ALBERT

Description: Improvements in our ability to model runoff from glaciers remain an important scientific goal. This paper describes a new temperature-radiation-index glacier melt model specifically enhanced for use in High-Arctic environments, utilising high temporal and spatial resolution datasets while retaining relatively modest data requirements. The model employs several physically constrained parameters and was tuned using a lidar-derived surface elevation model of Midtre Lovénbreen, meteorological data from sites spanning ~70% of the glacier's area-altitude distribution, and periodic ablation surveys during the 2005 melt season. The model explained 80% of the variance in observed ablation across the glacier, an improvement of ~40% on a simplified energy balance model (EBM), yet equivalent to the performance of a full EBM employed at the same location. Model performance was assessed further by comparing potential and measured runoff from the catchment, and through application to an earlier (2004) melt season. The additive model form and consideration of a priori parameters for the Arctic locality were shown to be beneficial, with a planimetry correction eliminating systematic errors in potential runoff. Further parameterisations defining modelled incident radiation failed to yield significant improvements to model output. Our results suggest that such enhanced melt models may perform well for singular melt seasons, yet are highly sensitive to the choice of lapse rates and their transferability to different locations and seasons may be limited. While modelling ablation requires detailed consideration of the transition between snow- and ice-melt, our study suggests that description of the ratio between radiative and turbulent heat fluxes may provide a useful step towards dynamic parameterisation of melt factors in temperature-index models. Copyright © 2012 John Wiley & Sons, Ltd.

Description: We designed, synthesized, and screened a library of analogs of the organophosphate pesticide metabolite paraoxon against a recombinant variant of human serum paraoxonase-1. Alterations of both the aryloxy leaving group and the retained alkyl chains of paraoxon analogs resulted in substantial changes to binding and hydrolysis, as measured directly by spectrophotometric methods or in competition experiments with paraoxon. Increases or decreases in the steric bulk of the retained groups generally reduced the rate of hydrolysis, while modifications of the leaving group modulated both binding and turnover. Studies on the hydrolysis of phosphoryl azide analogs as well as amino-modified paraoxon analogs, the former being developed as photoaffinity labels, found enhanced tolerance of structural modifications when compared with O -alkyl-substituted molecules. Results from computational modeling predict a predominant active site binding mode for these molecules, which is consistent with several proposed catalytic mechanisms in the literature and from which a molecular-level explanation of the experimental trends is attempted. Overall, the results of this study suggest that while paraoxonase-1 is a promiscuous enzyme, there are substantial constraints in the active site pocket, which may relate to both the leaving group and the retained portion of paraoxon analogs. Copyright © 2012 John Wiley & Sons, Ltd. We designed, synthesized, and screened a library of analogs of the organophosphate pesticide metabolite paraoxon against a recombinant paraoxonase-1. Increases or decreases in the steric bulk of the retained groups generally reduced the rate of hydrolysis, while modifications of the leaving group modulated both binding and turnover. Computational modeling predicted a predominant active site binding mode for these molecules, which is consistent with several proposed catalytic mechanisms in the literature.

Description: The capacity of forests to mitigate global climate change can be negatively influenced by tropospheric ozone that impairs both photosynthesis and stomatal control of plant transpiration, thus affecting ecosystem productivity and watershed hydrology. We have evaluated individual and interactive effects of ozone and climate on late season streamflow for six forested watersheds (38-970,000 ha) located in the southeastern United States. Models were based on 18-26 year data records for each watershed and involved multivariate analysis of interannual variability of late season streamflow in response to physical and chemical climate during the growing season. In all cases, some combination of ozone variables significantly improved model performance over climate-only models. Effects of ozone and ozone×climate interactions were also consistently negative and were proportional to variations in actual ozone exposures, both spatially across the region and over time. Conservative estimates of the influence of ozone on the variability (R 2 ) of observed flow ranged from 7% in the area of lowest ozone exposure in West Virginia to 23% in the areas of highest exposure in Tennessee. Our results are supported by a controlled field study using free-air concentration enrichment (FACE) methodology which indicated progressive ozone-induced loss of stomatal control over tree transpiration during the summer in mixed aspen-birch stands. Despite the frequent assumption that ozone reduces tree water loss, our findings support increasing evidence that ozone at near ambient concentrations can reduce stomatal control of leaf transpiration, and increase water use. Increases in evapotranspiration and associated streamflow reductions in response to ambient ozone exposures are expected to episodically increase the frequency and severity of drought and affect flow-dependent aquatic biota in forested watersheds. Regional and global models of hydrologic cycles and related ecosystem functions should consider potential interactions of ozone with climate under both current and future warmer and ozone enriched climatic conditions. © 2012 Blackwell Publishing Ltd

