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  • Wiley  (47)
  • International Union of Crystallography (IUC)  (16)
  • Seismological Society of America  (13)
  • 2020-2024  (1)
  • 2010-2014  (75)
  • 1
    Publication Date: 2012-02-12
    Description: In the title compound, C15H12I2N2O4·CH3OH, the hydrazone molecule exists in an E conformation with respect to the C=N bond. The dihedral angle between the rings is 11.9 (2)°. There is one intramolecular O—H...N hydrogen bond in the hydrazone molecule. In the crystal, the hydrazone and methanol molecules are linked through O—H...O and N—H...O hydrogen bonds and C—H...O interactions to form two-dimensional networks lying parallel to (001).
    Electronic ISSN: 1600-5368
    Topics: Chemistry and Pharmacology , Geosciences
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  • 2
    Publication Date: 2012-12-12
    Description: Due to its low water solubility and slow dissolution rate, genipin was micronized by an antisolvent precipitation process using ethanol as solvent and n -hexane as antisolvent. The effects of various experimental parameters on the mean particle size (MPS) of micronized genipin were investigated. By analysis of variance, only the concentration of the genipin solution has a significant effect on the MPS in genipin micronization. Under the optimum conditions, micronized genipin with an MPS of 1.8 μm was obtained. The micronized genipin was characterized by various methods, e.g., scanning electron microscopy and thermogravimetry. The analysis results indicated that the chemical structure of micronized genipin was not changed, but the crystallinity was reduced. The dissolution rate and solubility of the micronized genipin were 2.08 and 1.64 times that of the raw drug. In addition, the residual amounts of n -hexane and ethanol were less than the International Conference on Harmonization limit for solvents. Micronized genipin with a mean particle size of 1.8 μm was prepared by the antisolvent precipitation process. The chemical structure of micronized genipin remained unchanged, but the crystallinity was reduced. The dissolution rate and solubility of the micronized genipin were 2.08 and 1.64 times that of the raw drug, and the amounts of residual n -hexane and ethanol were lower than the International Conference on Harmonization limit for solvents.
    Print ISSN: 0930-7516
    Electronic ISSN: 1521-4125
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley
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  • 3
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    International Union of Crystallography (IUC)
    Publication Date: 2012-04-07
    Description: The title compound, C14H13NO4, was prepared through a palladium-catalysed Suzuki–Miyaura coupling reaction. The asymmetric unit comprises two molecules related by pseudo-inversion symmetry. The dihedral angles between the benzene rings in the two molecules are 44.30 (6) and 48.50 (6)° while those between the benzene ring and the nitro group are 6.54 (13) and 5.73 (10)°. The crystal packing is defined only by Van der Waals interactions.
    Electronic ISSN: 1600-5368
    Topics: Chemistry and Pharmacology , Geosciences
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  • 4
    Publication Date: 2012-04-15
    Description: A novel chemical soft-sensor approach for the prediction of the melt index (MI) in the propylene polymerization industry is presented. The MI is considered as one of the important variables of quality that determine the product specifications. Thus, a reliable estimation of the MI is crucial in quality control. An accurate optimal predictive model of MI values with the relevance vector machine (RVM) is proposed, where the RVM is employed to build the MI prediction model; a modified particle swarm optimization (MPSO) algorithm is then introduced to optimize the parameter of the RVM, and the MPSO-RVM model is thereby developed. An online correcting strategy (OCS) is further carried out to update the modeling data and to revise the model's parameter self-adaptively whenever model mismatch happens. Based on the data from a real polypropylene production plant, a detailed comparison is carried out among the least squares support vector machine (LS-SVM), RVM, MPSO-RVM, and OCS-MPSO-RVM models. The research results reveal the prediction accuracy and validity of the proposed approach. A chemical soft-sensor approach for the prediction of the melt index (MI) in the propylene polymeriza-tion industry is presented. The relevance vector machine (RVM) is employed to build the MI prediction model. A modified particle swarm optimization algorithm is then introduced to optimize the parameter of the RVM and an online correcting strategy is carried out to update the modeling data.
