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  • Chemistry  (38)
  • Animals  (34)
  • 2015-2019  (10)
  • 2000-2004  (22)
  • 1975-1979  (38)
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 1 (1978), S. 105-106 
    ISSN: 0935-6304
    Keywords: Thin Layer Chromatography, HPTLC ; Quantitative analysis of anticonvulsant drugs extracted from plasma ; Sample volume needed equals 2 microliter plasma ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The use of the mass spectrometric integrated ion current technique for the quantitative analysis of some trace metals at their tetraphenylporphyrin chelates is described. The linearity of the calibration curves and the sensitivity of the technique are improved by employing deuterated tetraphenylporphyrin chelates as loading agents. Femtomole quantities of the chelates may be detected. The use of deuterated tetraphenylporphyrin chelates as internal standards overcomes the problems of losses occurring during chromatographic separation and by thermal decomposition in the mass spectrometer.
    Additional Material: 3 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 955-962 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Temperature was calculated as a function of lateral and axial position within a thin poly(ethylene terephthalate) (PET) tape traveling alternately over a heated roll and through air. The system consists of a pair of rolls which are internally heated and located in an oven. The centers of the rolls are ten inches apart and the tape makes eight wraps around the roll pair. Three sources of heat transfer to the tape are considered: convection and radiation from the heated rolls, convection from the air, and radiation from the hot oven walls. Calculations were carried out for oven wall temperatures of 100 and 1000°C, air temperatures of 100 and 205°C, and roll surface temperatures of 180 and 235°C. The computations generally indicate that after several wraps the temperature of the outside surface of the tape (i.e., the surface that does not contact the rolls) is essentially the same each time the tape leaves the roll. However, this temperature changes us the tape then travels through the adjacent, downstream air space. Although there is a temperature gradient across the tape, the temperature of the inside surface (i.e., the side that contacts the rolls) exhibits behavior similar to that of the outside surface.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 17 (1977), S. 32-37 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A forced torsional oscillator (FTO) for measuring dynamic properties from 0.01 to 30 Hz and -190 to +250°C is described. It uses a digital transfer function analyzer to determine G′ and G″ directly. Errors such as clamping corrections, phase angle resolution, and instrument phase shift are evaluated. FTO measurements vs temperature on polymethylmethacrylate (PMMA) and polycarbonate compare well with free torsion pendulum data. Measurements on a silicone liquid vs frequency compare well to eccentric rotating disks data. The frequency sensitivity of the dynamic mechanical response of PMMA and polycarbonate is evaluated at 0.1, 1 and 10 Hz. The frequency dependence of the transitions is fit to an Arrhenius relation and activation energies calculated. A dimensionless transition temperature shift, ΔT*, giving the shift for a one decade frequency change divided by the temperature, is found to be approximately 0.01 for the glass transition and 0.07 for several secondary transitions in glassy polymers.
    Additional Material: 11 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 1165-1174 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The use of poly(phenylene oxide) film to monitor UV radiation is demonstrated, and the results from the continuous monitoring of solar UV radiation at 24 sites throughout the world are presented. The global and diffuse measurements from a temperate and from a tropical site are analyzed in detail, and the effects of season and weather conditions on the UV contribution to solar radiation and the relative importance of the diffuse and direct components of solar UV are discussed.
    Additional Material: 8 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 24 (1978), S. 1010-1014 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Formulas obtained by approximation of the rigorous expression for the interfacial tension of multicomponent, polyatomic fluids are shown to provide accurate and simple estimates of the composition dependence of the surface tension of nonaqueous, binary solutions at low vapor pressures. Similar formulas are recommended for multicomponent (that is, more than two components) solutions.
    Additional Material: 1 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 24 (1978), S. 1076-1080 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A comparison of experimental and theoretical surface tensions leads to a correlation between homogeneous fluid parameters and the inhomogeneous influence parameter c. From this correlation, it is possible to predict, to within excellent agreement with experiment, the surface tensions of normal alkanes and alcohols from bulk data only.
    Additional Material: 5 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 701-708 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An equation of state has been developed for convex nonspherical particles with nonpolar and multipolar forces. The effects of nonsphericity and multipolarity on phase behavior are characterized by a geometric shape parameter and an energy fluctuation parameter, respectively. The equation performs for real fluids better than the Van der Waals equation and as well as the Redlich-Kwong and Peng-Robinson equations.
    Additional Material: 8 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 813-813 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 48-56 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper is an experimental and theoretical study of horizontal stratified gas-liquid two phase flow in a circular tube. Both phases are considered to be in turbulent flow, and the liquid phase flow field is modeled by applying eddy viscosity expressions developed for single phase flow. The pressure drop and in situ volume of liquid are predicted from the gas and liquid flow rates, physical properties, and pipe size by means of an iterative procedure which terminates when calculated gas and liquid pressure drops match. The iterative design procedure is compared with new data for air-water flow in a smooth tube of 63.5 mm ID and with data available in the literature. For conditions corresponding to small amplitude interfacial waves, the average deviation between predicted and experimental results is 24.3% for the pressure drop and 7.7% for the holdup. For roll wave conditions, the corresponding average deviations are 4.6 and 26.4% for pressure drop and holdup, respectively. These results are substantially better than the predictions obtained using the Lockhart-Martinelli correlations.
    Additional Material: 16 Ill.
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