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  • Chemical Engineering  (9)
  • 2020-2022
  • 1995-1999  (4)
  • 1975-1979  (5)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 1077-1087 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The ignition-extinction behavior in the oxidation of methane, ethane, propane and isobutane, as well as of ethylene and propylene over a platinum-foil catalyst was studied over the entire range of fuel/air ratios at atmospheric pressure. Ignition and extinction of the heterogeneous surface reaction, homogeneous ignition and the autothermal behavior of these fuel-air mixtures were investigated. The results show a common trend in the ignition extinction behavior of the alkanes and a different trend for the olefins. This is discussed in terms of a simple model, which correctly predicts the composition dependence of the surface ignition curve for reasonable values of parameters, indicating a mainly oxygen-covered surface during ignition of the alkanes and a mainly hydrocarbon-covered surface in the case of the olefins. Different branches of the complete bifurcation diagrams are discussed separately, allowing qualitative conclusions about the catalytic activity of Pt for the oxidation reactions of different fuels.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 3484-3497 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The oxidative dehydrogenation of ethane to ethylene over Pt-coated foam monoliths in oxygen with varying levels of nitrogen dilution has been simulated using a 24-stepmodel of adsorption, desorption and surface reactions. Reaction parameters for these elementary steps were obtained from surface science and catalysis literature or fit to previously reported experimental data. The model agrees with the experimental data remarkably well, mimicking the selectivity and conversion trends observed experimentally with changing operating conditions. The model shows that a purely heterogeneous mechanism can be used to simulate the experimental results collected near atmospheric pressure accurately, suggesting that the mechanism we propose is sufficiently accurate to capture the main features of this reaction system. This model can also be used to examine this reaction system under conditions experimentally inaccessible. Application of this predictive ability to operation of this type of reactor under probable industrial conditions suggests that excellent ethylene yields are possible.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Silicon-based microfabrication of a novel chemical reactor (microreactor) having submillimeter flow channels with integrated heaters, and flow and temperature sensors is described. The potential application of this reactor to partial-oxidation reactions is explored by using Pt-catalyzed NH3 oxidation as a model reaction. Investigation of reactor behavior as a function of operating conditions shows that conversion and selectivity behavior of conventional laboratory reactors can be reproduced and demonstrates the feasibility of conducting chemical reactions in microfabricated systems. Ignition-extinction behavior is explored, along with high-temperature microreactor materials degradation. Potential applications and scale-up of microreactors are also discussed.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 786-791 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Effective reaction rates and selectivities on surfaces having active and inactive regions are calculated for systems in which diffusion of reactants and products through a boundary layer is significant. With a single reaction it is shown that rates are larger than those calculated assuming area weighted averages. The selectivity of production of an intermediate in a series of reactions on a heterogeneous surface is higher than on a homogeneous surface, and with parallel reactions selectivities may be lower or higher depending on the kinetics of the competing reaction.Numerical examples from NH3 oxidation on a Pt gauze and CO oxidation in the automotive converter indicate that these effects may be important in determining selectivities and conversions in some industrial reactors.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 15 (1975), S. 51-62 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A second-generation apparatus was built and used to inflate heat-softened plastic sheets to shapes from hemispheres to large spheroidal bubbles. Three sheet materials, polystyrene, high-impact polystyrene, and cellulose acetate butyrate, were successfully formed beyond the hemispherical shape at temperatures somewhat below industrial levels. Four others, rigid poly-(vinyl chloride), an acrylic-modified PVC, cast poly(methyl methacrylate), and polycarbonate, could not be deformed beyond the hemispherical shape without rupture. Measurements included bubble profiles, thickness distributions and local extension ratios for the final bubbles; two plots of profile growth measured from high-speed motion pictures; and a continuous record of bubble temperatures and blowing pressure from which the meridional temperature distributions were plotted.Fifteen bubbles were measured and analyzed. Profiles and extension ratios were compared with those computed from the equations of isotropic, isothermal elasticity, using several different strain-energy functions with constant material parameters. Agreement over all fifteen bubbles on all properties was about ±10.8 percent (absolute) for the best models considered. Bubble growth occurred over periods of 5 to 8 seconds, with about 90 percent of the final area of the larger bubbles being generated in the final 1.5 seconds. The maximum areal elongations obtained were 18,600 percent for clear polystyrene at 238°F, 14,300 percent for high-impact polystyrene at 224°F, and 1,010 percent for cellulose acetate butyrate at 280°F.
    Additional Material: 13 Ill.
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  • 6
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Five glass bead-filled polypropylene composites, which had been rheologically characterized, were used in mold-filling studies to investigate the influence of rigid beads (0 to 26 vol percent) in complex flow fields. The two basic flows studied were simple shear flow in an edge-gated, rectangular cavity and stagnation flow leading to diverging radial flow in a center-gated, rectangular cavity. Pigmented tracer elements were used to illustrate flow patterns and to distinguish the skin-core structure which is a consequence of the injection molding process.Despite the strong dependence of the rheological properties (both viscous and elastic) and physical properties (density, thermal conductivity, etc.) on bead volume fraction, the basic character of the polymer dominated the flow behavior of each composite and the flow patterns were unaffected by the beads. Injection pressures were increased with increasing bead fraction to maintain the same, constant volumetric flow rate (2.21 in.3/min) for each composite. Relative injection forces follow closely the relative viscosit trend.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 17 (1977), S. 657-665 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Five glass bead-filled polypropylene composites were rheologically characterized at 240°C using two rotational rheometers to obtain low shear-rate data and a capillary rheometer to obtain high shear-rate data. Both steady and dynamic properties were measured at low shear rates. Each composite was also injection molded into tensile and flexural test bars for a mechanical properties profile at 25°C. The tensile modulus was determined from a simple extensional deformation whereas the flexural modulus was determined from a three-point-bend test.The relative shear viscosity and relative loss modulus are different nonlinear functions of the volume fraction of beads at a constant shear rate, while the relative storage modulus appears to be a linear function of bead fraction. The relative viscosity decreases with increasing shear rate and the zero shear-rate data are in very good agreement with the Guth-Gold equation.The relative tensile modulus and relative flexural modulus are each linear functions of bead fraction over the entire range of filler concentration, 0-29 vol percent. From these data it is concluded that a simple correspondence between slow viscous flow and small strain elasticity does not exist for these composites.
    Additional Material: 11 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 883-887 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The linear viscoelastic limit of poly(methyl methacrylate) (PMMA) is established on the basis of the Reiner-Weissenberg criterion of strength. The obtained limit is not simply a “strainlimit” or a “stress-limit” but a function of both strain and stress, an energetical limit. In stress-strain representation the limit is independent of time and temperature, which means that the linear or non-linear behavior of the material depends only on the actual values of strain and stress. Some experimental data obtained on PMMA confirm the theory.
    Additional Material: 6 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 16 (1997), S. 262-268 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Predictive maintenance/inspection planning and fitness-for-service analyses are being applied more frequently to address the effect of component aging affecting plant reliabibility. Component aging is one of the critical issues in an increasingly competitive environment, especially in plant components built and installed during the 50s and 60s. Maintenance optimization is also a critical issue for components, such as those that operate in the creep regime, and therefore age quickly. Maximizing the value received for each predictive maintenance/inspection dollar is the key. This article introduces the use of decision analysis to unite engineering analysis and economic evaluation for decision making. To illustrate this idea, examples of this approach applied to chemical facility components will be presented. In addition, the concept of priority-ranking multiple component maintenance/inspectio projects having maintenance budget and safety constraints in a way that maximizes Net Present Value, will be presented.
    Additional Material: 8 Ill.
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