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  • Weitere Quellen  (84)
  • Elsevier  (69)
  • Cambridge University Press  (8)
  • International Union of Crystallography  (4)
  • American Chemical Society  (3)
  • 2020-2022  (7)
  • 2000-2004  (77)
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  • 1
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    International Union of Crystallography | 5 Abbey Square, Chester, Cheshire CH1 2HU, England
    Publikationsdatum: 2021-07-02
    Beschreibung: A new concept for temporal gating of synchrotron X‐ray pulses based on laser‐induced thermal transient gratings is presented. First experimental tests of the concept yield a diffraction efficiency of 0.18%; however, the calculations indicate a theoretical efficiency and contrast of 〉30% and 10−5, respectively. The full efficiency of the pulse picker has not been reached yet due to a long‐range thermal deformation of the sample after absorption of the excitation laser. This method can be implemented in a broad spectral range (100 eV to 20 keV) and is only minimally invasive to an existing setup.
    Beschreibung: A new concept for temporal gating of synchrotron X‐ray pulses based on laser‐induced thermal transient gratings is presented.
    Schlagwort(e): 548 ; synchrotron ; time‐resolved ; thermal deformation ; transient grating ; pulse picking
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
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    Cambridge University Press
    In:  Climate change 2001: the scientific basis. Contribution of working group I to the third assessment report of the Intergovernmental Panel on Climate Change
    Publikationsdatum: 2022-03-21
    Materialart: info:eu-repo/semantics/bookPart
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2017-07-27
    Beschreibung: Ten ODP sites drilled in a depth transect (2164–4775 m water depth) during Leg 172 recovered high-deposition rate (〉20 cm/kyr) sedimentary sections from sediment drifts in the western North Atlantic. For each site an age model covering the past 0.8–0.9 Ma has been developed. The time scales have a resolution of 10–20 kyr and are derived by tuning variations of estimated carbonate content to the orbital parameters precession and obliquity. Based on the similarity in the signature of proxy records and the spectral character of the time series, the sites are divided into two groups: precession cycles are better developed in carbonate records from a group of shallow sites (2164–2975 m water depth, Sites 1055–1058) while the deeper sites (2995–4775 m water depth, Sites 1060–1063) are characterized by higher spectral density in the obliquity band. The resulting time scales show excellent coherence with other dated carbonate and isotope records from low latitudes. Besides the typical Milankovitch cyclicity significant variance of the resulting carbonate time series is concentrated at millennial-scale changes with periods of about 12, 6, 4, 2.5, and 1.5 kyr. Comparisons of carbonate records from the Blake Bahama Outer Ridge and the Bermuda Rise reveal a remarkable similarity in the time and frequency domain indicating a basin-wide uniform sedimentation pattern during the last 0.9 Ma.
    Materialart: Article , PeerReviewed
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
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    Cambridge University Press
    In:  Biodiversity, sustainability and human communities: Protecting beyond the protected
    Publikationsdatum: 2022-03-21
    Materialart: info:eu-repo/semantics/bookPart
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2021-06-26
    Beschreibung: The high‐precision X‐ray diffraction setup for work with diamond anvil cells (DACs) in interaction chamber 2 (IC2) of the High Energy Density instrument of the European X‐ray Free‐Electron Laser is described. This includes beamline optics, sample positioning and detector systems located in the multipurpose vacuum chamber. Concepts for pump–probe X‐ray diffraction experiments in the DAC are described and their implementation demonstrated during the First User Community Assisted Commissioning experiment. X‐ray heating and diffraction of Bi under pressure, obtained using 20 fs X‐ray pulses at 17.8 keV and 2.2 MHz repetition, is illustrated through splitting of diffraction peaks, and interpreted employing finite element modeling of the sample chamber in the DAC.
