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  • LUNAR AND PLANETARY EXPLORATION  (3)
  • Atomic, Molecular and Optical Physics  (2)
  • 2020-2024
  • 2010-2014
  • 1975-1979  (5)
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  • 1
    Publication Date: 2019-07-13
    Description: Ca has been measured in a lunar soil in order to establish the presence of isotopically mass-fractionated components. Ca was extracted by a series of water leaches after the soils were 'activated' by brief exposures to fluorine gas. The O2 obtained by this fluorination is found to have delta (O-18) of +21 per mil and to be, therefore, significantly mass-fractionated. Ca obtained in the leaches was analyzed using the double-spike technique. Very small Ca isotope fractionation is found in the leaches of this soil of up to 1 per mil per mass unit difference. The small Ca effects are in marked contrast to the measured delta (O-18) for the same sample and to large effects observed in many soils for oxygen, silicon, sulfur, and potassium. The data on Ca provide stringent constraints on models which attempt to explain the isotope mass-fractionation effects in lunar soils.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Lunar Science Conference; Mar 14, 1977 - Mar 18, 1977; Houston, TX
    Format: text
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  • 2
    Publication Date: 2019-07-13
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Lunar Science Conference; Mar 17, 1975 - Mar 21, 1975; Houston, TX
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  • 3
    Publication Date: 2019-07-13
    Description: The variations of Si-30/Si-28 and Si-29/Si-28 in Allende inclusions are large, and are due predominantly to mass-dependent fractionation effects. Gas-soild or gas-liquid condensation processes at high temperatures have sufficiently large fractionation factors to account for the heavy-isotope enrichments in coarse-grained inclusions. Heavy isotope depletions are found in some Allende samples, and apparently result from a late-stage condensation. Thus, the silicon isotopic compositions may be useful for determining the sequence of events in forming the Allende meteorite. The peculiar Allende inclusion, Cl, has a very large mass-fractionated enrichment of Si-30/Si-28, and in addition, perhaps a small nuclear enrichment of Si-29. Olivine from the unusual pallasite, Eagle Station, has normal silicon isotope abundances even though it has a large O-16 excess.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Lunar and Planetary Science Conference; Mar 13, 1978 - Mar 17, 1978; Houston, TX
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 11 (1977), S. 881-884 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Some of Moccia's formulas (Int. J. Quant. Chem. 8, 293 (1974)) for corrections to “not completely optimized variational parameters” are compared with those resulting from a perturbation theory analysis. It is not possible to choose the zero-order Hamiltonian (at least not in any simple way) so as to get exact agreement, but one choice does come close.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 15 (1979), S. 147-167 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We consider the problem of determining variational, external-field-dependent corrections to nonoptimal zero-field nonlinear parameters. Both a direct analytic perturbation analysis and finite perturbation methods are described in a general way and in detail for the SCF approximation. The abstract theory is illustrated by reference to the results of several explicit calculations. Also, the sensitivity of the results to the choice of zero-field values is discussed.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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