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  • 1
    Publication Date: 2022-10-27
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Riedel, M., Rohr, K. M. M., Spence, G. D., Kelley, D., Delaney, J., Lapham, L., Pohlman, J. W., Hyndman, R. D., & Willoughby, E. C. Focused fluid flow along the Nootka fault zone and continental slope, explorer-Juan de Fuca Plate Boundary. Geochemistry Geophysics Geosystems, 21(8), (2020): e2020GC009095, doi:10.1029/2020GC009095.
    Description: Geophysical and geochemical data indicate there is abundant fluid expulsion in the Nootka fault zone (NFZ) between the Juan de Fuca and Explorer plates and the Nootka continental slope. Here we combine observations from 〉20 years of investigations to demonstrate the nature of fluid‐flow along the NFZ, which is the seismically most active region off Vancouver Island. Seismicity reaching down to the upper mantle is linked to near‐seafloor manifestation of fluid flow through a network of faults. Along the two main fault traces, seismic reflection data imaged bright spots 100–300 m below seafloor that lie above changes in basement topography. The bright spots are conformable to sediment layering, show opposite‐to‐seafloor reflection polarity, and are associated with frequency reduction and velocity push‐down indicating the presence of gas in the sediments. Two seafloor mounds ~15 km seaward of the Nootka slope are underlain by deep, nonconformable high‐amplitude reflective zones. Measurements in the water column above one mound revealed a plume of warm water, and bottom‐video observations imaged hydrothermal vent system biota. Pore fluids from a core at this mound contain predominately microbial methane (C1) with a high proportion of ethane (C2) yielding C1/C2 ratios 〈500 indicating a possible slight contribution from a deep source. We infer the reflective zones beneath the two mounds are basaltic intrusions that create hydrothermal circulation within the overlying sediments. Across the Nootka continental slope, gas hydrate‐related bottom‐simulating reflectors are widespread and occur at depths indicating heat flow values of 80–90 mW/m2.
    Description: This study represents data from numerous cruises acquired over more than two decades. We would like to thank all the scientific personnel and technical staff involved in data acquisition, processing of samples, and making observations during the ROV dives, as well as the crews and captains of the various research vessels involved. This is contribution #5877 from the University of Maryland Center for Environmental Science. This is NRCan contribution number / Numéro de contribution de RNCan: 20200324.
    Keywords: Fluid flow ; Nootka transform fault ; Gas hydrate ; Intrusion ; Heat flow
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-10-27
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ruppel, C. D., & Waite, W. F. Timescales and processes of methane hydrate formation and breakdown, with application to geologic systems. Journal of Geophysical Research: Solid Earth, 125(8), (2020): e2018JB016459, doi:10.1029/2018JB016459.
    Description: Gas hydrate is an ice‐like form of water and low molecular weight gas stable at temperatures of roughly −10°C to 25°C and pressures of ~3 to 30 MPa in geologic systems. Natural gas hydrates sequester an estimated one sixth of Earth's methane and are found primarily in deepwater marine sediments on continental margins, but also in permafrost areas and under continental ice sheets. When gas hydrate is removed from its stability field, its breakdown has implications for the global carbon cycle, ocean chemistry, marine geohazards, and interactions between the geosphere and the ocean‐atmosphere system. Gas hydrate breakdown can also be artificially driven as a component of studies assessing the resource potential of these deposits. Furthermore, geologic processes and perturbations to the ocean‐atmosphere system (e.g., warming temperatures) can cause not only dissociation, but also more widespread dissolution of hydrate or even formation of new hydrate in reservoirs. Linkages between gas hydrate and disparate aspects of Earth's near‐surface physical, chemical, and biological systems render an assessment of the rates and processes affecting the persistence of gas hydrate an appropriate Centennial Grand Challenge. This paper reviews the thermodynamic controls on methane hydrate stability and then describes the relative importance of kinetic, mass transfer, and heat transfer processes in the formation and breakdown (dissociation and dissolution) of gas hydrate. Results from numerical modeling, laboratory, and some field studies are used to summarize the rates of hydrate formation and breakdown, followed by an extensive treatment of hydrate dynamics in marine and cryospheric gas hydrate systems.
    Description: Both authors have received nearly two decades of support from the U.S. Geological Survey's (USGS's) Energy Resources Program and the Coastal/Marine Hazards and Resources Program and from numerous DOE‐USGS Interagency Agreements, most recently DE‐FE0023495. C. R. acknowledges support from NOAA's Office of Ocean Exploration and Research (OER) under NOAA‐USGS Interagency Agreement 16‐01118.
    Keywords: Gas hydrate ; Hydrate breakdown ; Hydrate formation ; Permafrost hydrate ; Geologic systems ; Marine hydrate
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Solid Earth 124(8), (2019): 7525-7537, doi: 10.1029/2019JB018186.
    Description: The proliferation of drilling expeditions focused on characterizing natural gas hydrate as a potential energy resource has spawned widespread interest in gas hydrate reservoir properties and associated porous media phenomena. Between 2017 and 2019, a Special Section of this journal compiled contributed papers elucidating interactions between gas hydrate and sediment based on laboratory, numerical modeling, and field studies. Motivated mostly by field observations in the northern Gulf of Mexico and offshore Japan, several papers focus on the mechanisms for gas hydrate formation and accumulation, particularly with vapor phase gas, not dissolved gas, as the precursor to hydrate. These studies rely on numerical modeling or laboratory experiments using sediment packs or benchtop micromodels. A second focus of the Special Section is the role of fines in inhibiting production of gas from methane hydrate, controlling the distribution of hydrate at a pore scale, and influencing the bulk behavior of seafloor sediments. Other papers fill knowledge gaps related to the physical properties of hydrate‐bearing sediments and advance new approaches in coupled thermal‐mechanical modeling of these sediments during hydrate dissociation. Finally, one study addresses the long‐standing question about the fate of methane hydrate at the molecular level when CO2 is injected into natural reservoirs under hydrate‐forming conditions.
    Description: C. R. was supported by the U.S. Geological Survey's Energy Resources Program and the Coastal/Marine Hazards and Resources Program, as well as by DOE Interagency Agreement DE‐FE0023495. C. R. thanks W. Waite and J. Jang for discussions and suggestions that improved this paper and L. Stern for a helpful review. J. Y. Lee was supported by the Ministry of Trade, Industry, and Energy (MOTIE) through the Project “Gas Hydrate Exploration and Production Study (19‐1143)” under the management of the Gas Hydrate Research and Development Organization (GHDO) of Korea and the Korea Institute of Geoscience and Mineral Resources (KIGAM). Any use of trade, firm, or product name is for descriptive purposes only and does not imply endorsement by the U.S. Government.
    Keywords: Gas hydrate ; Methane ; Reservoir properties ; Multiphase flow
    Repository Name: Woods Hole Open Access Server
    Type: Article
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