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  • 2020-2024  (5)
  • 1995-1999  (48)
  • 1990-1994  (73)
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  • 1
    Monographie ausleihbar
    Monographie ausleihbar
    New York [u.a.] : Oxford University Press
    Signatur: M 08.0276
    Beschreibung / Inhaltsverzeichnis: This text describes the full range of charts, graphs, maps, diagrams and tables used daily to manage, analyze and communicate information. It features over 3000 illustrations, acting as a source on presenting information for anyone who writes or designs reports.
    Materialart: Monographie ausleihbar
    Seiten: 448 S.
    ISBN: 9780195135329
    Standort: Kompaktmagazin oben
    Zweigbibliothek: GFZ Bibliothek
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2024-03-22
    Beschreibung: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Heat flow is estimated at eight sites drilled int the Guaymas Basin, Gulf of California, during the International Ocean Discovery Program Expedition 385. The expedition sought to understand the thermal regime of the basin and heat transfer between off‐axis sills intruding the organic‐rich sediments of the Guaymas Basin, and the basin floor. The distinct sedimentation rates, active tectonics, and magmatism make the basin interesting for scientific discoveries. Results show that sedimentation corrected heat flow values range 119–221 mW/m〈sup〉2〈/sup〉 in the basin and 257–1003 mW/m〈sup〉2〈/sup〉 at the site of a young sill intrusion, denominated Ringvent. Thermal analysis shows that heat in the Guaymas Basin is being dissipated by conduction for plate ages >0.2 Ma, whereas younger plate ages are in a state of transient cooling by both conduction and advection. Drilling sites show that Ringvent is an active sill being cooled down slowly by circulating fluids with discharge velocities of 10–200 mm/yr. Possible recharge sites are located ca. 1 km away from the sill's border. Modelling of the heat output at Ringvent indicates a sill thickness of ca. 240 m. A simple order‐of‐magnitude model predicts that relatively small amounts of magma are needed to account for the elevated heat flow in non‐volcanic, sediment‐filled rifts like the central and northern Gulf of California in which heating of the upper crust is achieved via advection by sill emplacement and hydrothermal circulation. Multiple timescales of cooling control the crustal, chemical and biological evolution of the Guaymas Basin. Here, we recognize at least four timescales: the time interval between intrusions (ca. 10〈sup〉3〈/sup〉 yr), the thermal relaxation time of sills (ca. 10〈sup〉4〈/sup〉 yr), the characteristic cooling time of the sediments (ca. 10〈sup〉5〈/sup〉 yr), and the cooling of the entire crust at geologic timescales.〈/p〉
    Beschreibung: Centro de Investigación Científica y de Educación Superior de Ensenada, Baja California http://dx.doi.org/10.13039/501100003089
    Beschreibung: German Research Center for Geosciences
    Beschreibung: https://web.iodp.tamu.edu/LORE/
    Beschreibung: https://mlp.ldeo.columbia.edu/logdb/scientific_ocean_drilling/
    Schlagwort(e): ddc:551.1 ; Guyamas Basin ; Heat Flow ; Heat Transfer ; IODP Expedition 385
    Sprache: Englisch
    Materialart: doc-type:article
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 6975-6990 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The dynamics of an adsorbate described by a two-band generalization of the small-polaron model [J. Chem. Phys. 95, 8599 (1991)] are investigated. Lattice induced mixing of the bands can result in the adsorbates becoming self-trapped at one end of an adsorption site or the other. Tunneling between adjacent sites can either preserve or change the end of the site in which the adsorbate resides. The associated rates have very different temperature and mass dependences, and contribute to the overall diffusion in very different ways. The observed equilibrium and transport properties of the H/W(110) system can be consistently explained within our model.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 8599-8615 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: A two-band generalization of the Hubbard model is developed in order to examine the different roles of adsorbate interactions with one another and with phonons. Variationally optimized unitary transformations of the Hamiltonian are performed in order to obtain dressed tunneling amplitudes. These display strong dimensional dependence and demonstrate fundamental differences between the effects of coupling of adsorbate density and of adsorbate vibrational excitation to the lattice modes. The occurrence of on-site asymmetric self-trapping induced by even weak coupling of interband excitations to the lattice is demonstrated, and the effect of this on the thermally averaged, intersite tunneling is investigated. Implications for surface transport and for surface reconstructions of hydrogen/metal systems are made.