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  • Articles  (92)
  • Springer Nature  (81)
  • Wiley-Blackwell  (11)
  • 2020-2022  (67)
  • 1965-1969  (10)
  • 1960-1964  (14)
  • 1935-1939  (1)
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  • Articles  (92)
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  • 1
  • 2
    Publication Date: 2020-10-29
    Description: Lily belongs to family liliaceae, which mainly propagates vegetatively. Therefore, sufficient number of polymorphic, informative, and functional molecular markers are essential for studying a wide range of genetic parameters in Lilium species. We attempted to develop, characterize and design SSR (simple sequence repeat) markers using online genetic resources for analyzing genetic diversity and population structure of Lilium species. We found di-nucleotide repeat motif were more frequent (4684) within 0.14 gb (giga bases) transcriptome than other repeats, of which was two times higher than tetra-repeat motifs. Frequency of di-(AG/CT), tri-(AGG/CTT), tetra-(AAAT), penta-(AGAGG), and hexa-(AGAGGG) repeats was 34.9%, 7.0%, 0.4%, 0.3%, and 0.2%, respectively. A total of 3607 non-redundant SSR primer pairs was designed based on the sequences of CDS, 5′-UTR and 3′-UTR region covering 34%, 14%, 23%, respectively. Among them, a sub set of primers (245 SSR) was validated using polymerase chain reaction (PCR) amplification, of which 167 primers gave expected PCR amplicon and 101 primers showed polymorphism. Each locus contained 2 to 12 alleles on average 0.82 PIC (polymorphic information content) value. A total of 87 lily accessions was subjected to genetic diversity analysis using polymorphic SSRs and found to separate into seven groups with 0.73 to 0.79 heterozygosity. Our data on large scale SSR based genetic diversity and population structure analysis may help to accelerate the breeding programs of lily through utilizing different genomes, understanding genetics and characterizing germplasm with efficient manner.
    Electronic ISSN: 2045-2322
    Topics: Natural Sciences in General
    Published by Springer Nature
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  • 3
    Publication Date: 2020-09-17
    Description: Ensete ventricosum (Musaceae, enset) is an Ethiopian food security crop. To realize the potential of enset for rural livelihoods, further knowledge of enset diversity, genetics and genomics is required to support breeding programs and conservation. This study was conducted to explore the enset genome to develop molecular markers, genomics resources, and characterize enset landraces while giving insight into the organization of the genome. We identified 233 microsatellites (simple sequence repeats, SSRs) per Mbp in the enset genome, representing 0.28% of the genome. Mono- and di-nucleotide repeats motifs were found in a higher proportion than other classes of SSR-motifs. In total, 154,586 non-redundant enset microsatellite markers (EMM) were identified and 40 selected for primer development. Marker validation by PCR and low-cost agarose gel electrophoresis revealed that 92.5% were polymorphic, showing a high PIC (Polymorphism Information Content; 0.87) and expected heterozygosity (He = 0.79–0.82). In silico analysis of genomes of closely related species showed 46.86% of the markers were transferable among enset species and 1.90% were transferable to Musa. The SSRs are robust (with basic PCR methods and agarose gel electrophoresis), informative, and applicable in measuring enset diversity, genotyping, selection and potentially breeding. Enset SSRs are available in a web-based database at https://enset-project.org/EnMom@base.html (or https://enset.aau.edu.et/index.html, downloadable from Figshare).
    Electronic ISSN: 2045-2322
    Topics: Natural Sciences in General
    Published by Springer Nature
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 7 (1963), S. 2199-2209 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics of low-temperature (60-100°C.) thermal degradation of deproteinized and deresinified petroleum ether soluble fraction of natural rubber in two chemically inert solvents, cyclohexane and trans-decalin, have been studied. The changes in Mw, A2, and (r2)1/2 at various stages of degradation have been obtained from the lightscattering data. The rate constants and the energy of activation for chain scission have been calculated from the observed variation in Mu. The scission has been found to be random and the average energy of activation is 25.8 kcal./mole. This low-energy requirement suggests the presence of weak links in the rubber molecule which get ruptured at low temperature.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 21 (1963), S. 147-148 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The coulometric determination of tripositive arsenic and antimony by electrogenerated iodine in a NaHCO3 buffered solution of pH 8 has been described. The end point can be determined visually using starch as an indicator. Quantities of As(III) and Sb(III) down to the microgram level can be determined within permissible limits of error.
    Additional Material: 2 Tab.
