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Note: CONTENTS PREFACE 1 Introduction: Matter, Energy, and Measurement 1.1 The Study of Chemistry The Atomic and Molecular Perspective of Chemistry Why Study Chemistry? 1.2 Classifications of Matter States of Matter Pure Substances Elements Compounds Mixtures 1.3 Properties of Matter Physical and Chemical Changes Separation of Mixtures 1.4 The Nature of Energy Kinetic Energy and Potential Energy 1.5 Units of Measurement SI Units Length and Mass Temperature Derived SI Units Volume Density Units of Energy 1.6 Uncertainty in Measurement Precision and Accuracy Significant Figures Significant Figures in Calculations 1.7 Dimensional Analysis Conversion Factors Using Two or More Conversion Factors Conversions Involving Volume Chapter Summary and Key Terms Learning Outcomes Key Equations Exercises Additional Exercises Chemistry Put to Work Chemistry and the Chemical Industry A Closer Look: The Scientific Method Chemistry Put to Work: Chemistry in the News Strategies for Success: Estimating Answers Strategies for Success: The Importance of Practice Strategies for Success: The Features of This Book 2 Atoms, Molecules, and Ions 2.1 The Atomic Theory of Matter 2.2 The Discovery of Atomic Structure Cathode Rays and Electrons Radioactivity The Nuclear Model of the Atom 2.3 The Modern View of Atomic Structure Atomic Numbers, Mass Numbers, and Isotopes 2.4 Atomic Weights The Atomic Mass Scale Atomic Weight 2.5 The Periodic Table 2.6 Molecules and Molecular Compounds Molecules and Chemical Formulas Molecular and Empirical Formulas Picturing Molecules 2.7 Ions and Ionic Compounds Predicting Ionic Charges Ionic Compounds 2.8 Naming Inorganic Compounds Names and Formulas of Ionic Compounds Names and Formulas of Acids Names and Formulas of Binary Molecular Compounds 2.9 Some Simple Organic Compounds Alkanes Some Derivatives of Alkanes Chapter Summary and Key Terms Learning Outcomes Key Equations Exercises Additional Exercises A Closer Look Basic Forces A Closer Look The Mass Spectrometer Chemistry and Life Elements Required by Living Organisms Strategies for Success: How to Take a Test 3 Chemical Reactions and Stoichiometry 3.1 The Conservation of Mass, Chemical Equations, and Stoichiometry How to Balance Chemical Equations A Step-by-Step Example of Balancing a Chemical Equation 3.2 Simple Patterns of Chemical Reactivity: Combination, Decomposition, and Combustion Combination and Decomposition Reactions Combustion Reactions 3.3 Formula Weights and Elemental Compositions of Substances Formula and Molecular Weights Elemental Compositions of Substances 3.4 Avogadro's Number and the Mole; Molar Mass The Mole and Avogadro's Number Molar Mass Converting Between Masses, Moles, and Atoms/Molecules/Ions 3.5 Formula Weights and Elemental Compositions of Substances Molecular Formulas from Empirical Formulas Combustion Analysis 3.6 Reaction Stoichiometry 3.7 Limiting Reactants Theoretical and Percent Yields Chapter Summary and Key Terms Learning Outcomes Key Equations Exercises Additional Exercises Integrative Exercises Design an Experiment Strategies for Success: Problem Solving Chemistry and Life: Glucose Monitoring Strategies for Success: Design an Experiment 4 Reactions in Aqueous Solution 4.1 General Properties of Aqueous Solutions Electrolytes and Nonelectrolytes How Compounds Dissolve in Water Strong and Weak Electrolytes 4.2 Precipitation Reactions Solubility Guidelines for Ionic Compounds Exchange (Metathesis) Reactions Ionic Equations and Spectator Ions 4.3 Acids, Bases, and Neutralization Reactions Acids Bases Strong and Weak Acids and Bases Identifying Strong and Weak Electrolytes Neutralization