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 96 (1992), S. 2437-2443 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: This paper extends the McClain formulation of two-photon absorption to show what observables can be independently determined in an emission experiment for which incident and scattered photon polarizations are resolved. Interelectronic state coupling contributions and quantum interference can be extracted from the polarized emission spectrum by determining the three linearly independent contributions to the scattering intensity. This enhances the value of polarized emission spectroscopy as a tool for understanding transitions between coupled electronic states that occur during dissociation dynamics. We demonstrate that the three linearly independent contributions to the polarized emission spectrum can be determined by performing three polarization experiments, at least one of which must involve circularly polarized light. Furthermore, the three polarization experiments must be performed at a scattering angle other than π/2. We also present sample calculations on a model of the methyl iodide system which serve as an illustration of the general theory and demonstrate the sensitivity of this technique to the details of the potential-energy surfaces.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 94 (1991), S. 6995-7002 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: Motion of nuclei within a molecule induces a magnetic moment me in the electronic charge distribution, giving a nonzero electronic contribution to the magnetic transition dipole that produces vibrational circular dichroism. In this paper, we develop a new susceptibility density theory for the induced magnetic moment. The theory is based on the response of the electrons to changes in the nuclear Coulomb field, due to shifts in nuclear positions. The electronic response to these changes depends on the same susceptibility densities that determine response to external fields. Our analysis suggests a new physical picture of vibrational circular dichroism. It yields an equation for the density of the induced electronic magnetic moment within a molecule; it also yields a new relation connecting the electric-field shielding at nucleus I of a molecule in an applied magnetic field of frequency ω to the derivative of me with respect to the velocity of nucleus I, regarded as a parameter in the electronic wave function. Within our theory, the derivative of me with respect to nuclear velocity separates into quantum-mechanical and classical components in close analogy with the Hellmann–Feynman theorem for forces on nuclei. In matrix-element form, results from our theory are identical to those obtained with nonadiabatic perturbation theory, to leading order. In general, the leading nonadiabatic corrections to electronic properties are determined directly by the electrons' response to the changes in the nuclear Coulomb field, when the nuclei move.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 6687-6696 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: Electron densities obtained from a ground state path integral approach to density functional theory using a primitive Monte Carlo method display large statistical uncertainties when short wavelength fluctuations of the paths are considered directly. An optimized Thomas–Fermi approximation is developed to eliminate these degrees of freedom in a systematic and physically motivated fashion. Beyond improving the precision of the numerical results, this theoretical development permits a simple qualitative discussion of how the calculation pushes electron density into tunneling regions by iteratively renormalizing the Fermi wavelength appropriate to the remaining integrations which involve only long wavelength coordinates.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 98 (1993), S. 2077-2093 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: A multiband tight binding model of the metal trihydrides, including on-site repulsion and exchange, is examined. By linearly coupling the system to a harmonic bath we show that the multiband model yields an effective temperature dependent Heisenberg spin Hamiltonian. This system exhibits a temperature dependent competition between ferro- and antiferromagnetic exchange spin couplings. The resulting spin spectrum is consistent with observed anomalous isotope dependent metal trihydride H-N.M.R. spectra.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 7652-7663 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The model of Hiller and Harris [J. Chem. Phys. 98, 2077 (1993)] is modified by a Jastrow correlation function to incorporate short-range correlations. The resulting model describes exchange in the metal trihydrides at low temperature. Direct and virtual exchange processes are compared for upper and lower bounds to the repulsive proton–proton potential, eight different locally isotropic double-well frequencies, and four well separations. Exchange through the virtual double-occupancy state dominates the coupling, although direct exchange significantly renormalizes the tunneling matrix element. It is shown that a simpler two-state Jastrow–Gaussian Heitler–London basis used in other calculations suffers in this strongly correlated system.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    ISSN: 1520-4995
    Quelle: ACS Legacy Archives
    Thema: Biologie , Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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