    Print ISSN: 0930-7516
    Electronic ISSN: 1521-4125
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 5
    Publication Date: 2012-08-29
    Description: Using the PPMLR-MHD global simulation model, we examined the Kelvin-Helmholtz (K-H) instability at the low-latitude boundary layer (LLBL) under northward interplanetary magnetic field (IMF) conditions with various solar wind speeds (400, 600, and 800 km/s). The spatial distribution of the K-H wave power in the equatorial plane shows two distinct power populations, referring to the two modes of K-H surface waves. The spatial evolution of K-H instability at the boundary layer is classified into four phases: quasi-stable, exponential growth, linear growth, and nonlinear phases. The boundary layer is quasi-stable near the subsolar point region. The K-H instability starts at about 30° longitude, and grows exponentially with a spatial growth rate of 0.28∼0.87 RE−1 until ∼45° longitude where the vortices fully develop. At larger longitudes, the instability grows linearly, while the vortices grow in size. From ∼80° longitude to the distant magnetotail, the K-H instability develops nonlinearly and the vortices roll up. The wave frequency, wavelength, and phase speed are given at various spatial points. Model results show that the higher solar wind speed generates K-H waves with higher frequency under the northward IMF, and the wavelengths and the phase speeds increase with the increase of the longitude. Moreover, we made a comparison of the K-H wave periods on Earth's, Mercury's and Saturn's magnetopauses by a proposed prediction method.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 6
    Publication Date: 2012-06-07
    Description: Slow shock formation and structure associated with magnetic reconnection are investigated in the presence of sub-Alfvénic shear flow using a compressible resistive MHD model. It is found for the first time that one or two pairs of the slow shocks are formed in the inflow region away from the reconnection separatrices within compressible resistive MHD. The distributions of the slow shocks depend largely on the plasma beta and the shear flow velocity that lead to the increase of magnetic reconnection rate. One pair of the slow shocks is formed for β = 0.2 and two pairs of the slow shocks are generated for β = 1.0 with the shear flow velocity in the range 0.6 VA to 0.9 VA. For high plasma beta (β = 5.0), there is no slow shock formed outside the reconnection separatrices. The results can be applied to interpret slow shock observations at the dayside magnetopause.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 7
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    International Union of Crystallography (IUC)
    Publication Date: 2012-06-11
    Description: The title compound, (C10H10N2)[Co(H2O)6](SO4)2, consists of 4,4′-bipyridinium dications, hexaaquacobalt(II) cations and sulfate anions that are linked by hydrogen bonds into a network structure. Six water molecules are coordinated to the Co atom and the geometry is octahedral. The bipyridinium cation has site symmetry 2 and the Co atom lies on a position of site symmetry 2/m.
    Electronic ISSN: 1600-5368
    Topics: Chemistry and Pharmacology , Geosciences
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  • 8
    Publication Date: 2011-11-17
    Description: The structure of the title salt complex, [Fe(C12H8N3O2)2]ClO4·H2O, contains one FeIII cation, two N-(pyridin-2-ylcarbonyl)pyridine-2-carboxamidate (bpca−) anions, one perchlorate anion and one water molecule. The FeIII cation has an approximate octahedral geometry, defined by six N atoms from two bpca− anions. The nearly parallel [dihedral angle = 1.50 (1)°] bpca− anions form two-dimensional supermolecules along the a axis by the way of weak π–π stacking inteactirons [centroid–centroid distances = 3.948 (2), 4.000 (2), 3.948 (2), 3.911 (2), 3.897 (2), 3.984 (2) and 3.929 (2) Å]. Intra- and intermolecular C—H...O hydrogen bonding occurs. The water molecule [occupancies 0.520 (5) and 0.480 (5)], two carbonyl O atoms [occupancies 0.622 (7) and 0.378 (7)] and the four perchlorate O atoms [occupancies 0.887 (4) and 0.113 (4)] are each disordered over two positions.
    Electronic ISSN: 1600-5368
    Topics: Chemistry and Pharmacology , Geosciences
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  • 9
    Publication Date: 2011-06-04
    Description: In the title compound, [Zn(NCS)2(C10H15N3)], the Zn atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two N atoms from two thiocyanate anions, forming a distorted ZnN5 trigonal–bipyramidal coordination geometry for the metal ion. The side chain of the ligand is disordered over two sets of sites in a 0.655 (12):0.345 (12) ratio. In the crystal, molecules are linked by N—H...S hydrogen bonds, generating [100] chains.
    Electronic ISSN: 1600-5368
    Topics: Chemistry and Pharmacology , Geosciences
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  • 10
    Publication Date: 2013-12-08
    Description: The dielectric and ferroelectric characteristics of ( Sr x Ba 1− x ) Nb 2 O 6 unfilled tungsten bronze ceramics have been investigated together with the structure. The dielectric and ferroelectric characteristics of the present ceramics vary significantly with x , and the A1/A2-sites occupancy has been determined as the primary parameter governing this variation tendency. Ba ions tend to occupy A2-sites, Sr ions tend to occupy A1-sites, and one A1-site is empty. When the ratio of Sr / Ba is close to 1:4 (where four A2-sites are just occupied by Ba ions, and one A1-site is occupied by Sr ion while another A1-site is empty), the normal ferroelectric transition is observed with one anomaly in the tanδ– T curve ( x  = 0.25). When the ratio of Sr / Ba is far away from 1:4, the typical relaxor behavior is indicated together with three anomalies in the tanδ– T curve ( x  = 0.75). The incommensurate oxygen octahedral tilting and A-site random distribution are considered to be the structure origins for the relaxor ferroelectricity and low temperature dielectric relaxations.
    Print ISSN: 0002-7820
    Electronic ISSN: 1551-2916
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Wiley
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