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  • Analytical Chemistry and Spectroscopy  (1)
  • Atm/Ocean Structure/ Phenomena  (1)
  • 2020-2024
  • 2010-2014  (1)
  • 1985-1989  (1)
  • 1
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Self-chemical ionization Fourier transform ion cyclotron resonance (FT-ICR) mass spectra are reported for bases, nucleosides, and alkylated and exocyclic adducts of bases and nucleosides. The technique always produces a protonated molecular ion and in the majority of cases this is a single, intense peak. Analysis of a base mixture and a nucleoside mixture demonstrates the technique as an excellent method to identify the constituent compounds qualitatively. The high resolution capabilities and tandem mass spectrometric techniques (msn) in FT-ICR are discussed with respect to developing the technique as a future method to identify and characterize nucleic acid constituents, specifically adducts.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2014. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 44 (2014): 2569–2587, doi:10.1175/JPO-D-14-0026.1.
    Description: This paper describes the occurrence of diurnal restratification events found in the southeast trade wind regime off northern Chile. This is a region where persistent marine stratus clouds are found and where there is a less than complete understanding of the dynamics that govern the maintenance of the sea surface temperature. A surface mooring deployed in the region provides surface meteorological, air–sea flux, and upper-ocean temperature, salinity, and velocity data. In the presence of steady southeast trade winds and strong evaporation, a warm, salty surface mixed layer is found in the upper ocean. During the year, these trade winds, at times, drop dramatically and surface heating leads to the formation of shallow, warm diurnal mixed layers over one to several days. At the end of such a low wind period, mean sea surface temperature is warmer. Though magnitudes of the individual diurnal warming events are consistent with local forcing, as judged by running a one-dimensional model, the net warming at the end of a low wind event is more difficult to predict. This is found to stem from differences between the observed and predicted near-inertial shear and the depths over which the warmed water is distributed. As a result, the evolution of SST has a dependency on these diurnal restratification events and on near-surface processes that govern the depth over which the heat gained during such events is distributed.
    Description: RAW was supported by the NOAA Climate Program Office. SM and AT were supported by NASA Grant NNX12AD47G,ONR Grant N000140910196, and NSF-OCE 0928138 RAW.
    Description: 2015-03-01
    Keywords: Atm/Ocean Structure/ Phenomena ; Atmosphere-ocean interaction ; Boundary layer ; Diurnal effects ; Mixed layer
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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