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  • 6
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A convenient method of preparing zinc ethylenediamine complex (ZED) solution for use as solvent for cellulose pulp is described, and the advantages in using this solvent (0.25M zinc in 41% ethylenediamine in water) over cupriethylenediamine (CED) or cuprammonium solutions for viscometric determination of molecular weight of cellulose are indicated. Intrinsic viscosities of eight rayon-grade pulp solutions have been determined at four temperatures: 15, 20, 25, and 30°C. The constants K = 5.85 × 10-5 and a = 0.936 of the Mark-Houwink equation [η] = KMna, required for evaluating the molecular weight of cellulose pulps in ZED solution, have been determined by using the molecular weight values obtained from CED solutions.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics of degradation of butyl rubber in two solvents, cyclohexane and toluene, was studied by two independent techniques: viscosity measurements and free-radical estimation as a function of DPPH consumed. The general shape of the rate curves in the two cases is similar, but not identical. The rate given by estimation of DPPH is faster than that obtained from solution viscosity data. This has been attributed to the inherent limitations of the two methods for the quantitative determination of the number of breaks occurring in the polymer molecules. The rate is also reduced as the viscosity of the solution medium is increased, which may be correlated with the reduction of the cavitation effect responsible for degradation. The degradation rates in two solvent media initially having the same viscosity were unequal. This may be due to different solvent-solute characteristics, which means that the viscosity and cavitation change to different extents in the two cases throughout the course of degradation. The limiting degree of Polymerization (DP)∞ obtained after prolonged irradiation has been found to be dependent on parameters such as intensity of irradiation, solution viscosity, and initial DP of the molecules.
    Additional Material: 4 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 2653-2659 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Sol rubber dissolved in three solvents - cyclohexane, petroleum ether (40-60°C. fraction), and toluene - was degraded by ultrasonic waves, the degradation kinetics being followed by measuring spectrophotometrically the consumption of the free radical scavenger α,α′-diphenyl-β-picryl hydrazyl. The kinetic data have been examined by the rate equations developed from two different approaches: one by Jellinek and the other by Ovenall. It has been observed that the number of bonds broken as a function of time can be fitted equally well by both equations in the initial stage, but as the time of degradation increases, especially when the number-average degree of polymerization attains a value less than 3Pe/2, the rate can be described better by Jellinek's equation than that of Ovenall. The rate constants K and the final degree of polymerization for rubber are found to depend on the nature of the solvent.
    Additional Material: 4 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 28 (1965), S. 137-140 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Schemes have been worked out for the quantitative separation and subsequent determination of the constituents in a number of alloys containing Au—Cu, Cu—Al, Fe—Au and Fe—Cu—Al by the ring oven technique. Gold is migrated to the ring zone by extraction with n-butanol at pH = 1.5 and iron or copper with acetylacetone. Aluminium is moved to the ring zone by acidified ethanol.
    Additional Material: 3 Tab.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 124 (1969), S. 263-273 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: In Gegenwart von Vanadiumpentoxid als heterogenern Katalysator Wurde N-Vinylcarbazol (NVC) in Substanz polymerisiert. Die Polymerisationsgeschwindigkeit hängt vom Verhältnis des Katalysators zum Monomeren ab. Es wurde ein kationischer Reaktionsmechanismus vorgeschlagen, und es wurde versucht, die Rolle der V2O5-Oberfläche bei der Polymerisation aufzuklären. Es wird vermutet, daß die π-Säureeigenschaft des V5⊕-Ions bei der Initiierung der Polymerisation miteinbezogen werden muß.Die Wirkung einer Anzahl von Zusätzen auf die Polymerisationsgeschwindigkeit wurde untersucht; das Ergebnis bekräftigt die Annahme eines kationischen Verlaufs.Es wurde auch die katalytische Wirksamkeit einer Anzahl von Metallvanadaten bei der Polymerisation von NVC untersucht. Es ergab sich eine hinreichend gute Bezichung zwischen der katalytischen Wirksamkeit und dem elektronegativen Charakter des metallischen Bestandteils.
    Notes: Bulk polymerization of N-Vinylcarbazole (NVC) has been carried out using vanadium pentoxide as the contact catalyst. The rate of polymerizatlon has been found to depend upon catalyst to monomer ratio. A cationic mechanism has been suggested and the role of V2O5 surface in the polymerization has been tentatively analyzed. The π-acid characteristies of V5⊕ ion is believed to be involved in initiating the polymerization. The effect of a number of additives on the polymerization rate has been studied, which endorses the cationic mechanism. The catalytic efficiency of a number of metal vanadates for the polymerization of NVC has also been studied. A fairly good correlation between the activity and electronegativity of the metallic moiety has been established.
    Additional Material: 4 Ill.
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