Reactions and Salts Neutralization Reactions with Gas Formation 4.4 Oxidation-Reduction Reactions Oxidation and Reduction Oxidation Numbers Oxidation of Metals by Acids and Salts The Activity Series 4.5 Concentrations of Solutions Molarity Expressing the Concentration of an Electrolyte Interconverting Molarity, Moles, and Volume Dilution 4.6 Solution Stoichiometry and Chemical Analysis Titrations Chapter Summary and Key Terms Learning Outcomes Key Equations Exercises Additional Exercises Integrative Exercises Design an Experiment Chemistry Put to Work Antacids Strategies for Success Analyzing Chemical Reactions 5 Thermochemistry 5.1 The Nature of Chemical Energy 5.2 The First Law of Thermodynamics System and Surroundings Internal Energy Relating Δf to Heat and Work Endothermic and Exothermic Processes State Functions 5.3 Enthalpy Pressure-Volume Work Enthalpy Change 5.4 Enthalpies of Reaction 5.5 Calorimetry Heat Capacity and Specific Heat Constant-Pressure Calorimetry Bomb Calorimetry (Constant-Volume Calorimetry) 5.6 Hess's Law 5.7 Enthalpies of Formation Using Enthalpies of Formation to Calculate Enthalpies of Reaction 5.8 Bond Enthalpies Bond Enthalpies and the Enthalpies of Reactions 5.9 Foods and Fuels Foods Fuels Other Energy Sources Chapter Summary and Key Terms Learning Outcomes Key Equations Exercises Additional Exercises Integrative Exercises Design an Experiment A Closer Look: Energy, Enthalpy, and P-V Work A Closer Look: Using Enthalpy as a Guide Chemistry and Life: The Regulation of Body Temperature Chemistry Put to Work: The Scientific and Political Challenges of Biofuels 6 Electronic Structure of Atoms 6.1 The Wave Nature of Light 6.2 Quantized Energy and Photons Hot Objects and the Quantization of Energy The Photoelectric Effect and Photons 6.3 Line Spectra and the Bohr Model Line Spectra Bohr's Model The Energy States of the Hydrogen Atom Limitations of the Bohr Model 6.4 The Wave Behavior of Matter The Uncertainty Principle 6.5 Quantum Mechanics and Atomic Orbitals Orbitals and Quantum Numbers 6.6 Representations of Orbitals The s Orbitals The p Orbitals The d and f Orbitals 6.7 Many-Electron Atoms Orbitals and Their Energies Electron Spin and the Pauli Exclusion Principle 6.8 Electron Configurations Hund's Rule Condensed Electron Configurations Transition Metals The Lanthanides and Actinides 6.9 Electron Configurations and the Periodic Table Anomalous Electron Configurations Chapter Summary and Key Terms Learning Outcomes Key Equations Exercises Additional Exercises Integrative Exercises Design an Experiment A Closer Look: Measurement and the Uncertainty Principle A Closer Look: Thought Experiments and Schrödinger's Cat A Closer Look: Probability Density and Radial Probability Functions Chemistry and Life Nuclear Spin and Magnetic Resonance Imaging 7 Periodic Properties of the Elements 7.1 Development of the Periodic Table 7.2 Effective Nuclear Charge 7.3 Sizes of Atoms and Ions Periodic Trends in Atomic Radii Periodic Trends in Ionic Radii 7.4 Ionization Energy Variations in Successive Ionization Energies Periodic Trends in First Ionization Energies Electron Configurations of Ions 7.5 Electron Affinity Periodic Trends in Electron Affinity 7.6 Metals, Nonmetals, and Metalloids Metals Nonmetals Metalloids 7.7 Trends for Group 1 and Group 2 Metals Group 1: The Alkali Metals Group 2: The Alkaline Earth Metals 7.8 Trends for Selected Nonmetals Hydrogen Group 16: The Oxygen Group Group 17: The Halogens Group 18: The Noble Gases Chapter Summary and Key Terms Learning Outcomes Key Equations Exercises Additional Exercises Integrative Exercises Design and Experiment A Closer Look: Effective Nuclear Charge