ISSN:
1572-8854
Keywords:
antimony(V)
;
mononuclear carboxylate
;
heptacoordinated, structure
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The X-ray structure of a novel mononuclear heptacoordinated compound chlorodiphenylantimony(V) bis(2-methyl benzoate), SbPh2CI(O2C—2—Me—C6H4)2 is described. Crystal data are: Monoclinic, P21/c, a = 8.791(3), b = 21.687(3), c = 13.488(4) Å, β = 103.78(2)°, and Z = 4. A distorted pentagonal bipyramidal geometry for antimony with both the carboxylates chelating is found in the solid state.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009505724312
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