ALBERT

Description: The Amazon region, being a large source of methane (CH4), contributes significantly to the global annual CH4 budget. For the first time, a forward and inverse modelling framework on regional scale for the purpose of assessing the CH4 budget of the Amazon region is implemented. Here, we present forward simulations of CH4 as part of the forward and inverse modelling framework based on a modified version of the Weather Research and Forecasting model with chemistry that allows for passive tracer transport of CH4, carbon monoxide, and carbon dioxide (WRF-GHG), in combination with two different process-based bottom-up models of CH4 emissions from anaerobic microbial production in wetlands and additional datasets prescribing CH4 emissions from other sources such as biomass burning, termites, or other anthropogenic emissions. We compare WRF-GHG simulations on 10 km horizontal resolution to flask and continuous CH4 observations obtained during two airborne measurement campaigns within the Balanço Atmosférico Regional de Carbono na Amazônia (BARCA) project in November 2008 and May 2009. In addition, three different wetland inundation maps, prescribing the fraction of inundated area per grid cell, are evaluated. Our results indicate that the wetland inundation maps based on remote-sensing data represent the observations best except for the northern part of the Amazon basin and the Manaus area. WRF-GHG was able to represent the observed CH4 mixing ratios best at days with less convective activity. After adjusting wetland emissions to match the averaged observed mixing ratios of flights with little convective activity, the monthly CH4 budget for the Amazon basin obtained from four different simulations ranges from 1.5 to 4.8 Tg for November 2008 and from 1.3 to 5.5 Tg for May 2009. This corresponds to an average CH4 flux of 9–31 mg m−2 d−1 for November 2008 and 8–36 mg m−2 d−1 for May 2009.

Description: The main source of information on future climate conditions are global circulation models (GCMs). While the various GCMs agree on an increase of surface temperature, the predictions for precipitation exhibit high spread among the models, especially in shorter-than-daily temporal resolution. This paper presents a method to predict regional distributions of the hourly rainfall depth based on daily mean sea level pressure and temperature data. It is an indirect downscaling method avoiding uncertain precipitation data from the GCM. It is based on a fuzzy logic classification of atmospheric circulation patterns (CPs) that is further subdivided by means of the average daily temperature. The observed empirical distributions at 30 rain gauges to each CP-temperature class are assumed as constant and used for projections of the hourly precipitation sums in the future. The method was applied to the CP-temperature sequence derived from the 20th-century run and the scenario A1B run of ECHAM5. For the study region in southwestern Germany ECHAM5 predicts that the summers will become progressively drier. Nevertheless, the frequency of the highest hourly precipitation sums will increase. According to the predictions, estival water stress and the risk of extreme hourly precipitation will both increase simultaneously during the next decades. However, the results are yet to be confirmed by further mbox{investigation} based on other GCMs.

Description: Although regenerating forests make up an increasingly large portion of humid tropical landscapes, little is known of their water use and effects on streamflow (Q). Since the 1950s the island of Puerto Rico has experienced widespread abandonment of pastures and agricultural lands, followed by forest regeneration. This paper examines the possible impacts of these secondary forests on several Q characteristics for 12 mesoscale catchments (23–346 km2; mean precipitation 1720–3422 mm yr−1) with long (33–51 yr) and simultaneous records for Q, precipitation (P), potential evaporation (PET), and land cover. A simple spatially-lumped, conceptual rainfall–runoff model that uses daily P and PET time series as inputs (HBV-light) was used to simulate Q for each catchment. Annual time series of observed and simulated values of four Q characteristics were calculated. A least-squares trend was fitted through annual time series of the residual difference between observed and simulated time series of each Q characteristic. From this the total cumulative change (Â) was calculated, representing the change in each Q characteristic after controlling for climate variability and water storage carry-over effects between years. Negative values of  were found for most catchments and Q characteristics, suggesting enhanced actual evaporation overall following forest regeneration. However, correlations between changes in urban or forest area and values of  were insignificant (p ≥ 0.389) for all Q characteristics. This suggests there is no convincing evidence that changes in the chosen Q characteristics in these Puerto Rican catchments can be ascribed to changes in urban or forest area. The present results are in line with previous studies of meso- and macro-scale (sub-)tropical catchments, which generally found no significant change in Q that can be attributed to changes in forest cover. Possible explanations for the lack of a clear signal may include errors in the land cover, climate, Q, and/or catchment boundary data; changes in forest area occurring mainly in the less rainy lowlands; and heterogeneity in catchment response. Different results were obtained for different catchments, and using a smaller subset of catchments could have led to very different conclusions. This highlights the importance of including multiple catchments in land-cover impact analysis at the mesoscale.