    Beschreibung: The high‐precision X‐ray diffraction (XRD) setup for work with diamond anvil cells (DACs) in Interaction Chamber 2 of the High Energy Density (HED) instrument of the European X‐ray Free‐Electron Laser is described. image
    Schlagwort(e): 548 ; diamond anvil cells ; X‐ray free‐electron lasers ; high‐precision X‐ray diffraction ; finite element modeling
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
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    American Chemical Society
    In:  The Journal of Physical Chemistry A, 107 (7). pp. 1050-1054.
    Publikationsdatum: 2020-05-11
    Beschreibung: We determined the coordination environment of Zn2+ in aqueous Cl- brines at 25 °C and 300 °C using ab initio molecular dynamics simulations. The ZnCl+ and ZnCl2 complexes exist as pseudo-octahedral ZnClm(H2O)6-m clusters at 25 °C but occur as pseudo-tetrahedral ZnClm(H2O)4-m clusters at 300 °C. The ZnCl3- complex occurs as the pseudo-tetrahedral ZnCl3(H2O)- cluster at 25 and 300 °C. The tetrahedral ZnCl42- complex, however, is the dominant Zn−Cl complex at 25 °C, at least in highly concentrated (7.4 m) Cl- brines. The change in hydration number with temperature for the ZnCl+ and ZnCl2 complexes will complicate extrapolations of solvation energies to hydrothermal conditions using a Born-model-based equation of state.
    Materialart: Article , PeerReviewed
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Publikationsdatum: 2017-01-05
    Beschreibung: In the present work responses of carp (Cyprinus carpio) head kidney-derived neutrophils to the blood parasite T. borreli, and the consequences of these responses for parasite survival and other host response mechanisms, were studied. In co-cultures of head kidney leucocytes (HKL) with viable and lysed T. borreli a prominent shape change of neutrophilic granulocytes towards increased size and complexity was observed. In addition, the longevity of neutrophils in vitro was prolonged in the presence of T. borreli antigens. In these cultures, neutrophils also exhibited an increased phagocytosis activity. An up regulation of the production of nitric oxide (NO) and reactive oxygen species (ROS) was observed in T. borreli- and mitogen-stimulated HKL cultures. However, addition of live, fluorescence-labelledT. borreli to previously stimulated HKL cultures, revealed neither killing nor phagocytosis of the parasite by activated neutrophils. Moreover, viable T. borreli, when added to HKL cultures of infected carp, reduced their phagocytosis activity and NO production. Supernatants of co-cultures between T. borreli and HKL also contained mediators, which suppressed a mitogen-induced proliferative response of peripheral blood leucocytes (PBL) in vitro. Thus, while T. borreli itself appeared not to be sensitive to responses of activated neutrophils, the flagellates interferes with the production of immunomodulatory signals of these cells, probably resulting in a partial immunosuppression, which may favour the parasite development in vivo.
    Materialart: Article , PeerReviewed
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
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    Elsevier
    In:  Progress in Oceanography, 59 . pp. 75-176.
    Publikationsdatum: 2016-10-05
    Beschreibung: This paper is an observational study of small-scale coherent eddies in the Labrador Sea, a region of dense water formation thought to be of considerable importance to the North Atlantic overturning circulation. Numerical studies of deep convection emphasize coherent eddies as a mechanism for the lateral transport of heat, yet their small size has hindered observational progress. A large part of this paper is therefore devoted to developing new methods for identifying and describing coherent eddies in two observational platforms, current meter moorings and satellite altimetry. Details of the current and water mass structure of individual eddy events, as they are swept past by an advecting flow, can then be extracted from the mooring data. A transition is seen during mid-1997, with long-lived boundary current eddies dominating the central Labrador Sea year-round after this time, and convectively formed eddies similar to those seen in deep convection modeling studies apparent prior to this time. The TOPEX / Poseidon altimeter covers the Labrador Sea with a loose “net” of observations, through which coherent eddies can seem to appear and disappear. By concentrating on locating and describing anomalous events in individual altimeter tracks, a portrait of the spatial and temporal variability of the underlying eddy field can be constructed. The altimeter results reveal an annual “pulsation” of energy and of coherent eddies originating during the late fall at a particular location in the boundary current, pinpointing the time and place of the boundary current-type eddy formation. The interannual variability seen at the mooring is reproduced, but the mooring site is found to be within a localized region of greatly enhanced eddy activity. Notably lacking in both the annual cycle and interannual variability is a clear relationship between the eddies or eddy energy and the intensity of wintertime cooling. These eddy observations, as well as hydrographic evidence, suggest an active role for boundary current dynamics in shaping the energetics and water mass properties of the interior region.
