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  • Elsevier  (2)
  • American Chemical Society  (1)
  • American Society of Hematology
  • Blackwell Publishing Ltd
  • 2020-2023  (3)
  • 1
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    Assessment of potentially toxic elements (PTEs) sources on soils surrounding a fossil fuel power plant in a semi-arid/arid environment: A case study from the Sonoran Desert (2022)
    Elsevier
    Details
    Publication Date: 2022-03-07
    Description: Understanding the sources of potentially toxic elements (PTEs) in soils is a worldwide challenge that requires effective discrimination between geogenic and anthropogenic contributions, particularly in areas with certain geological complexity. This study aims to examine the chemical contents of 23 topsoil samples collected from the surroundings of a fossil fuel power plant in the village of Puerto Libertad (Sonoran Desert, Mexico). The study did not exclusively focus on the source identification of the priority PTEs to evaluate soil pollution. Furthermore, major oxides and immobile trace element (Zr, Hf, and REE: La→Lu) data were provided for a reliable assessment of the provenance of the soils. The relatively high SiO2 contents (65.26–75.42 wt%, anhydrous basis), the Post-Archean Australian Shale (PAAS)-normalized REE patterns, and the uniformity of the values of the Index of Compositional Variability (ICV = 1.11–2.72) and the Chemical Index of Alteration (CIA = 31.65–51.79) suggest that the soils were derived from intermediate to felsic source rocks, controlled by the local weathering of the parent bedrocks, under a low degree of chemical weathering conditions. The PTE data were treated following a robust workflow, which included the use of the enrichment factor (EF), the Spearman rank correlation (ρ), and multivariate statistical analyses allowed the generation of significant elemental associations and the identification of pools related either to the geological background or to anthropogenic activities. The results suggesting that Mo and Zn concentrations present a moderate anthropogenic influence while the concentrations of Pb, Sn, Cu, Cd, As, Cr, and Co are predominantly of geogenic origin. Vanadium (avg. EFV = 3.4) and Ni (avg. EFNi = 4.6) were the most enriched elements in the soils. Moreover, the highest values of the integrated Nemerow Pollution Index (PIN〉3) were recorded at the sampling stations closer to the village, suggesting point-source pollution by the emissions of the power station. Finally, in this paper is traced the extent of the particulate released into the atmosphere, which can be dispersed in a wide area into the Sonoran Desert.
    Description: Published
    Description: 105158
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Environmental geochemistry ; Geogenic sources ; Anthropogenic impact ; Provenance ; Power plant pollution ; Puerto libertad ; PTEs ; Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Carbon dioxide diffuse emission at the Tolhuaca hydrothermal system (Chile) controlled by tectonics and topography (2022)
    Elsevier
    Details
    Publication Date: 2022-02-11
    Description: The Tolhuaca hydrothermal system is one of the few attested geothermal resources in Chile. While recent investigations provided some insights into the depth and temperature of the geothermal reservoirs and the chemical and mineralogical evolution of the hydrothermal system, little is still known about the CO2 degassing of the system and the local and shallow control of fluid pathways. Here, we document the soil CO2 degassing and soil temperature distributions in the southern part of the Tolhuaca hydrothermal system and at one of its northern fumaroles, and provide a first estimate of its total CO2 release. The surveyed area is responsible for a total CO2 emission of up to 30 t d-1. Hydrothermal CO2 emissions (~ 4-27 t d-1) are mostly restricted to the thermal manifestations or generally distributed along NNW trending lineaments, sharing the same orientation as the volcanic vents and thermal springs and fumaroles. Hydrothermal CO2 fluxes, fumaroles and thermal springs are generally encountered in topographic lows, in close vicinity of streams and often in clay-rich pyroclastic units, highlighting a relation between landscape evolution and the activity of the hydrothermal system. We suggest that glacial unloading and incision of the stream inside the clay-rich units have likely enhanced locally the permeability, creating a preferential pathway for the migration of deeper fluid to the surface. As several hydrothermal systems in the Andes are found on the flank of volcanoes hosting glaciers, we propose that they could have had a similar development to that of the Tolhuaca hydrothermal system.
    Description: Published
    Description: 107316
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: CO2 emission ; Tolhuaca volcano
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Quantification of amine- and alcohol-containing metabolites in saline samples using pre-extraction benzoyl chloride derivatization and ultrahigh performance liquid chromatography tandem mass spectrometry (UHPLC MS/MS) (2021)
    American Chemical Society
    Details
    Publication Date: 2022-05-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Widner, B., Kido Soule, M. C., Ferrer-González, F. X., Moran, M. A., & Kujawinski, E. B. Quantification of amine- and alcohol-containing metabolites in saline samples using pre-extraction benzoyl chloride derivatization and ultrahigh performance liquid chromatography tandem mass spectrometry (UHPLC MS/MS). Analytical Chemistry, 93(11), (2021): 4809-4817, https://doi.org/10.1021/acs.analchem.0c03769.
    Description: Dissolved metabolites serve as nutrition, energy, and chemical signals for microbial systems. However, the full scope and magnitude of these processes in marine systems are unknown, largely due to insufficient methods, including poor extraction of small, polar compounds using common solid-phase extraction resins. Here, we utilized pre-extraction derivatization and ultrahigh performance liquid chromatography electrospray ionization tandem mass spectrometry (UHPLC-ESI-MS/MS) to detect and quantify targeted dissolved metabolites in seawater and saline culture media. Metabolites were derivatized with benzoyl chloride by their primary and secondary amine and alcohol functionalities and quantified using stable isotope-labeled internal standards (SIL-ISs) produced from 13C6-labeled benzoyl chloride. We optimized derivatization, extraction, and sample preparation for field and culture samples and evaluated matrix-derived biases. We have optimized this quantitative method for 73 common metabolites, of which 50 cannot be quantified without derivatization due to low extraction efficiencies. Of the 73 metabolites, 66 were identified in either culture media or seawater and 45 of those were quantified. This derivatization method is sensitive (detection limits = pM to nM), rapid (∼5 min per sample), and high throughput.
    Description: Funding included the Gordon and Betty Moore Foundation (Award GBMF5503 to M.A.M. and E.B.K.), Simons Foundation International (Award 409923 to E.B.K.), and the National Science Foundation (Award 1656311 to M.A.M.).
    Repository Name: Woods Hole Open Access Server
    Type: Article
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