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  • Coherent structures  (1)
  • Keywords. Potentiometry; Glycine; Cephalosporins; Complexes.  (1)
  • 2020-2021
  • 2000-2004  (2)
  • 1960-1964
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Monatshefte für Chemie 131 (2000), S. 1031-1038 
    ISSN: 1434-4475
    Schlagwort(e): Keywords. Potentiometry; Glycine; Cephalosporins; Complexes.
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary.  The interaction of Ca(II), Cu(II), Zn(II), Pb(II), and La(III) ions with the antibiotics cephalexin, cefadroxil, cephaloridine, and cefoperazone as secondary ligands was investigated potentiometrically. The formation constants were determined for a ligand-to-metal ratio of 1:1 at 25°C and KNO3. The protonation constants of the complexes were evaluated for the system . The order of stability of the binary and ternary complexes were examined. It was found that glycine adds preferably [M(II)-cephalosporin] rather than to the aqueous complexes of M(II). In all cases 1:1:1 complexes were formed.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    ISSN: 1573-1472
    Schlagwort(e): Coherent structures ; Numerical modelling ; Turbulence
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Physik
    Notizen: Abstract In two preceding papers, coherent structures of theatmospheric boundary layer (ABL), such as rollvortices or cells, were investigated through radar andaircraft observations collected during the TRAC-93(Turbulence Radar Aircraft Cells) experiment held inFrance in June 1993. The analysis of this experimentaldata set provided information on the spatialcharacteristics of these organisations (length scale,orientation, type ... ), their temporal and verticalevolution, and their relation with the dynamic andthermodynamic conditions of the ABL. For the thirdpaper in this series, a large eddy simulation model is used to examine the impact of thecoherent structures on the ABL vertical fluxes. Theanalysis of the simulated horizontal fields is madewith two-dimensional auto and cross-correlationsapplied on different pertinent ABL variables. Theresults emphasise a directional anisotropy of theseorganised fields throughout the ABL, much morepronounced in the heat flux fields, not only at thelength scale of organisations but also at theturbulence scales. This finding has an importantconsequence for traditional ABL flux measurementsbased on the hypothesis of isotropic and homogeneousturbulence. It can explain part of the underestimationof the surface fluxes often mentioned in theliterature. This approach makes it possible tomodify the concept of diffusion time (in chemicalmodelling) and could also lead to revised ABLparameterisations in Range Scale models.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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