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  • Lunar and Planetary Science and Exploration  (53)
  • ASTROPHYSICS
  • Chemistry
  • Humans
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  • 2015-2019  (73)
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  • 1930-1934
  • 2018  (73)
  • 1
    Publication Date: 2018-10-05
    Description: Photocatalysis based on optically active, "plasmonic" metal nanoparticles has emerged as a promising approach to facilitate light-driven chemical conversions under far milder conditions than thermal catalysis. However, an understanding of the relation between thermal and electronic excitations has been lacking. We report the substantial light-induced reduction of the thermal activation barrier for ammonia decomposition on a plasmonic photocatalyst. We introduce the concept of a light-dependent activation barrier to account for the effect of light illumination on electronic and thermal excitations in a single unified picture. This framework provides insight into the specific role of hot carriers in plasmon-mediated photochemistry, which is critically important for designing energy-efficient plasmonic photocatalysts.
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
    Publication Date: 2019-07-13
    Description: We present the first comprehensive set of lunar exospheric line width and line width derived effective temperatures as a function of lunar phase (66 waxing phase to 79 waning phase). Data were collected between November 2013 and May 2014 during six observing runs at the National Solar Observatory McMath-Pierce Solar Telescope by applying high-resolution Fabry-Perot spectroscopy (R ~ 180,000) to observe emission from exospheric sodium (5,889.9509 , D2 line). The 3-arc min field of view of the instrument, corresponding to ~336 km at the mean lunar distance (384,400 km), was positioned at several locations off the lunar limb; only equatorial observations taken out to 950 km are presented here. We find the sodium effective temperature distribution to be approximately a symmetric function of lunar phase with respect to full Moon. Within magnetotail passage we find temperatures in the range of 2500-9000 K. For phase angles greater than 40deg we find that temperatures flatten out to ~1700 K.
    Keywords: Lunar and Planetary Science and Exploration
    Type: GSFC-E-DAA-TN61679 , Journal of Geophysical Research: Planets (ISSN 2169-9097) (e-ISSN 2169-9100); 123; 9; 2430-2444
    Format: text
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  • 3
    Publication Date: 2019-07-13
    Description: The presence of allophane and other nanophase materials on Mars indicates a time when water was intermittent and short lived. These materials likely represent partially altered or leached basaltic ash and therefore, could represent a geologic marker for where water was present on the Martian surface. Further, they may indicate regions of climate change, where surface water was not present long enough to form clays. Characterization of these materials is important for increasing spectral recognition capacities of our current Martian science array. Ongoing work suggests that variability in the Al:Si ratio of allophane can dictate the amount of both structural and adsorbed water in the crystalline structure.
    Keywords: Lunar and Planetary Science and Exploration
    Type: LPI Contrib. No. 2083-2137 , JSC-E-DAA-TN54276 , Lunar and Planetary Science Conference (LPSC); Mar 19, 2018 - Mar 23, 2018; Woodlands, TX; United States
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  • 4
    Publication Date: 2018-07-27
    Description: Vinyl carbocations have been the subject of extensive experimental and theoretical studies over the past five decades. Despite this long history in chemistry, the utility of vinyl cations in chemical synthesis has been limited, with most reactivity studies focusing on solvolysis reactions or intramolecular processes. Here we report synthetic and mechanistic studies of vinyl cations generated through silylium–weakly coordinating anion catalysis. We find that these reactive intermediates undergo mild intermolecular carbon-carbon bond–forming reactions, including carbon-hydrogen (C–H) insertion into unactivated sp 3 C–H bonds and reductive Friedel-Crafts reactions with arenes. Moreover, we conducted computational studies of these alkane C–H functionalization reactions and discovered that they proceed through nonclassical, ambimodal transition structures. This reaction manifold provides a framework for the catalytic functionalization of hydrocarbons using simple ketone derivatives.
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 5
    Publication Date: 2018-06-22
    Description: It is commonly assumed that recognition and discrimination of chirality, both in nature and in artificial systems, depend solely on spatial effects. However, recent studies have suggested that charge redistribution in chiral molecules manifests an enantiospecific preference in electron spin orientation. We therefore reasoned that the induced spin polarization may affect enantiorecognition through exchange interactions. Here we show experimentally that the interaction of chiral molecules with a perpendicularly magnetized substrate is enantiospecific. Thus, one enantiomer adsorbs preferentially when the magnetic dipole is pointing up, whereas the other adsorbs faster for the opposite alignment of the magnetization. The interaction is not controlled by the magnetic field per se, but rather by the electron spin orientations, and opens prospects for a distinct approach to enantiomeric separations.
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 6
    Publication Date: 2018-03-16
    Description: Single adatoms are expected to participate in many processes occurring at solid surfaces, such as the growth of graphene on metals. We demonstrate, both experimentally and theoretically, the catalytic role played by single metal adatoms during the technologically relevant process of graphene growth on nickel (Ni). The catalytic action of individual Ni atoms at the edges of a growing graphene flake was directly captured by scanning tunneling microscopy imaging at the millisecond time scale, while force field molecular dynamics and density functional theory calculations rationalize the experimental observations. Our results unveil the mechanism governing the activity of a single-atom catalyst at work.
