ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The base hydrolysis of the optically active title compound proceeds with full racemization whilst the meridional arrangement of the diethylenetriamine ligand is fully retained. The optically active hydroxo complex prepared independently with retention of configuration racemizes ≳ 104 times slower. This unique result is discussed in terms of the classical π-stabilization hypothesis for the base hydrolysis mechanism.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19800630319
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