ISSN:
1572-9028
Keywords:
iron–molybdenum–antimony catalysts
;
solid-state reactions in catalysts
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Catalysts were prepared by impregnation of Fe2(MoO4)3 with different quantities of antimony butoxide. BET surface area measurement, XRD, Mössbauer spectroscopy, CTEM-AEM, XPS and ISS were used to characterize phase and surface architectures and their changes after calcination and catalytic reaction. Before calcination, antimony was present as pure oxide or hydroxide, partly as particles and partly as an incomplete monolayer on the surface of Fe2(MoO4)3. After calcination at 400°C, antimony got detached from the Fe2(MoO4)3 surface and aggregated very intensively, partly as Sb2O4 and partly, through reaction with the iron molybdate, as a mixture of distorted FeSbO4 and MoO3. After reaction or calcination at 500°C, more distorted FeSbO4 and MoO3 are formed, separated from Fe2(MoO4)3. Selective oxidation of isobutene to methacrolein was carried out on the calcined material. Impregnated catalysts show considerably improved catalytic performances compared to the pure Fe2(MoO4)3 phase or mechanical mixtures of it with α-Sb2O4. The catalytic performances are explained by several catalytic cooperations via spillover oxygen. These cooperative effects involve all the oxide phases present in the material having worked as catalyst: Fe2(MoO4)3 (pure or possibly contaminated by small amounts of antimony oxide), FeSbO4, MoO3 and SbyOx.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1027287528394
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