ALBERT

Description: Today, coastal cities worldwide are facing major changes resulting from climate change and anthropogenic forcing, which requires adaptation and mitigation strategies to be established. In this context, sedimentological archives in many Mediterranean cities record a multi-millennial history of environmental dynamics and human adaptation, revealing a long-lasting resilience. Founded by the Phoenicians around 3000 years ago, Cádiz (south-western Spain) is a key example of a coastal resilient city. This urban centre is considered to be one of the first cities of western Europe and has experienced major natural hazards during its long history, such as coastal erosion, storms, and also tsunamis (like the one in 1755 CE following the destructive Lisbon earthquake). In the framework of an international, joint archaeological and geoarchaeological project, three cores have been drilled in a marine palaeochannel that ran through the ancient city of Cádiz. These cores reveal a ≥50 m thick Holocene sedimentary sequence. Importantly, most of the deposits date from the 1st millennium BCE to the 1st millennium CE. This exceptional sedimentary archive will allow our scientific team to achieve its research goals, which are (1) to reconstruct the palaeogeographical evolution of this specific coastal area; (2) to trace the intensity of activities of the city of Cádiz based on archaeological data, as well as geochemical and palaeoecological indicators; and (3) to identify and date high-energy event deposits such as storms and tsunamis.

Description: The southern Black Forest was temporarily covered by a ∼1000 km2 large ice cap during the Late Pleistocene. However, during the last glaciation maximum in the Alps the atmospheric circulation over Europe was presumably characterised by the advection of humid air masses from the Mediterranean Sea. As a consequence, the ice cap of the Black Forest was likely in a leeward position due to its location north of the Alps. This raises the question of whether it reached its last maximum extent simultaneously with the glaciers in the Alps. As modern dating techniques have hitherto not been applied to the southern Black Forest, the timing of the last local glaciation maximum remains poorly constrained. As a first step towards an independent regional glacier chronology, we present a critical re-examination of glacial landforms in the area north-west of the highest summit of the Black Forest (Feldberg, 1493 m a.s.l.). It relies on both the analysis of remote sensing data and field mapping. The review of previous studies highlights important disagreements regarding the location of ice-marginal positions and their correlation. In addition, our findings challenge earlier studies on the glaciation of the Black Forest: some previously described ice-marginal positions could not be confirmed, whereas some of the newly identified moraines are described for the first time. This highlights the need for detailed geomorphological investigations prior to the application of geochronological methods. A multi-ridged series of terminal moraines in one of the studied valleys, Sankt Wilhelmer Tal, is proposed as the main target for future dating. Due to discrepancies with earlier studies, future efforts should reinvestigate other key areas related to the last glaciation of the southern Black Forest.

Description: Biocides used in film protection products leaching from facades are known to be a potential threat to the environment. This study identifies individual sources and entry pathways in a small-scale urban area. We investigate emissions of commonly used biocides (terbutryn, diuron, and octylisothiazolinone – OIT) and some of their transformation products (TPs; diuron-desmethyl, terbumeton, terbuthylazine-2-hydroxy, and terbutryn-desethyl) from a 2 ha residential area 13 years after construction has ended. Sampling utilizes existing urban water infrastructure representative for decentralized storm water management in central and northern Europe and applies a two-step approach to (a) determine the occurrence of biocides above water quality limits (i.e., predicted no-effect concentration, PNEC) and (b) identify source areas and characterize entry pathways into surface and groundwater. Monitoring focuses on the analysis of selected biocides and TPs by liquid chromatography–mass spectrometry/mass spectrometry (LC-MS/MS) in water samples taken from facades, rainwater pipes, drainage, and storm water infiltration systems. In standing water in a swale, we found high concentrations of diuron (174 ng L−1) and terbutryn (40 ng L−1) above PNEC for surface water. We confirmed expected sources, i.e., facades. Sampling of rain downpipes from flat roofs identified additional sources of all biocides and two TPs of terbutryn and one TP of diuron. Diuron and terbutryn were found in three drainage pipes representing different entry pathways of biocides. In one drainage pipe collecting road runoff, only diuron-desmethyl and terbutryn-desethyl were detected. In two other drainage pipes collecting infiltrated water through soil, terbuthylazine-2-hydroxy was additionally detected. One of the pipes collecting infiltrated water through soil concentration showed the highest concentrations of terbutryn and two of its TPs (terbutryn-desethyl and terbuthylazine-2-hydroxy). This suggests a high leaching potential of terbutryn. The applied two-step approach determined sources and pathways of biocide and their TPs. This study contributes to expanding knowledge on their entry and distribution and, thus, eventually towards reducing emissions.

Description: Luminescence dating has become a pillar of the understanding of Pleistocene glacial advances in the northern foreland of the Swiss Alps. However, both quartz and feldspar from the region are equally challenging as dosimeters with anomalous fading and partial bleaching being some of the obstacles to overcome for the establishment of decisive chronologies. In this study, luminescence properties of coarse- and fine-grained quartz, feldspar, and polymineral fractions of eight samples from a palaeovalley, Rinikerfeld in northern Switzerland, are systematically assessed. Standard performance tests are conducted on all four fractions. Deconvolution of luminescence signals of the quartz fractions is implemented and shows the dominance of stable fast components. Reader-specific low preheat temperatures are investigated on the infrared stimulated luminescence (IRSL) signal of feldspar. Thermal stability of this signal is found for low preheats, and thermal quenching could be excluded for higher preheats. However, anomalous fading is observed in the feldspar and polymineral IRSL signals and two correction approaches are applied. For one approach, fading corrected coarse-grained feldspar ages are consistent with those derived from quartz. In general, coarse-grained quartz and feldspar, as well as the fine-grained polymineral fraction of one sample, are in chrono-stratigraphic agreement and present negligible evidence for partial bleaching. However, ages derived from fine-grained quartz are found to underestimate those of the coarse-grained quartz fractions. Hence, the impact of alpha efficiency and water content on the dose rate and thus the ages are assessed. A finite explanation for the observed discrepancies remains lacking, but this systematic investigation of different luminescence signals allows for the establishment of a chronology for the palaeovalley fill dating back to at least Marine Isotope Stage 6 (MIS 6).