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  • Wiley-Blackwell  (143)
  • Institute of Physics  (126)
  • 2020-2024  (1)
  • 1965-1969  (268)
  • 1
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The aesthetascs, short thin-walled pegs on the antennule flagella of Coenobita clypeatus, a terrestrial hermit crab, are similar to those of other decapod crustacea in containing the dendrites of many bipolar neurons whose cell bodies are grouped in spindle-shaped masses beneath the bases of each hair. The dendrites contain rootlets, basal bodies, and cilia, which divide dichotomously before entering the aesthetasc, so that within the hair, each cilium becomes represented by a group of slender branches.The aesthetascs themselves are short, blunt, and partially recumbent so that each has an exposed and an unexposed side. The cuticle on the exposed side is thinner and more tenuous than that on the protected side, and the dendrite branches are concentrated just underneath. The protected side, on the other hand, is lined with nondendritic supporting cells, and the cuticle is thicker, more lamellar, and probably less permeable.All dendritic elements proximal to the dendrite branches are enclosed within the main body of the antennular flagellum, and the initial segments of the cilia lie within a vacuole. In these respects, the aesthetascs of Coenobita resemble the thin-walled pegs on insect antennae more than they do those of the marine decapods thus far examined. This convergence in the terrestrial forms may be in response to the need to conserve water.
    Additional Material: 2 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 7 (1969), S. 1775-1783 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A systematic study of factors affecting the GPC separation showed that peak spreading with increasing flow rate was much less than predicted from the Van Deemter equation. Viscous fingering decreased and peak symmetry improved at increased flow rates. As a result, fast GPC analysis was shown to be readily attainable through optimization of operating parameters.
    Additional Material: 7 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 657-662 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper presents theoretical studies of a method of using a radioactive tracer technique to evaluate the kinetic data of heterogeneous catalytic reactions that are coupled with a Knudsen type of pore diffusion. By superimposing a transient radioactive tracer response over the steady state concentration profile in the catalyst particle, one can establish an implicit relation between the total amount of radioactive components diffused out of the particle and the kinetic data of the reaction system. This relation can then be used to evaluate kinetic data of the reaction system. A detailed study of general monomolecular complex systems is given. Use of the method for nonlinear systems is also included.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 1210-1211 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 295-311 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In an effort to develop new and improved polymeric materials for space application, a new series of polymers has been prepared. Some of these have shown outstanding thermal stability and good stability when exposed to ultraviolet radiation in a vacuum environment. High molecular weight polymers of the general type, have been prepared by the reaction of a silyldiamine with various organic diols. Bis-(anilino)diphenylsilane has been reacted with such diols as hydroquinone, resorcinol, p,p′-biphenol, 2,7-naphthalenediol, 2,2-propane-bis(4-hydroxybenzene), 1,6-hexanediol, and 4,4′-dihydroxydiphenyl ether. Of these, the polymer containing the biphenyl linkage, polydiphenylsiloxybiphenyl, has the more desirable properties. Polydiphenylsiloxybiphenyl is stable to 600°C. for short periods of time. Fibers with fairly good tenacity, 0.5 g./den. may be drawn directly and continuously from the polymer melt. This polymer forms a hard protective coating on aluminum, remains stable after being heated at 500°C. for 60 min., and shows no change after 96 hr. at 270°C. (518°F.). It also forms good transparent semiflexible films and has good tensile strength as an ambient temperature adhesive.
    Additional Material: 7 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 1 (1967), S. 253-261 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Porous laminates prepared by incorporating a volatile solvent into an epoxy resin system used to impregnate a fabric filler satisfactorily alleviated the problems caused by perspiration in upper extremity prostheses, but did not have sufficient strength for use in artificial legs. A new technique is described which results in a 100% increase in both porosity and strength of porous epoxy laminates. The method consists of impregnation of the fabric with resin and solvent and evaporation of the solvent prior to laying up the laminate. The improvement in properties is ascribed to better control and homogeneity of impregnation.
