampling by hand; Silicon dioxide; Sodium oxide; Strontium; Strontium-87/Strontium-86 ratio; Tantalum; Terbium; Thorium; Thulium; Titanium dioxide; Total; Uranium; Vanadium; Ytterbium; Yttrium; Zinc; Zirconium
    Type: Dataset
    Format: text/tab-separated-values, 1768 data points
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  • 8
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    PANGAEA
    In:  Supplement to: Obrochta, Stephen P; Fazekas, S Z; Lougheed, Bryan C; Snowball, Ian; Yokoyama, Yusuke; Miyairi, Yosuke; Kondo, R; Kotilainen, Aarno T; Hyttinen, Outi; Fehr, Annick (2017): The undateables: Quantifying uncertainty in a highly expanded Late Glacial - Holocene sediment sequence recovered from the deepest Baltic Sea basin - IODP Site M0063. Geochemistry, Geophysics, Geosystems, 18(3), 858-871, https://doi.org/10.1002/2016GC006697
    Publication Date: 2024-01-25
    Description: Laminated, organic-rich silts and clays with high dissolved gas content characterize sediments at IODP Site M0063 in the Landsort Deep, which at 459 m is the deepest basin in the Baltic Sea. Cores recovered from Hole M0063A experienced significant expansion as gas was released during the recovery process, resulting in high sediment loss. Therefore during operations at the subsequent four holes, penetration was reduced to 2 m per 3.3 m coring run, permitting expansion into 1.3 m of initially empty liner. Fully filled liners were recovered from Holes B through E, indicating that the length of each recovered interval exceeded the penetrated distance by a factor of 〉1.5. We note a typical logarithmic trend in the down-core gamma density profiles, with anomalously low density values within the upper ~1 m of each core. We interpret that expansion primarily occurred in this upper interval, which is also visible in the core images, and suggest that a simple linear correction is inappropriate. This is supported by Anisotropy of Magnetic Susceptibility data that indicate vertical stretching in the upper ~1.5 m of expanded cores. Based on the mean gamma density profiles of cores from Holes M0063C and D, we obtain an expansion function that is used to adjust the depth of each core to conform to its known penetration. The variance in these profiles allows for quantification of uncertainty in the adjusted depth scale. Together with a number of bulk 14C dates, we explore how the presence of multiple carbon source pathways leads to poorly constrained variations in radiocarbon reservoir age, which significantly affects age and sedimentation rate calculations.
    Keywords: Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP
    Type: Dataset
    Format: application/zip, 7 datasets
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  • 9
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    PANGAEA
    In:  Supplement to: Riethdorf, Jan-Rainer; Thibodeau, Benoit; Ikehara, Minoru; Nürnberg, Dirk; Max, Lars; Tiedemann, Ralf; Yokoyama, Yusuke (2016): Surface nitrate utilization in the Bering sea since 180kA BP: Insight from sedimentary nitrogen isotopes. Deep Sea Research Part II: Topical Studies in Oceanography, 125-126, 163-176, https://doi.org/10.1016/j.dsr2.2015.03.007
    Publication Date: 2024-01-25
    Description: We present high-resolution records of sedimentary nitrogen (d15Nbulk) and carbon isotope ratios (d13Cbulk) from piston core SO201-2-85KL located in the western Bering Sea. The records reflect changes in surface nitrate utilization and terrestrial organic matter contribution in submillennial resolution that span the last 180 kyr. The d15Nbulk record is characterized by a minimum during the penultimate interglacial indicating low nitrate utilization (~62-80%) despite the relatively high export production inferred from opal concentrations along with a significant reduction in the terrestrial organic matter fraction (mterr). This suggests that the consumption of the nitrate pool at our site was incomplete and even more reduced than today (~84%). d15Nbulk increases from Marine Isotope Stage (MIS) 5.4 and culminates during the Last Glacial Maximum, which indicates that nitrate utilization in the Bering Sea was raised during cold intervals (MIS 5.4, 5.2, 4) and almost complete during MIS 3 and 2 (~93-100%). This is in agreement with previous hypotheses suggesting that stronger glacial stratification reduced the nutrient supply from the subeuphotic zone, thereby increasing the iron-to-nutrient ratio and therefore the nitrate utilization in the mixed surface layer. Large variations in d15Nbulk were also recorded from 180 to 130 ka BP (MIS 6), indicating a potential link to insolation and sea-level forcing and its related feedbacks. Millennial-scale oscillations were observed in d15Nbulk and d13Cbulk that might be related to Greenland interstadials.
    Keywords: AGE; Carbon, organic, total; Comment; DEPTH, sediment/rock; Element analyser isotope ratio mass spectrometer (EA-IRMS); KALMAR II; Nitrogen, total; PC; Piston corer; Shirshov Ridge; SO201/2; SO201-2-85; Sonne; δ13C, organic matter; δ15N, organic matter
    Type: Dataset
    Format: text/tab-separated-values, 1427 data points
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  • 10
    Publication Date: 2024-01-25
    Keywords: 347-M0063A; 347-M0063C; 347-M0063D; 347-M0063E; Age, dated; Age, dated standard deviation; Baltic Sea, Landsort Deep; Baltic Sea Paleoenvironment; BSB-9; Depth, adjusted; DEPTH, sediment/rock; DSDP/ODP/IODP sample designation; Event label; Exp347; Greatship Manisha; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; Laboratory code/label; Method comment; Sample code/label
    Type: Dataset
    Format: text/tab-separated-values, 186 data points
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