ALBERT

Description: This data set is predominantly sourced from the National Water Quality Monitoring Council (https://www.waterqualitydata.us/portal) and contains water quality data for the United States as well as climate and other ancillary data. This data was used to develop a model to explain groundwater dissolved organic carbon concentrations in the manuscript "Changes in global groundwater organic carbon driven by climate change and urbanization". Units for variables are included in the file "Units for Variables". --- National Water Quality Monitoring Council water chemistry data (https://www.waterqualitydata.us/portal) was obtained from: Chapelle, F. H., Bradley, P. M., Journey, C. A., & McMahon, P. B. (2013). Assessing the Relative Bioavailability of DOC in Regional Groundwater Systems. Ground water 51(3), doi:10.1111/j.1745-6584.2012.00987.x. --- Water table depth data obtained from: Fan, Y., Li, H., & Miguez-Macho, G. (2013). Global patterns of groundwater table depth. Science, 339, 940–943, doi:10.1126/science.1229881. --- Climatic data obtained from www.worldclim.org: Hijmans, R. J., Cameron, S. E., Parra, J. L., Jones, P. G., & Jarvis, A. (2005). Very high resolution interpolated climate surfaces for global land areas. International Journal of Climatology, 25, 1965-1978, doi:10.1002/joc.1276. --- Land use data obtained from: Channan, S., Collins, K., & Emanuel, W. R. (2014). Global mosaics of the standard MODIS land cover type data. University of Maryland and the Pacific Northwest National Laboratory, College Park, Maryland, USA. Retrieved from University of Maryland and the Pacific Northwest National Laboratory. - Friedl, M. A., Sulla-Menasche, D., Tan, B., Schneider, A., Ramankutty, N., Sibley, A., & Huang, X. (n.d.). MODIS Collection 5 global land cover: Algorithm refinements and characterization of new datasets, 2001-2012. Collection 5.1 IGBP Land Cover. Boston University, Boston, MA, USA.

Description: Total Suspended Particulate (TSP) aerosol samples were collected daily during the Stratospheric ozone: Halogen Impacts in a Varying Atmosphere (SHIVA) cruise (FS Sonne, SO218) during 16 - 28 November 2011 through the South China and Sulu Seas. The samples were collected by Birgit Quack and Anke Schneider of GEOMAR, Kiel, Germany. The aerosol sampler was situation on the roof of the ship's wheelhouse and collection time for each sample varied between 13.0 and 24.7 hours. Samples were extracted with ultrapure water and the major ions Na+, NH4+, Mg2+, K+, Ca2+, Cl-, NO3-, SO42-, oxalate and Br- were determined by ion chromatography (IC). Total soluble iodine (TSI) was determined by inductively coupled plasma - mass spectrometry (ICP-MS) and iodide (I-) and iodate (IO3-) were determined by IC-ICP-MS. The dataset contains the atmospheric concentrations of all measured soluble major ions (in nmol m-3) and iodine species (in pmol m-3). The data for iodine species are reported in “The influence of collection substrate and extraction method on the speciation of soluble iodine in atmospheric aerosols”, Chan Yodle, Alex R. Baker, in preparation for Analytical and Bioanalytical Chemistry.

Description: Benthic foraminiferal stable isotope data are presented for Sites 1014 (Tanner Basin, 1176 m) and 1020 (Gorda Ridge, 3040 m) to constrain past changes in Pacific deep- and intermediate-water nutrient chemistry associated with the onset of large-amplitude 100-k.y. climate cycles after ~900 ka. The Site 1014 data were based on analyses of separate species of Cibicidoides, whereas only Cibicidoides wuellerstorfi was used to generate the Site 1020 record. The present data span 380-920 and 620-950 ka at Sites 1014 and 1020, respectively.

Description: Widespread silicic pyroclastic eruptions of the Oligocene Afro-Arabian flood volcanic province (ignimbrites and airfall tuffs) produced up to 20% of the total flood volcanic stratigraphy (〉6*10**4 km**3). Volumes of individual ignimbrites and tuffs exposed on land range from ~150 to 〉2000 km**3 and eight major units (15-100 m thick) were erupted in 〈2 Myr, placing these amongst the largest-magnitude silicic pyroclastic eruptions on Earth. They are compositionally distinctive time-stratigraphic markers which were deposited as co-ignimbrite ashfall deposits on a near-global scale around the time of the Oi2 cooling anomaly at ~30 Ma. Two ignimbrites from the lower part of the flood volcanic succession in Yemen have been correlated to: (a) the conjugate rifted margin of Ethiopia (〉500 km distant); and (b) to two deep sea ash layers sampled by ODP Leg 115 in the Indian Ocean ~2700 km to the southeast. This correlation is based on whole rock analyses of silicic units for isotope ratios (Pb, Nd) and rare earth element compositions, in conjunction with novel in situ Pb isotope laser ablation multicollector inductively coupled plasma mass spectroscopy analysis of groundmass and glass shards. Compositional diversity preserved on the scale of individual ash shards in these deep sea tephra layers record chemical heterogeneity present in the silicic magma chambers that is not evident in the welded on-land deposits. Ages of the ash layers can be established by correlation to precisely dated on-land ignimbrites, and current evidence suggests that while these eruptions may have exacerbated already changing climatic conditions, they both marginally post-date the Oi2 global cooling anomaly.

Description: A detailed (ca. 100 yr resolution) and well-dated (18 AMS 14C dates to 23 cal. ka BP) record of latest Pleistocene–Holocene variations in terrigenous (eolian) sediment deposition at ODP Site 658C off Cap Blanc, Mauritania documents very abrupt, large-scale changes in subtropical North African climate. The terrigenous record exhibits a well-defined period of low influx between 14.8 and 5.5 cal. ka BP associated with the African Humid Period, when the Sahara was nearly completely vegetated and supported numerous perennial lakes; an arid interval corresponding to the Younger Dryas Chronozone punctuates this humid period. The African Humid Period has been attributed to a strengthening of the African monsoon due to gradual orbital increases in summer season insolation. However, the onset and termination of this humid period were very abrupt, occurring within decades to centuries. Both transitions occurred when summer season insolation crossed a nearly identical threshold value, which was 4.2% greater than present. These abrupt climate responses to gradual insolation forcing require strongly non-linear feedback processes, and current coupled climate model studies invoke vegetation and ocean temperature feedbacks as candidate mechanisms for the non-linear climate sensitivity. The African monsoon climate system is thus a low-latitude corollary to the bi-stable behavior of high-latitude deep ocean thermohaline circulation, which is similarly capable of rapid and large-amplitude climate transitions.