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  • Springer  (366)
  • Springer Nature  (189)
  • 2020-2022  (257)
  • 1985-1989  (276)
  • 1940-1944  (22)
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  • 11
    ISSN: 1572-879X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A study has been made of ZSM5 zeolite deacidification (dealumination) by high temperature treatment in SiCl4 vapour, monitoring total acidity by Na+-exchange, and external surface acidity by methylene blue adsorption (exchange), with comparative measurements of theN Si/NAl ratio (nominally external surface) by XPS. Using H-ZSM5, the highest specificity for external surface deacidification was found at the lowest usable values of treatment temperature, time andp Sicl4. Using Na-ZSM5 in place of H-ZSM5 did not offer a useful improvement. A steaming/HCl-leaching method was shown not to be suitable for selective external surface deacidification. Values ofN Si/NAl by XPS were dependent on the method of sample preparation, with mechanical stress (pelleting, pressing) tending to give abnormally low values due to crystal or aggregate fracture: this effect became more serious with increasing severity of SiCl4 treatment. Even after correcting for XPS emission from subsurface layers, agreement between surfaceN Si/NAl values from XPS and acidity measurements was poor for samples with a low degree of bulk deacidification (mild SiCl4 treatments), and is ascribed to non-acidic surface Al.
    Type of Medium: Electronic Resource
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  • 12
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Impedance measurements on 23 Ah Ni-Cd cells at various residual capacity levels are described. These have been made using non-inductive connections coupled directly to a potentiostat and a frequency response analyser. The capacitive reactance at 0.39 Hz provided the best residual capacity indicator.
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  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 16 (1986), S. 555-564 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The problem of estimating the residual usable energy of a lead-acid cell has been intensified by the introduction of fully sealed units. These rely on the recombination of gaseous oxygen produced during overcharge at the positive electrode with the active material at the negative electrode. This introduction has removed the possibility of electrolyte density measurements, third electrode measurements and restricted residual capacity assessments to the two cell terminals. A method for this process is described using a parameter based on a characteristic frequency. The parameter is also a useful measure of cell ageing.
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  • 14
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 15 (1985), S. 399-404 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Impedance measurements have been made on a mini electrode disposed between two large (identical) counter electrodes. A general mechanism is obtained for the electrode behaviour from the experimental data. The electrode reaction is two step and complex. Where comparison is possible agreement is obtained with earlier work.
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  • 15
    Electronic Resource
    Electronic Resource
    Springer
    Entomologia experimentalis et applicata 48 (1988), S. 257-262 
    ISSN: 1570-7458
    Keywords: feeding stimulants ; soybean ; Mexican bean beetle ; Epilachna varivestis ; relative growth rate ; relative consumption rate ; feeding preference ; sulfur dioxide ; soluble carobhydrate ; soluble protein ; glutathione ; plant stress
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Description / Table of Contents: Résumé Les taux de consommation relative (RCR) et de croissance relative (RGR) sont significativement supérieurs chez les larves d'E. varivestis après fumigation des feuilles de soja par SO2. L'étude de la relation entre RCR et RGR a révélé que les insectes se sont développés davantage, avant tout parce qu'ils ont consommé plus, et non pas par modification de la valeur nutritive des tissus de l'hôte. La teneur en carbohydrates solubles des feuilles traitées au glutathion on ayant subi une fumigation était bien supérieure à celle des témoins; les concentrations de sucrose, fructose et glucose, principaux phagostimulants de cet insecte avaient augmenté de 40 à 50%; la teneur en protéine soluble était inchangée (cas de la fumigation) ou significativement réduite (cas des feuilles traitées au glutathion). Des expériences de choix avec des disques de papier filtre ont montré que les insectes pouvaient distinguer nettement des différences de concentration en sucres, du même ordre d'importance que celles provoquées par le polluant, et y répondre. Ainsi, la cause primaire par laquelle SO2 augmente les performances d'E. varivestis sur soja semble être l'augmentation de la concentration foliaire en sucres stimulateurs, ce qui serait, au moins en partie, la conséquence de l'interférence du polluant avec la charge du phloème et le transfert du sucre à partir des feuilles atteintes.
