ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Excitation of the NH-stretch overtone transitions of HN3 to v1=5 and 6 resulted in predissociation to HN(X) and N2(X) with lifetimes of 80+60−30 and ≤3 ns, respectively. Following excitation of either overtone, the HN fragments were formed predominantly in the symmetric F1, F3 spin–rotation states, with less than 4% population in the antisymmetric F2 levels. Fragment Doppler profiles confirmed that most of the available energy (〉96%) went into translational motion.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.455454
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