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  • 2020-2022
  • 2015-2019  (6)
  • 2010-2014
  • 2018  (6)
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  • 2020-2022
  • 2015-2019  (6)
  • 2010-2014
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  • 1
    Publication Date: 2018-10-12
    Description: Surface coarse structure is one of key factors affecting the superhydrophobicity, yet it’s not very clear that what kind of structure is the best for hydrophobicity. Herein in order to study the effect of surface coarse structure, eight kinds of spherical SiO 2 (20 nm, 60 nm, 200 nm, 500 nm, 1 μm, 2 μm, 5 μm and 10 μm) were taken as raw material respectively to explore the effect of particle size on the hydrophobic performance. SiO 2 was deposited on the glass substrate layer by layer using the electrostatic assembly method based on the reaction of amino and epoxy groups. The sample’s structure and properties were characterized respectively by scanning electron microscopy and contact angle measuring instrument. The relationship between SiO 2 particle size and surface hydrophobicity was explored and the superhydrophobic stability were tested. The results show that the surface of SiO 2 film layers are stacked together and arranged tightly, a...
    Print ISSN: 1755-1307
    Electronic ISSN: 1755-1315
    Topics: Geography , Geosciences , Physics
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  • 2
    Publication Date: 2018-02-10
    Description: The development of membrane technology is central to fields ranging from resource harvesting to medicine, but the existing designs are unable to handle the complex sorting of multiphase substances required for many systems. Especially, the dynamic multiphase transport and separation under a steady-state applied pressure have great benefits for membrane science, but have not been realized at present. Moreover, the incorporation of precisely dynamic control with avoidance of contamination of membranes remains elusive. We show a versatile strategy for creating elastomeric microporous membrane-based systems that can finely control and dynamically modulate the sorting of a wide range of gases and liquids under a steady-state applied pressure, nearly eliminate fouling, and can be easily applied over many size scales, pressures, and environments. Experiments and theoretical calculation demonstrate the stability of our system and the tunability of the critical pressure. Dynamic transport of gas and liquid can be achieved through our gating interfacial design and the controllable pores’ deformation without changing the applied pressure. Therefore, we believe that this system will bring new opportunities for many applications, such as gas-involved chemical reactions, fuel cells, multiphase separation, multiphase flow, multiphase microreactors, colloidal particle synthesis, and sizing nano/microparticles.
    Electronic ISSN: 2375-2548
    Topics: Natural Sciences in General
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  • 3
    Publication Date: 2018-02-03
    Description: Absorbing materials are developed with the concept of “thin, light, wide and strong”, and various methods and materials have been attempted to satisfy the demand. In this work, the in situ growth method were conducted to grow reduced graphene (RGO) into carbon fiber (CF) to prepare CF-RGO composites. Moreover, the phase, microstructure and electromagnetic performance of the flexibility and lightweight composites were characterized. Consequently, the XRD and SEM results indicate the RGO is well grown on the surface of CF. The microwave absorption performance of the as-prepared samples were calculated, and the results show that the effective absorption band of the composites move towards low frequency once the RGO were introduced into the CF.
    Print ISSN: 1757-8981
    Electronic ISSN: 1757-899X
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 4
    Publication Date: 2018-02-03
    Description: Ni 0.5 Zn 0.5 Fe 2 O 4 is one of the traditional microwave absorbing materials, and it has attract the focus of the whole world in the past years. The composites behave well in absorbing areas due to its coexistence of dielectric property and ferrimagnetism. The graphene is one of the new absorbing materials and it has been used in varies areas due to its excellent electrical conductivity, thermal conductivity and mechanical properties. In the work, the Ni 0.5 Zn 0.5 Fe 2 O 4 nanoparticles were surficiently compounded with the reduced graphene (RGO), and the microstructure and microwave absorbing performance of the composites were characterized. Consequently, the results indicated that the as-prepared materials perform well in microwave absorption area.
    Print ISSN: 1757-8981
    Electronic ISSN: 1757-899X
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 5
    Publication Date: 2018-06-21
    Description: In this paper, the relaxation kinetics of the oxidation process of the YBaCo 4 O 7+ , Y 0.95 Ti 0.05 BaCo 4 O 7+ and Y 0.5 Dy 0.5 BaCo 4 O 7+ oxygen carriers is studied with isothermal reaction data. XRD analysis for fresh samples shows that all the samples have YBaCo 4 O 7+ structure. Scanning electron microscopy images of samples show that the samples consist of porous agglomerates of primary particles. Isothermal TG experiments are conducted with temperatures of 290°C, 310°C, 330°C and 350°C, respectively. It is found that the Avrami-Eroféev model describes solid-phase changes in the oxygen absorption process adequately. The results show that the distributed activation energies of the oxidation process obtained by the Avrami-Eroféev model are 42.079 kJ mol –1 , 42.944 kJ mol –1 and 41.711 kJ mol –1 for the YBaCo 4 O 7+ , Y 0.95 Ti 0.05 BaCo 4 O 7+ and Y 0.5 Dy 0.5 BaCo 4 O 7+ oxygen carriers, respectively. The kinetic model was obtained to predict the oxygen carrier conversion of oxygen absorption for different time durations. The kinetic parameters obtained here are quite vital when this material is used in reactors.
    Keywords: thermodynamics, energy
    Electronic ISSN: 2054-5703
    Topics: Natural Sciences in General
    Published by Royal Society
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  • 6
    Publication Date: 2018-05-04
    Print ISSN: 1351-0754
    Electronic ISSN: 1365-2389
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by Wiley
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