Chemistry Put to Work: Ionic Size and Lithium-Ion Batteries Chemistry and Life: The Improbable Development of Lithium Drugs 8 Basic Concepts of Chemical Bonding 8.1 Lewis Symbols and the Octet Rule Lewis Symbols The Octet Rule 8.2 Ionic Bonding Energetics of Ionic Bond Formation Electron Configurations of Ions of the s- and p-Block Elements Transition Metal Ions 8.3 Covalent Bonding Lewis Structures Multiple Bonds 8.4 Bond Polarity and Electronegativity Electronegativity Electronegativity and Bond Polarity Dipole Moments Comparing Ionic and Covalent Bonding 8.5 Drawing Lewis Structures Formal Charge and Alternative Lewis Structures 8.6 Resonance 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Note: Contents Xu, J., Oppenheimer, C., Hammond, J.O.S. and Wei, H. / Perspectives on the active volcanoes of China Wei, H., Zhao, B., Chen, Z. and Yu, H. / Volcanic processes and magmatic evolution of Tianchi volcano, Changbaishan Zhao, B., Xu, D., Bai, Z. and Chen, Z. / Volcanism in the Longgang volcanic field of NE China: insights from eruption history, volcano types and geochemical characteristics Bai, X., Wei, W., Yu, H. and Chen, Z. / Petrogenesis and dynamic implications of the Cenozoic alkali basalts from the Jingpohu Volcanic Field, NE China Chen, Z., Zhao, Y., Bai, X., Wei, W., Liu, Y. and Bai, Z. / Wudalianchi volcanic field, NE China: tectonic setting, eruptive history, and geophysical insights Zhao, Y.-W., Zou, H. and Li, N. / Geomorphology and geochemistry of the Late Cenozoic volcanoes in the Halaha River–Chaoer River volcanic fields, western Greater Hinggan Mountain Range, NE China Li, N., Zhao, Y.-W., Gong, L.-W. and Wang, J.-L. / The Late Cenozoic volcanic groups in the South Daxing’anling, NE China: geology, geochemistry, and chronology Hong, L., Zhang, Y., Zhang, L., Xu, Y.-G., Liu, Z. and He, P. / Olivine chemistry of the Quaternary Datong basalts of the Trans-North China Orogen: insights into mantle source lithology and redox–hydration state Xu, J., Zhao, B., Yu, H., Wei, F. and Chen, Z. / Volcanic geology and petrochemistry of Ashikule volcanic field in western Kunlun Mountains of the Tibetan plateau Zhao, B., Wei, F., Yang, W., Xu, J. and Cui, X. / Cenozoic volcanism along Dahongliutan fault in the West Kunlun Mountains, China: implication from distribution of volcanic rocks, volcanic geology, and geochemistry Yu, H., Zhao, B., Chen, Z., Wei, H., Yang, W. and Bai, X. / Eruption history, petrogeochemistry, and geodynamic background of Tengchong volcanoes in Yunnan Province, SW China Wei, F., Wei, W. and Yu, H. / The Cenozoic volcanic fields in northern Hainan Island and the Leizhou Peninsula, south China: eruption history, magma source and dynamic background Yu, W., Wei, W., Wei, F., Bai, X., Liu, S. and Xu, D./ Magma plumbing system and origin of the intraplate volcanoes in Mainland China: an overview of constraints from geophysical imaging Ji, L., Xu, J., Liu, L. and Zhang, W. / A review of present-day deformation of active volcanoes in China between 1970 and 2013 Pan, B., Liu, G., Cheng, T., Zhang, J., Sun, Z., Ma, B., Wu, H., Liang, G., Guo, M., Kong, Q., Wei, F., Zhao, C. and Zhao, Q. / Development and status of active volcano monitoring in China Liang, Y. and Xu, J. / The impact of volcanic ash on the safety of aviation industry: review of China’s current situation Wang, X., Pan, B., Pan, M. and Liang, Y. / Current situation of early warning and emergency countermeasures of volcanic eruptions in China Chen, Z. and Chen, Z. / Identifying references to volcanic eruptions in Chinese historical records Pan, B., Cheng, T., Xu, J., Zhang, J. and Chen, Z. / Knowledge base of Cenozoic volcanoes in China Index