    Materialart: Article , PeerReviewed
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Publikationsdatum: 2015-02-24
    Beschreibung: The spatio-temporal pattern of peak Holocene warmth (Holocene thermal maximum, HTM) is traced over 140 sites across the Western Hemisphere of the Arctic (0–180°W; north of ∼60°N). Paleoclimate inferences based on a wide variety of proxy indicators provide clear evidence for warmer-than-present conditions at 120 of these sites. At the 16 terrestrial sites where quantitative estimates have been obtained, local HTM temperatures (primarily summer estimates) were on average 1.6±0.8°C higher than present (approximate average of the 20th century), but the warming was time-transgressive across the western Arctic. As the precession-driven summer insolation anomaly peaked 12–10 ka (thousands of calendar years ago), warming was concentrated in northwest North America, while cool conditions lingered in the northeast. Alaska and northwest Canada experienced the HTM between ca 11 and 9 ka, about 4000 yr prior to the HTM in northeast Canada. The delayed warming in Quebec and Labrador was linked to the residual Laurentide Ice Sheet, which chilled the region through its impact on surface energy balance and ocean circulation. The lingering ice also attests to the inherent asymmetry of atmospheric and oceanic circulation that predisposes the region to glaciation and modulates the pattern of climatic change. The spatial asymmetry of warming during the HTM resembles the pattern of warming observed in the Arctic over the last several decades. Although the two warmings are described at different temporal scales, and the HTM was additionally affected by the residual Laurentide ice, the similarities suggest there might be a preferred mode of variability in the atmospheric circulation that generates a recurrent pattern of warming under positive radiative forcing. Unlike the HTM, however, future warming will not be counterbalanced by the cooling effect of a residual North American ice sheet.
    Materialart: Article , PeerReviewed
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Publikationsdatum: 2017-01-05
    Beschreibung: In an attempt to characterise the role of nitric oxide (NO) in immune responses of carp, carp leucocytes obtained during an acute T. borreli infection were examined, for their capacity to generate NO. In a second set of experiments the impact NO on viability of the parasite and on the modulation of functional carp leucocyte responses were testedin vitro . Both in carp head-kidneys and in the peripheral blood, the fractions of lymphoblasts among separated leucocytes were increased. However, the relative proportions of granulocytes among head-kidney leucocytes (HKL) significantly decreased during infection, whereas granulocytes appeared among peripheral blood leucocytes (PBL). The cellular dynamics of HKL and PBL of infected carp were paralleled by an enhanced spontaneous NO release in vitro. NO production was further increased after addition of viable parasites to these cultures. The hypothesis that NO had a possible role in granulocyte activation and lymphocyte proliferation in carp was supported by the reduction of mitogen-induced proliferative responses of PBL from healthy carp in the presence of NO donor substances. The negative effects of NO on lymphocyte proliferation were contrasted by enhancing effects on granulocyte functions: the inhibition of NO generation in T. borreli -stimulated HKL cultures by the l-arginine analogue L-NMMA reduced the viability of granulocytes and their phagocytic activity. Even massive amounts of nitric oxide produced by donor substances (up to 600 μmol l−1 NO−2) caused no reduction in the numbers of viable T. borreli flagellates in vitro. Thus, in carp, T. borreli seems to induce high amounts of NO in vivo which are apparently not harmful for the parasite but which may interfere with co-ordinated interactions of activated cells aiming at the defence of the parasite.
    Materialart: Article , PeerReviewed
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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