Description: Estuarine and early-marine survival of transported and in-river migrant Snake River spring Chinook salmon smolts Scientific Reports 2, 11062012 doi: 10.1038/srep00448 Erin L. Rechisky David W. Welch Aswea D. Porter Melinda C. Jacobs-Scott Paul M. Winchell John L. McKern Many juvenile Snake River Chinook salmon are transported downriver to avoid hydroelectric dams in the Columbia River basin. As mortality to the final dam is ∼50%, transported fish should return as adults at roughly double the rate of nontransported fish; however, the benefit of transportation has not been realized consistently. “Delayed” mortality caused by transportation-induced stress is one hypothesis to explain reduced returns of transported fish. Differential timing of ocean entry is another. We used a large-scale acoustic telemetry array to test whether survival of transported juvenile spring Chinook is reduced relative to in-river migrant control groups after synchronizing ocean entry timing. During the initial 750 km, 1 month long migration after release, we found no evidence of decreased estuarine or ocean survival of transported groups; therefore, decreased survival to adulthood for transported Chinook is likely caused by factors other than delayed effects of transportation, such as earlier ocean entry.

Description: The Pampean flat-slab region, located in central Argentina and Chile between 29° and 34°S, is considered a modern analog for Laramide flat-slab subduction within western North America. Regionally, flat-slab subduction is characterized by the Nazca slab descending to ∼100 km depth, flattening out for ∼300 km laterally before resuming a more “normal” angle of subduction. Flat-slab subduction correlates spatially with the track of the Juan Fernandez Ridge, and is associated with the inboard migration of deformation and the cessation of volcanism within the region. To better understand flat-slab subduction we combine ambient-noise tomography and earthquake-generated surface wave measurements to calculate a regional 3D shear velocity model for the region. Shear wave velocity variations largely relate to changes in lithology within the crust, with basins and bedrock exposures clearly defined as low- and high-velocity regions, respectively. We argue that subduction-related hydration plays a significant role in controlling shear wave velocities within the upper mantle. In the southern part of the study area, where normal-angle subduction is occurring, the slab is visible as a high-velocity body with a low-velocity mantle wedge above it, extending eastward from the active arc. Where flat-slab subduction is occurring, slab velocities increase to the east while velocities in the overlying lithosphere decrease, consistent with the slab dewatering and gradually hydrating the overlying mantle. The hydration of the slab may be contributing to the excess buoyancy of the subducting oceanic lithosphere, helping to drive flat-slab subduction.

Description: The Weather Research and Forecasting (WRF) model is used to explore the sensitivity of the large-scale atmospheric energy and moisture budgets to prescribed changes in Arctic sea ice and sea surface temperatures (SSTs). Observed sea ice fractions and SSTs from 1996 and 2007, representing years of high and low sea ice extent, are used as lower boundary conditions. A pan-Arctic domain extending into the North Pacific and Atlantic Oceans is used. ERA-Interim reanalysis data from 1994 to 2008 are employed as initial and lateral forcing data for each high and low sea ice simulation. The addition of a third ensemble, with a mixed SST field between years 1996 and 2007 (using 2007 SSTs above 66°N and 1996 values below), results in a total of three 15-member ensembles. Results of the simulations show both local and remote responses to reduced sea ice. The local polar cap averaged response is largest in October and November, dominated by increased turbulent heat fluxes resulting in vertically deep heating and moistening of the Arctic atmosphere. This warmer and moister atmosphere is associated with an increase in cloud cover, affecting the surface and atmospheric energy budgets. There is an enhancement of the hydrologic cycle, with increased evaporation in areas of sea ice loss paired with increased precipitation. Most of the Arctic climate response results from within-Arctic changes, although some changes in the hydrologic cycle reflect circulation responses to midlatitude SST forcing, highlighting the general sensitivity of the Arctic climate.

Description: Today's agriculture and the food systems that it underpins are at crossroads. Food security – the availability of and access to sufficient and healthy foods and good nutrition - is central for the well being of people and nations. Until recently, it was expected that despite climate change and increasing world population, there would be several decades with food surplus - and low prices - ahead (IPCC, 2007)

Description: We report the observation of a large linear magnetoresistance in the ohmic regime in commonplace commercial n-type silicon wafer with a P dopant density of (1.4±0.1) ×1015 cm–3, and report measurements of it in the temperature range 30–200 K. It arises from the deformation of current paths, which causes a part of the Hall field to be detected at the voltage probes. In short, wide samples we found linear magnetoresistance as large as 4707% in an 8 tesla field at 35 K. Sample geometry effects like these are commonplace in commercial Hall sensors. However, we found that the effect persisted in long, thin samples where the macroscopic current flow should be uniform between the voltage probes: we observed a magnetoresistance of 445% under the same conditions as above. We interpret this result as arising due to spatial fluctuations in the donor density, in the spirit of the Herring model. Scientific Reports 2 doi: 10.1038/srep00565