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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 2 (1979), S. 405-410 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary, glass ; Stationary phases of polysiloxane-type degrade in acidic solution ; Several salt traces affect stability at high temperature NaCl on Duran-5O: no effect at 260°C ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A number of polysiloxanes have been shown to be sensitive to acids when dissolved in chloroform.At 26O°C polysiloxanes were found to degrade under the influence of several compounds used or produced during the preparation of glass capillary columns.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 22 (1999), S. 24-28 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; ECD ; Micro-ECD ; GC detector ; organochlorine pesticides ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---A new ECD, the HP 6890 Series Micro-ECD, was designed to address inherent deficiencies in classical electron capture detectors (ECD), especially with respect to sensitivity, linearity, dynamic range, and ruggedness. Several novel technologies were incorporated in the totally new design and were refined through practical testing and user feedback. Validation of the micro-ECD performance was accomplished through side-by-side testing of the Micro-ECD with previous ECDs following US EPA Contract Laboratory Program methods for pesticides and PCBs. In addition, extensive interviews were conducted with early users of the Micro-ECD who also had experience with other designs running a variety of ECD methods. The design and resulting performance improvements are described.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 2 (1979), S. 351-356 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary, glass ; Potash soda lead and fused silica as wall material investigated ; Thin-walled fused silica is an ideal material ; Inherently more inert than normal glass ; High flexibility avoids fragility problems ; Application examples (alcohols, mercaptanes, sulfides, phenolsamines, acids) ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An investigation was conducted of various glasses, other than soda lime or borosilicate, for use in glass capillary gas chromatography. The work has uncovered some unique chromatographic qualities in the use of potash soda lead and fused silica glasses as materials for making glass capillary columns. The fused silica proved to be an ideal material for capillary column construction, being inherently more inert than glass containing metal oxides. It has been shown that through the use of thin wall capillary tubing of high flexibility many of the mechanical problems associated with glass capillary columns, such as fragility and column straightening, can be avoided.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary, glass ; Organic gas phase cigarette smoke ; Microprocessor-controlled ; Cryogenic preconcentration trap ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An automatic injection system for the analysis of gas phase smoke has been designed and evaluated using the microprocessor-controlled Hewlett-Packard 5830 gas chromatograph. The cryogenic preconcentration trap was constructed from relatively inexpensive and readily available materials. It was determined that the use of the preconcentration trap, as opposed to condensing the smoke on the head of the cold (-50°C) chromatographic column, significantly enhanced the resolution of the more volatile gas phase components. Data are presented which illustrate the injection system characteristics. In addition, chromatograms of gas phase smoke are presented which demonstrate the effectiveness of this technique.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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