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  • Chemical Engineering  (5)
  • Atomic, Molecular and Optical Physics  (2)
  • Inorganic and Physical Chemistry
  • 2020-2021
  • 1995-1999  (4)
  • 1990-1994  (5)
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  • 1975-1979
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  • 2020-2021
  • 1995-1999  (4)
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  • 1
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 38 (1990), S. 461-486 
    ISSN: 0020-7608
    Schlagwort(e): Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: This study is a unified approach to quantum theories of polyacen carcinogenesis. Part I discusses the M, L, and B regions theory. Although the M region of polyacens is much less reactive than is the K region, the chemical reactivity of these two regions parallels each other. Consequently, the K-L Pullman's theory may be reformulated by replacing the K region by the M region. The M-L regions theory improves all the quantum structure-carcinogenic activity relationships obtained previously in the K-L framework. Moreover, it would appear that in these correlations, the most important role is played by nonconcerted electrophilic reactions. We suggest that the M-L modified Pullman's theory and the Bay (B) region theory, proposed by Jerina et al., are related to different steps of the metabolic activation mechanism leading to ultimate carcinogen: the first step for the Pullman's theory and the carbocation step for the theory of the Bay region. We have termed the “M, L and B regions theory” as this unified approach to the problem of polyacens carcinogenesis.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 2146-2147 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 2055-2059 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 746-752 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Competitive liquid-phase hydrodesulfurization of thiophene and hydrogenation of cyclohexene on a monolithic CoMo/γ-Al2O3 catalyst were studied. The flow pattern in the monolithic catalyst reactor was segmented gas-liquid flow (slug flow). The hydrogen pressure and the temperature were varied between 30-40 bar and 509-523 K, respectively. The experimental data are consistent with rate expressions of the Langmuir-Hinshelwood type where the reactions proceed on two different types of active sites. This kinetic model is based on hydrogenation of the thiophene ring prior to sulfur elimination.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 1815-1823 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A finite-element analysis of Taylor flow in a cylindrical capillary was performed using a commercial FEM program (FIDAP) to solve the fundamental fluid dynamics equations together with the capillary forces at the gas-liquid interface. A moving-surface formulation was used to calculate the bubble shape. The thickness of the liquid film surrounding the gas bubble, the degree of mixing in the liquid phase, and the slip velocity between the two phases were calculated. These parameters influence the performance of monolith reactors operating in the Taylor flow regime. On comparison with experimental results it was found that the FEM calculation generally predicts a thinner liquid film, which can possibly be explained in terms of a peripheral variation in surface tension. Moreover, the wavelength of the wiggles predicted in the liquid film near the tail end of the bubble was compared to those arising from a simplified mathematical analysis available in the literature. Good agreement was found for Ca 〈 0.005, while for higher Ca the FEM predicts significantly shorter wavelengths, indicating that the lubrication theory is not valid here.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    ISSN: 0020-7608
    Schlagwort(e): Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: This study is a unified approach to quantum theories of polyacen carcinogenesis. Part II is on the role of the K-region in metabolic activation process leading to ultimate carcinogen and discusses the M, L, and BK theory. The saturation of the polyacen K-region, or the transformation into a quinoid one, deactivates the carcinogenic process going through a diol epoxyde, which results in Bay-region carbocation. K and B regions must be considered as two interdependent parts of the same structural entity, which may be termed the BK-region. The M, L, and BK theory achieves a complete unification of the Pullman and Jerina and other theories.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Brookfield, Conn. : Wiley-Blackwell
    Journal of Vinyl and Additive Technology 15 (1993), S. 17-21 
    ISSN: 0193-7197
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: This study seeks to substitute fumed silica for chlorinated polyethylene (CPE) within a rigid PVC formulation intended for profile extrusion such as doors and window frames. The effect of fumed silica on both mechanical (tensile and impact) and thermal (Vicat point, HDT, and linear thermal expansion coefficient) properties were investigated. Five rigid PVC formulations were prepared, including a reference one (F1), then F1 with CPE, F1 with untreated silica, F1 with heat treated silica, and finally F1 with dried silica and a coupling agent. The effect of CPE on mechanical properties was very modest. On the other hand, CPE showed its inefficiency, in that HDT and Vicat point were decreased. Heat treated silica showed the greatest improvement in both mechanical and thermal properties. Untreated silica showed a small effect on both properties. Finally, the incorporation of coupling agent gave considerable improvement in both mechanical and thermal properties.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Publikationsdatum: 2019-06-28
    Beschreibung: The present numerical study is concerned with the fundamental physics of the multi-way interaction between turbulence, chemical reaction and buoyancy in a nonpremixed flame. The method of direct numerical simulation (DNS) is used to solve the instantaneous three-dimensional governing equations (continuity, Navier-Stokes, species mass fractions and energy) under the zero-Mach number assumption. Because of the present supercomputer limitations, we consider two simple flow geometries, namely an initially uniform flow without shear (equivalent to grid-generated turbulence) and an initially uniform shear flow. In each flow, the fuel and oxidant initially exist as two separate streams. As the reactants mix, chemical reaction takes place and exothermic energy is released causing variations in density. In the presence of a gravity field, the spatial and temporal distributions of the induced buoyancy forces depend on the local density gradients and the direction of the gravitational acceleration.
    Schlagwort(e): Inorganic and Physical Chemistry
    Materialart: Fourth International Microgravity Combustion Workshop; 173-178; NASA-CP-10194
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    facet.materialart.
    Unbekannt
    In:  CASI
    Publikationsdatum: 2019-06-28
    Beschreibung: Trace levels of molecular oxygen are measured by introducing a gas containing the molecular oxygen into a target zone, and impacting the molecular oxygen in the target zone with electrons at the O(-) resonant energy level for dissociative electron attachment to produce O(-) ions. Preferably, the electrons have an energy of about 4 to about 10 eV. The amount of O(-) ions produced is measured, and is correlated with the molecular oxygen content in the target zone. The technique is effective for measuring levels of oxygen below 50 ppb. and even less than 1 ppb. The amount of O(-) can be measured in a quadrupole mass analyzer. Best results are obtained when the electrons have an energy of about 6 to about 8 eV. and preferably about 6.8 eV. The method can be used for other species by selecting the appropriate electron energy level.
    Schlagwort(e): Inorganic and Physical Chemistry
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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