Publication Date:
2017-01-11
Description:
The formation of Li 7 La 3 Zr 2 O 12 (LLZ), a Li ion conducting oxide with a garnet-type crystal structure, from a powder mixture of Li 2 CO 3 , La(OH) 3 , and ZrO 2 was investigated, and two possible reaction pathways were identified. Based on the obtained results, LLZ was synthesized at low temperatures and short reaction times, using Li 2 CO 3 , La(OH) 3 , and La 2 Zr 2 O 7 (instead of ZrO 2 ) as starting materials. According to the proposed method, single-phase LLZ was obtained by heating the initial mixture to 800°C for 1 hour in air, which eliminated possible Li losses. The produced LLZ species exhibited a tetragonal crystal structure with the lattice parameters a= 1.3189(3) nm and c= 1.2694(1) nm, while their transmission electron microscopy images confirmed that LLZ formation occurred through the dissolution of La 2 Zr 2 O 7 and La(OH) 3 in a Li 2 CO 3 melt followed by LLZ precipitation from solution.
Print ISSN:
0002-7820
Electronic ISSN:
1551-2916
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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