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 7
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    American Association for the Advancement of Science (AAAS)
    In: Science
    Publication Date: 2018-02-23
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 8
    Publication Date: 2019-07-12
    Description: For the first time in human history, we will soon be able to apply to the scientific method to the question "Are We Alone?" The rapid advance of exoplanet discovery, planetary systems science, and telescope technology will soon allow scientists to search for life beyond our Solar System through direct observation of extrasolar planets. This endeavor will occur alongside searches for habitable environments and signs of life within our Solar System. While these searches are thematically related and will inform each other, they will require separate observational techniques. The search for life on exoplanets holds potential through the great diversity of worlds to be explored beyond our Solar System. However, there are also unique challenges related to the relatively limited data this search will obtain on any individual world.
    Keywords: Lunar and Planetary Science and Exploration
    Type: GSFC-E-DAA-TN52771
    Format: application/pdf
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  • 9
    Publication Date: 2019-07-13
    Description: The Kepler spacecraft's imaging photometer monitored the Pluto system from October-December 2015 during Campaign 7 of the K2 extended mission. Kepler obtained an unprecedented and fortuitous nearly continuous 12-Pluto day lightcurve from measurements acquired every 30 min using long cadence sampling. This 3-month-long baseline anchors the Pluto+Charon lightcurve near the time of the New Horizons July 2015 encounter, observing at solar phase angles between 1.16 and 1.74. Long-term modeling of Pluto's lightcurve will ultimately reveal its long-term seasonal variation. K2's combined Pluto+Charon lightcurves measured at this epoch have an average total amplitude of 0.120+/- 0.006, 0.07 magnitudes smaller than the amplitude predicted by a static frost model (Buie and Tholen, 1989) projected from Hubble Space Telescope surface maps (Buie et al., 1992). Subtracting a static Charon lightcurve from the Pluto+Charon K2 lightcurve produces the same results. Likewise, we subtract each rotation model from the model for the first full rotation and find that the average difference of all variations is 0.017 +/- 0.008 magnitudes. Moreover, the difference between the first and last K2 rotation is 0.005 magnitudes, implying that there are no significant changes in the lightcurve during the 3 months of K2 observations. These results are consistent with seasonal transport on Pluto's surface and the predictions of Buratti et al. (2015a). However, a detailed understanding of the surface-atmosphere interactions associated with these phenomena requires decades of monitoring.
    Keywords: Lunar and Planetary Science and Exploration
    Type: GSFC-E-DAA-TN60769 , Icarus (ISSN 0019-1035); 314; 265-273
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  • 10
    Publication Date: 2019-07-13
    Description: NASA's Resource Prospector (RP) mission is intended to characterize the three-dimensional nature of volatiles in lunar polar and permanently shadowed regions. The Near-Infrared Volatile Spectrometer System (NIRVSS) observes while a drill penetrates to a maximum depth of 1 m. Any 10 cm increment of soil identified as containing water ice can be delivered to a heating crucible with the evolved gas delivered to a gas chromatograph / mass spectrometer. NIRVSS consists of two components; a spectrometer box (SB) and bracket assembly (BA), connected by two fiber optic cables. The SB contains separate short- and long-wavelength spectrometers, SW and LW respectively, that collectively span the 1600-3400 nm range. The BA contains an IR emitter (lamp), drill observation camera (DOC, 2048 x 2048 CMOS detector), 8 different wavelength LEDs, and a longwave calibration sensor (LCS) measuring the surface emissivity at four IR wavelengths. Tests of various RP sub-systems have been under-taken in a large cryo-vacuum chamber at Glenn Re-search Center. The chamber accommodates a tube (1.2 m high x 25.4 cm diameter) filled with lunar simulant, NU-LHT-3M, prepared with known abundances of water. Thermocouples are embedded at different depths, and also across the surface of the soil tube. In the chamber the tube is cooled with LN2 as the pressure is reduced to approx. 5-6x10(exp -6) Torr. For the May 2016 tests two soil tubes were prepared with initially 2.5 Wt.% water. The shroud surrounding the soil tube was held at different temperatures for each tube to simulate a warm and cold lunar environment. Table 1 provides a summary of experimental conditions and Figure 1 shows the nominal view of the NIRVSS components, the drill foot, and the top of the soil tube. Once the average soil temperature reached approx. 178 K, drilling commenced. During drilling activities NIRVSS was alternating between obtaining spectra and obtaining images. Here we discuss NIRVSS spectral data obtained during controlled drill percussions.
    Keywords: Lunar and Planetary Science and Exploration
    Type: ARC-E-DAA-TN52117 , Lunar and Planetary Science Conference; Mar 19, 2018 - Mar 23, 2018; The Woodlands, TX; United States
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