ALBERT

Description: Ship traffic, population, infrastructure development, and mining activities are expected to increase in the Arctic due to its rising temperatures. This is expected to produce a major impact on aerosol composition. Metals contained in atmospheric particles are powerful markers and can be extremely helpful to gain insights on the different aerosol sources. Thiswork aims at studying the sources of metals in the Arctic aerosol sampled at the Thule High Arctic Atmospheric Observatory (THAAO; Greenland, 76.5°N 68.8°W). Due to the particular composition of Greenlandic soils and to properties of other sources, it was possible to find several signatures of natural and anthropogenic aerosols transported from local and long-range regions. Arctic haze (AH) at Thule builds up on long-range transported aerosol mainly from Canada and Nord America. From a chemical standpoint, this aerosol is characterized by a high concentration of sulfate, Pb, As and Cd and by a La/Ce ratio larger than 1. The Ti/Al and Fe/Al ratios in the AH aerosol are lower (Ti/Al = 0.04 w/w; Fe/ Al= 0.79 w/w) than for local aerosol (Ti/Al= 0.07 w/w; Fe/Al = 0.89 w/w). Conversely, aerosol arising from coastal areas of South-West Greenland is characterized by a high concentration of V,Ni, and Cr. These metals, generally considered anthropogenic, arise heremainly fromnatural crustal sources. In some summer samples, however, the V/Ni ratio becomes larger than 3. In particular, cases displaying this characteristic ratio, as also shown by backward trajectories, are associated with sporadic transport to Thule of ship aerosol from ships passing through Baffin Bay and arriving to Thule during summer. Although further measurements are necessary to confirm the discussed results, the analysis carried out in this work on a large number of metals sampled in coastal Greenland aerosol is unprecedented.

Description: Published

Description: 140511

Description: 5A. Ricerche polari e paleoclima

Description: JCR Journal

Description: The Arctic climate is influenced by the interaction of shortwave (SW) and longwave (LW) radiation with the atmosphere and the surface. The comprehensive evolution of the Surface Radiative Fluxes (SRF) on different time scales is of paramount importance to understanding the complex mechanisms governing the Arctic climate. However, only a few sites located in the Arctic region provide long-term time series of SRF allowing for capturing the seasonality of atmospheric and surface parameters and carrying out validation of satellite products and/or reanalyses. This paper presents the daily and monthly SRF record collected at the Thule High Arctic Atmospheric Observatory (THAAO, 76.5° N, 68.8° W), in North-Western Greenland. The downwelling components of the SW (DSI) and the LW (DLI) irradiances have been measured at THAAO since 2009, while the collection of the upwelling SW (USI) and LW (ULI) irradiance was started in 2016, together with additional measurements, such as e.g., meteorological parameters and column water vapour. The datasets of DSI (Meloni et al., 2022a; https://doi.org/10.13127/thaao/dsi), USI (Meloni et al., 2022b; https://doi.org/10.13127/thaao/usi), DLI (Meloni et al., 2022c; https://doi.org/10.13127/thaao/dli), ULI (Meloni et al., 2022d; https://doi.org/10.13127/thaao/uli), and near surface air temperature (Muscari et al., 2018; https://doi.org/10.13127/thaao/met), can be accessed through the THAAO web site (https://www.thuleatmos-it.it/data). DSI is absent (solar zenith angle≥90°) from 29 October to 13 February, assuming maxima in June (monthly mean of 277.0 Wm-2), when it is about half of the total incoming irradiance. The USI maximum occurs in May (132.4 Wm-2) due to the combination of moderately high DSI values and high albedo. The shortwave surface albedo (A) assumes an average of 0.16 during summer, when the surface is free of snow. Differently, during months of snow-covered surface, when solar radiation allows estimating A, its values are greater than 0.6. A large interannual variability is observed in May and September, months characterized by rapidly changing surface conditions, which appear to be linked with air temperature anomalies. DLI and ULI maxima occur in July and August, and minima in February and March. ULI is always larger than DLI and shows a wider annual cycle. ULI is well described by a fourth-order polynomial fit to the air temperature (R2〉0.99 for monthly data and R2〉0.97 for daily data). The surface radiation budget (SRB) is positive from April to August, when absorption of solar radiation exceeds the infrared net cooling, with a maximum value of 153.2 Wm-2 in June. From November to February, during the polar night, the LW net flux varies between -34.5 and -43.0 Wm-2. In March and September, the negative LW net flux overcomes the positive SW contribution, producing a negative SRB. THAAO measurements show clear evidence of the influence of several regional weather/climate events, which appear strongly linked with SRF anomalies. These anomalies are found for example during summer 2012, when a large ice melting event took place over Greenland, and during winter 2019–2020, extraordinarily cold in the Arctic region.