    Additional Material: 2 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 6 (1966), S. 158-168 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow of polymer melts is normally laminar, but pseudoplastic in character. That is, flow rate increases in proportion to a power higher then 1, usually between 1.5 and 4, of the applied pressure difference. Viscosities are extremely high - more then a mollion times that of water - so considerable heat is generated in the flowing melt by viscous dissipation of flow energy. This mode of heat generation is put to good practial use in the screw extruder, a device that converts plastic pellets into hot melt for shaping into pipe, sheets, coatings and molded products. Equations are given for computing flow rates and viscous dissipation rates. Heating (except by viscous working) and cooling of polymers are slow processes because all these materials are poor heat conducts nad their extreme viscosities make convection impracticable. The princliples of heat transfer are reviewed, and the solutions are given for some transient-conduction problems frequenlty encountered in processing. Equations are given for judging the operation of extruders.
    Additional Material: 3 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 10 (1966), S. 1011-1026 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: When an uncompounded elastomer is processed on a two-roll mill, four different regions of mechanical behavior are observed, depending upon the temperature and the severity of the nip deformation. this behavior is observed on materials with a wide variety in chemical composition, through the severity varies. The flow at high temperatures is typical of melt or polymer solution behavior. At lower temperatures unstable flow and elastic solidike regions are observed. By presuming the elastomer to be an isotropicviscoelastic medium, the stress and velocity fields were computed in the polymer melt region. The unstable regime was found to correspond to a critical value of the ratio of viscoelastic to viscous forces. The mathematical analysis, done interms of the Green-Rivlin-Noll theory of viscoelastic media, extends earlier studies of deformation in this geometry by Gaskell and Bergen.
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 3605-3616 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Cast amorphous one mil films of poly(ethylene terephthalate)were allowed to crystallize isothermally in silicone oil over the temperature range 25-240°C. The crystallization paths were followed by recording the percent of transmission of 4000 A. light through the films as a function of time at specific temperatures. At temperatures between 70 and 90°C. the transmission increased to a value higher than the initial transmission and did not decrease with time. From about 95 to 125°C. the curves showed a similar increase, followed by a decrease to a minimum and then an increase to a new maximum before leveling off. The shapes of these curves were interpreted in terms of the sizes of the growing spherulites. The first detectable signs of crystallization were observed at 96.5°C., as evidenced by density and densitometer measurements. It is shown that the polymer passed through a temperature range beginning at the glass transition point (66°C.) and extending to about 95°C., where molecular and chain rearrangements occurred without crystallization. Half lives and rate constants were found to increase exponentially over the range 96.5-119.5°C. Above approximately 125°C., the crystallization process took place at such a rapid rate that accurate data were impossible to obtain. Activation energies were calculated from the rate constants and from an estimation of induction times from the light transmission-time curves. These values were found to be 37 and 30 kcal./mole, respectively. The density-time data were also fitted to the Avrami relationship. Evaluation of the constants indicated that the initial crystallization growth was lineal.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 3471-3487 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The temperature dependence of the dynamic mechanical properties of dicumyl peroxide/sulfur vulcanizates of seven members of the poly(vinyl alkyl ether) series of elastomers has been determined. The relative position of the curves, relating the dynamic resilience to the dynamic modulus of these polymers, was generally in the order of their glass transformation temperatures (Tg). The dynamic mechanical property data on poly(vinyl n-pentyl ether) and poly(vinyl 2-ethylhexyl ether), which have the same Tg, fall on a common curve characteristic of the temperature of measurement. The dynamic resilience versus dynamic modulus curves are displaced towards higher dynamic resilience and usually lower dynamic modulus values as the temperature of measurement is increased. Poly(vinyl isobutyl ether) and poly(vinyl ethyl ether) show a larger temperature coefficient of resilience than do the other poly(vinyl alkyl ethers), which also include the n-butyl, n-hexyl, and n-octyl members. Apparently, the Tg is a major factor in correlating the dynamic mechanical behavior of this homologous series of elastomers. The size and shape of the alkyl group appear to be reflected primarily in their effect on the Tg. Poly(vinyl isobutyl ether) was the only member of the series showing any anomalies in dynamic mechanical properties that might be ascribed to structure. Because the dynamic resilience of various poly(vinyl alkyl ether) vulcanizates, possessing the same concentration of chemical crosslinks, correlate better with their degree of polymerization than with their molecular weight it appears that the dynamic resilience depends more on the length of the free chain ends than it does on their mass or volume.
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