Description: Although regenerating forests make up an increasingly large portion of humid tropical landscapes, comparatively little is known of their water use and effects on streamflow (Q). Since the 1950s the island of Puerto Rico has experienced widespread abandonment of pastures and agricultural lands, followed by forest regeneration. This paper examines the possible impacts of forest regeneration on several Q metrics for 12 meso-scale catchments (23–346 km2; mean precipitation 1720–3422 mm yr−1) with long (33–51 yr) and simultaneous records for Q, precipitation (P), potential evapotranspiration (PET), and land cover. A simple spatially-lumped, conceptual rainfall-runoff model that uses daily P and PET time series as inputs (HBV-light) was used to simulate Q for each catchment. Annual time series of observed and simulated values of four Q metrics were calculated. A least-squares trend was fitted through annual time series of the residual difference between observed and simulated time series of each Q metric. From this the total cumulative change  was calculated, representing the change in each metric after controlling for climate variability and water storage carry-over effects between years. Negative values of  were found for most catchments and Q metrics, suggesting enhanced actual evapotranspiration overall following forest regeneration. However, correlations between changes in urban or forest area and values of  were insignificant (p ≥ 0.389) for all Q metrics. This suggests there is no convincing evidence that changes in the chosen Q metrics in these Puerto Rican catchments can be ascribed to changes in urban or forest area. The present results are in line with previous studies of meso- and macro-scale (sub-)tropical catchments, which generally found no significant change in Q that can be attributed to changes in forest cover. Possible explanations for the apparent lack of a clear signal may include: errors in the land-cover, climate, Q, and/or catchment boundary data; changes in forest area occurring mainly in the less rainy lowlands; and heterogeneity in catchment response. Different results were obtained for different catchments, and using a smaller subset of catchments could have led to very different conclusions. This highlights the importance of including multiple catchments in land-cover impact analysis at the meso scale.

Description: Many hydraulic applications like the design of urban sewage systems require projections of future precipitation in high temporal resolution. We developed a method to predict the regional distribution of hourly precipitation sums based on daily mean sea level pressure and temperature data from a Global Circulation Model. It is an indirect downscaling method avoiding uncertain precipitation data from the model. It is based on a fuzzy-logic classification of atmospheric circulation patterns (CPs) that is further subdivided by means of the average daily temperature. The observed empirical distributions at 30 rain gauges to each CP-temperature class are assumed as constant and used for projections of the hourly precipitation sums in the future. The method was applied to the CP-temperature sequence derived from the 20th century run and the scenario A1B run of ECHAM5. According to ECHAM5, the summers in southwest Germany will become progressively drier. Nevertheless, the frequency of the highest hourly precipitation sums will increase. According to the predictions, estival water stress and the risk of extreme hourly precipitation will both increase simultaneously during the next decades.

Description: This study investigates the use of total column CH4 (XCH4) retrievals from the SCIAMACHY satellite instrument for quantifying large scale emissions of methane. A unique data set from SCIAMACHY is available spanning almost a decade of measurements, covering a period when the global CH4 growth rate showed a marked transition from stable to increasing mixing ratios. The TM5 4DVAR inverse modelling system has been used to infer CH4 emissions from a combination of satellite and surface measurements for the period 2003–2010. In contrast to earlier inverse modelling studies, the SCIAMACHY retrievals have been corrected for systematic errors using the TCCON network of ground based Fourier transform spectrometers. The aim is to further investigate the role of bias correction of satellite data in inversions. Methods for bias correction are discussed, and the sensitivity of the optimized emissions to alternative bias correction functions is quantified. It is found that the use of SCIAMACHY retrievals in TM5 4DVAR increases the estimated inter-annual variability of large-scale fluxes by 22% compared with the use of only surface observations. The difference in global methane emissions between two year periods before and after July 2006 is estimated at 27–35 Tg yr−1. The use of SCIAMACHY retrievals causes a shift in the emissions from the extra-tropics to the tropics of 50 ± 25 Tg yr−1. The large uncertainty in this value arises from the uncertainty in the bias correction functions. Using measurements from the HIPPO and BARCA aircraft campaigns, we show that systematic errors are a main factor limiting the performance of the inversions. To further constrain tropical emissions of methane using current and future satellite missions, extended validation capabilities in the tropics are of critical importance.

Description: Firn and polar ice cores offer the only direct paleoatmospheric archive. Analyses of past greenhouse gas concentrations and their isotopic compositions in air bubbles in the ice can help to constrain changes in global biogeochemical cycles in the past. For the analysis of the hydrogen isotopic composition of methane (δD (CH4)) 0.5 to 1.5 kg of ice was previously necessary to achieve the required precision. Here we present a method to improve precision and reduce the sample amount for δD (CH4) measurements on (ice core) air. Pre-concentrated methane is focused before a high temperature oven (pre pyrolysis trapping), and molecular hydrogen formed by pyrolysis is trapped afterwards (post pyrolysis trapping), both on a carbon-PLOT capillary at −196 °C. A small amount of methane and krypton are trapped together with H2 and must be separated using a short second chromatographic column to ensure accurate results. Pre and post pyrolysis trapping largely removes the isotopic fractionation induced during chromatographic separation and results in a narrow peak in the mass spectrometer. Air standards can be measured with a precision better than 1‰. For polar ice samples from glacial periods we estimate a precision of 2.2‰ for 350 g of ice (or roughly 30 mL (at standard temperature and pressure (STP)) of air) with 350 ppb of methane. This corresponds to recent tropospheric air samples (about 1900 ppb CH4) of about 6 mL (STP) or about 500 pmol of pure CH4.