Description: In press

Description: OSA2: Evoluzione climatica: effetti e loro mitigazione

Description: JCR Journal

Description: Boreal fires have increased during the last years and are projected to become more intense and frequent as a consequence of climate change. Wildfires produce a wide range of effects on the Arctic climate and ecosystem, and understanding these effects is crucial for predicting the future evolution of the Arctic region. This study focuses on the impact of the long-range transport of biomass-burning aerosol into the atmosphere and the corresponding radiative perturbation in the shortwave frequency range. As a case study, we investigate an intense biomass-burning (BB) event which took place in summer 2017 in Canada and subsequent northeastward transport of gases and particles in the plume leading to exceptionally high values (0.86) of Aerosol Optical Depth (AOD) at 500 nm measured in northwestern Greenland on 21 August 2017. This work characterizes the BB plume measured at the Thule High Arctic Atmospheric Observatory (THAAO; 76.53∘N, 68.74∘W) in August 2017 by assessing the associated shortwave aerosol direct radiative impact over the THAAO and extending this evaluation over the broader region (60∘N–80∘N, 110∘W–0∘E). The radiative transfer simulations with MODTRAN6.0 estimated an aerosol heating rate of up to 0.5 K/day in the upper aerosol layer (8–12 km). The direct aerosol radiative effect (ARE) vertical profile shows a maximum negative value of −45.4 Wm−2 for a 78∘ solar zenith angle above THAAO at 3 km altitude. A cumulative surface ARE of −127.5 TW is estimated to have occurred on 21 August 2017 over a portion (∼3.1×106 km2) of the considered domain (60∘N–80∘N, 110∘W–0∘E). ARE regional mean daily values over the same portion of the domain vary between −65 and −25 Wm−2. Although this is a limited temporal event, this effect can have significant influence on the Arctic radiative budget, especially in the anticipated scenario of increasing wildfires.

Description: This research was partially funded by the Italian Ministry of University and Research (MIUR) within the framework of OASIS-YOPP—Observations of the Arctic Stratosphere In Support of YOPP (PNRA 2016–2018); CLARA2—CLouds And Radiation in the Arctic and Antarctica (PNRA 2019–2021), and ECAPAC—Effects of changing albedo and precipitation on the Arctic climate (PRA 2021–2023). The work of F. Calì Quaglia and G. Muscari was also partially funded under the INGV environmental project MACMAP—A Multidisciplinary Analysis of Climate change indicators in the Mediterranean And Polar regions (2020–2023). The NCAR FTIR observation program at Thule, Greenland is supported under contract by the National Aeronautics and Space Administration (NASA). The National Center for Atmospheric Research (NCAR) is sponsored by the U.S. National Science Foundation (NSF). The Thule work is also supported by the NSF Office of Polar Programs (OPP).

Description: Published

Description: 313

Description: 5A. Ricerche polari e paleoclima

Description: JCR Journal

Description: Ground-based high resolution observations of downward longwave irradiance (DLI), surface air temperature, water vapour surface partial pressure and column amount, zenith sky infrared (IR) radiance in the atmospheric window, and all-sky camera images are regularly obtained at the Thule High Arctic Atmospheric Observatory (THAAO, 76.5° N, 68.8° W), North-West Greenland. The datasets for the years 2017 and 2018 have been used to assess the performance of different empirical formulas to infer clear sky DLI. An algorithm to identify clear sky observations has been developed, based on value, variability, and persistence of zenith sky IR radiance. Seventeen different formulas to estimate DLI have been tested against the THAAO dataset, using the originally determined coefficients. The formulas which combine information on total column water vapour and surface air temperature appear to perform better than others, with a mean bias with respect to the measured DLI smaller than 1 W/m2 and a root mean squared error (RMSE) around 6 W/m2. Some formulas, specifically developed for the Arctic, are found to produce poor statistical results; this is attributed partly to limitations in the originally used dataset, which does not cover a whole year, or is relative to very specific conditions (i.e., the ice sheet). The bias displays a significant improvement when the coefficients of the different formulas are calculated using the THAAO dataset. The presence of two full years of data allows the investigation of the inter-annual variability, and the use of different years for the determination of the coefficients and the evaluation of results. The smallest values of the bias and RMSE reach 0.1 W/m2 and 5 W/m2, respectively. Overall, best results are found for formulas which use both surface parameters and total water vapour column, and have been developed from global datasets. Conversely, formulas which express the atmospheric emissivity as a linear function of the logarithm of the column integrated water vapour appear to poorly reproduce the observations at THAAO.

Description: Published

Description: 1617–1632

Description: OSA2: Evoluzione climatica: effetti e loro mitigazione

Description: JCR Journal