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  • 2020-2022
  • 2005-2009  (5)
  • 2008  (5)
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  • 2020-2022
  • 2005-2009  (5)
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  • 1
    Publication Date: 2024-01-09
    Keywords: 165-999A; AGE; Alkalinity, total; Boron/Calcium ratio; Calculated; Carbonate ion; Carbon dioxide; Caribbean Sea; DEPTH, sediment/rock; DRILL; Drilling/drill rig; Joides Resolution; Leg165; Multi-collector inductively coupled plasma mass spectrometer (MC-ICP-MS); Ocean Drilling Program; ODP; pH; Salinity; δ11B; δ11B, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 414 data points
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  • 2
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    In:  Supplement to: Foster, Gavin L (2008): Seawater pH, pCO2 and [CO3 [2-] ] variations in the Caribbean Sea over the last 130 kyr: A boron isotope and B/Ca study of planktic foraminifera. Earth and Planetary Science Letters, 271(1-4), 254-266, https://doi.org/10.1016/j.epsl.2008.04.015
    Publication Date: 2024-06-26
    Description: Here a new analytical methodology is described for measuring the isotopic composition of boron in foraminifera using multicollector inductively coupled plasma mass spectrometry (MC-ICPMS). This new approach is fast (~10 samples analysed in duplicate per analytical session) and accurate (to better than 0.25 per mil at 95% confidence) with acceptable sample size requirements (1-3 mg of carbonate). A core top calibration of several common planktic and two benthic species from geographically widespread localities shows a very close agreement between the isotopic composition measured by MC-ICPMS and the isotopic composition of B(OH)-4 in seawater (as predicted using the recently measured isotopic equilibrium factor of 1.0272) at the depth of habitat. A down core and core top investigation of boron concentration (B/Ca ratio) shows that the partition coefficient is influenced by [CO2-3] complicating the application of this proxy. Nevertheless, it is demonstrated that these two proxies can be used to fully constrain the carbonate system of surface water in the Caribbean Sea (ODP Site 999A) over the last 130 kyr. This reconstruction shows that during much of the Holocene and the last interglacial period surface water at Site 999A was in equilibrium with the atmosphere with respect to CO2. During the intervening colder periods although the surface water pCO2 was lower than the Holocene, it was a minor to significant source of CO2 to the atmosphere possibly due to either an expansion of the eastern equatorial Atlantic upwelling zone, or a more local expansion of coastal upwelling in the southern Caribbean. Such reorganisation of the oceanic carbonate system in favour of a larger source of CO2 to the atmosphere from the equatorial ocean may require mechanisms responsible for lowering atmospheric CO2 during glacial periods to be more efficient than previously supposed.
    Keywords: 108-664C; 108-668B; 130-806A; 138-847B; 138-851B; 154-925B; 165-999A; Agadir Canyon; BOFS11891#4; BOFS11905#1; BOFS11K; BOFS17K; Cape Basin; Caribbean Sea; D184; Discovery (1962); DRILL; Drilling/drill rig; GeoB1208-2; GeoB4216-1; Gravity corer (Kiel type); Joides Resolution; KAL; Kasten corer; Leg108; Leg130; Leg138; Leg154; Leg165; M12/1; M37/1; Meteor (1986); Northeast Atlantic; North Pacific Ocean; Ocean Drilling Program; ODP; SL; South Atlantic Ocean
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 3
    Publication Date: 2024-06-26
    Keywords: -; 108-664C; 108-668B; 130-806A; 138-847B; 138-851B; 154-925B; 165-999A; Agadir Canyon; BOFS11891#4; BOFS11905#1; BOFS11K; BOFS17K; Boron/Calcium ratio; Boron hydroxide/Bicarbonate ratio; Calculated; Cape Basin; Carbonate ion; Caribbean Sea; Cibicidoides mundulus, δ18O; Cibicidoides wuellerstorfi, δ18O; Confidence; D184; DEPTH, sediment/rock; Discovery (1962); DRILL; Drilling/drill rig; Elevation of event; Event label; GeoB1208-2; GeoB4216-1; Globigerinoides ruber white, δ18O; Globigerinoides sacculifer sac, δ18O; Gravity corer (Kiel type); Joides Resolution; KAL; Kasten corer; Latitude of event; Leg108; Leg130; Leg138; Leg154; Leg165; Longitude of event; M12/1; M37/1; Mass spectrometer Finnigan MAT 252; Meteor (1986); Multi-collector inductively coupled plasma mass spectrometer (MC-ICP-MS); Neogloboquadrina dutertrei, δ18O; Northeast Atlantic; North Pacific Ocean; Ocean Drilling Program; ODP; pH; Salinity; SL; South Atlantic Ocean; Species; Temperature, water; δ11B; δ11B, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 318 data points
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  • 4
    Publication Date: 2008-08-01
    Print ISSN: 0028-0836
    Electronic ISSN: 1476-4687
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Published by Springer Nature
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  • 5
    Publication Date: 2008-10-13
    Description: The Mid-Pliocene ( ca 3 Myr ago) was a relatively warm period, with increased atmospheric CO 2 relative to pre-industrial. It has therefore been highlighted as a possible palaeo-analogue for the future. However, changed vegetation patterns, orography and smaller ice sheets also influenced the Mid-Pliocene climate. Here, using a general circulation model and ice-sheet model, we determine the relative contribution of vegetation and soils, orography and ice, and CO 2 to the Mid-Pliocene Arctic climate and cryosphere. Compared with pre-industrial, we find that increased Mid-Pliocene CO 2 contributes 35 per cent, lower orography and ice-sheet feedbacks contribute 42 per cent, and vegetation changes contribute 23 per cent of Arctic temperature change. The simulated Mid-Pliocene Greenland ice sheet is substantially smaller than that of modern, mostly due to the higher CO 2 . However, our simulations of future climate change indicate that the same increase in CO 2 is not sufficient to melt the modern ice sheet substantially. We conclude that, although the Mid-Pliocene resembles the future in some respects, care must be taken when interpreting it as an exact analogue due to vegetation and ice-sheet feedbacks. These act to intensify Mid-Pliocene Arctic climate change, and act on a longer time scale than the century scale usually addressed in future climate prediction.
    Print ISSN: 1364-503X
    Electronic ISSN: 1471-2962
    Topics: Mathematics , Physics , Technology
    Published by The Royal Society
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