    Notes: Abstract Relative consumption rate (RCR) and relative growth rate (RGR) were significantly higher for larvae of the Mexican bean beetle fed leaves from plants fumigated with SO2. The insects grew faster primarily because they ate faster, rather than as a result of change in nutritional value of affected host tissue. Soluble carbohydrate content of fumigated or glutathione-treated leaves was much higher than that of corresponding control leaves, and concentrations of sucrose, fructose, and glucose, major feeding stimulants for this insect, were increased 40–50% by the treatments; soluble protein was unchanged (fumigated leaves) or significantly lower (glutathione-treated leaves) than controls. Feeding choice assays using filter-paper discs demonstrated that the beetles can discriminate clearly and respond to differences in sugar content of the magnitude produced by exposure to the pollutant. Thus, the primary mechanism by which SO2 increases performance of Mexican bean beetle on soybean appears to be increase in foliar concentration of stimulatory sugars, which, at least in part, would be a consequence of the pollutant interfering with phloem loading and translocation of sugar from affected leaves.
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  • 16
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Gross errors in impedance measurements of high capacity electrical storage cells can be observed when using a commercial Frequency Response Analyser (FRA) coupled with an electrochemical interface. The magnitudes of these errors are discussed and an appropriate automatic calibration procedure is described which enables the correct impedance to be recorded at any frequency.
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  • 17
    ISSN: 1434-6052
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract This paper reports studies of the reactions γp→ρ π π πp and γp→ρ ρ πp. In particular a peak is reported in the ρ ρ π mass spectrum with closely similar mass and width to those of the ω ρ π peak previously reported in the reaction γp→ω ρ πp. The ratio of production cross sections is found to be ρ ρ π/ω ρ π=0.96±0.19, in serious disagreement with the expectation from Vector Meson Dominance. A possible explanation is indicated.
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  • 18
    Electronic Resource
    Electronic Resource
    Springer
    Aequationes mathematicae 37 (1989), S. 219-232 
    ISSN: 1420-8903
    Keywords: Primary 94A17 ; Secondary 94A15, 39B40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Summary Using a recent result by B. Ebanks on the functional equation $$h(x,y) + h(x + y,z) = h(x,y + z) + h(y,z)$$ we derive a representation theorem for a large class of entropy functionals that exhibit the “branching property”. LetV(Ω, F,m) be the set of probability densities on a non-atomic measure space {Ω,F,m} and $$\bar V$$ (Ω,F,m) be the set of all simple probability densities. A functional Ф: (Ω,F,m) →R ∪ { − ∞, ∞} will be said to have thebranching property, if, given any setA ∈ F and any two functionsf, g ∈ V such that at least one of Ф(f) or Ф(g) is finite andf(ω) = g(ω) whenever ω ∈ Ω/A, then $$\Phi (f) - \Phi (g) = \Psi (f_A ,g_A ),$$ wheref A is the restriction off to the setA and Ψ:L 1(A, F,m) ×L 1(A, F,m) →R ∪ {− ∞, ∞}. Theorem 1.Given Ф: V(Ω,F,m) →R ∪ {−∞, ∞}, $$\bar V$$ (Ω,F,m) →R,If (i) Фhas the branching property (ii) Фis invariant under all metric endomorphisms (iii) (continuity) for any sequence of simple functions {si}, with si ↑ f we have (with ∥ · ∥ the L1 norm) $$\Phi \left( {\frac{{s_i }}{{\parallel s_i \parallel }}} \right) \to \Phi (f)$$ then there exists h:[0, ∞) →R continuous on (0, ∞)with h(0) = 0such that Ф(f) = ∫ Ω h(f) d m. Фis said to be “recursive” if, for any set A ∈ F and any two functions, f, g ∈ V such that f(ω) = g(ω) at each ω ∈ Ω/A and p:=∫ A f d m =∫ A g d m 〉0, $$\Phi (f) - \Phi (g) = p\left[ {\Phi \left( {\frac{{f\chi _A }}{p}} \right) - \Phi \left( {\frac{{g\chi _A }}{p}} \right)} \right],$$ where ϰ A is the characteristic function of the set A. By strengthening (i) in Theorem 1 to “Ф is recursive” we obtain a new characterization of the Boltzmann—Shannon entropy.
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  • 19
    ISSN: 0945-3245
    Keywords: AMS(MOS):65N30 ; CR: G1.8
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Summary Adding to the classical Hellinger Reissner formulation another residual form of the equilibrium equation, a new Petrov-Galerkin finite element method is derived. It fits within the framework of a mixed finite element method and is proved to be stable for rather general combinations of stress and displacement interpolations, including equal-order discontinuous stress and continuous displacement interpolations which are unstable within the Galerkin approach. Error estimates are presented using the Babuška-Brezzi theory and numerical results confirm these estimates as well as the good accuracy and stability of the method.
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  • 20
    Electronic Resource
    Electronic Resource
    Springer
    Catalysis letters 2 (1989), S. 71-72 
    ISSN: 1572-879X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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