ALBERT

Description: New 238U–230Th disequilibria data by thermal ionisation mass spectrometry are presented for a comprehensive set of postglacial basaltic lavas from the neovolcanic zones in Iceland. The new data show a striking systematic decrease in 230Th excess towards central Iceland and the presumed centre of the Iceland plume. This finding would appear paradoxical if source composition was the main factor responsible for generating the 238U–230Th disequilibria, because generally main rift lavas erupted proximal to the plume should be generated from a melting column that initiates deeper in the garnet stability field, compared to the marginal rift zones. Preferential crustal interaction in central Iceland, where the crust is thickest, involving either old (〉350 kyr) Icelandic crust or lower crustal melts, may provide a viable explanation for only part of the data variation, namely the moderately low 238U–230Th disequilibria found in the more evolved SE rift lavas. Moreover, there is no variation of 230Th excesses with degree of differentiation (Mg# or ppm Th) overall, or within individual rift systems, to indicate that crustal contamination causes the radial variation in 230Th excess. The 238U–230Th disequilibria variation is therefore ascribed to variable dynamic parameters in the melting regime induced by interaction of the Iceland plume with the rift systems. The higher 230Th excesses in alkalic off-rift lavas (Snæfellsnes Peninsula) (24±3%) compared to the main rift lavas (15±3%) is consistent with more garnet-rich lithologies dominating the bulk melt compositions away from the main rifts and indicates small-scale source heterogeneity beneath Iceland. The data are reconciled within a model in which mantle upwelling rates in the centre of the plume are significantly faster than at the margins, consistent with fluid dynamic predictions for a plume head. The radial variation observed in (230Th/238U) provides independent support that the centre of the Iceland plume is located beneath SE Iceland, as has been proposed from seismic tomographic studies. For a reasonable range of mantle porosities (Φ=0.05–0.2%) we can explain the Iceland data with a dynamic melting model, by relatively fast mantle upwelling rates in the centre (∼5–20 cm/yr), compared to those at the margins (∼1–4 cm/yr). The radial variation is also shown to be consistent with, though not requiring, a model of deep dehydration melting [Ito et al., Earth Planet. Sci. Lett. 165 (1999) 81–96]. In such a scenario, the generation of (moderately) low 238U–230Th disequilibria will be confined to the lowermost part of the melting column, which is characterised by fast upwelling and low porosity. For Φ values down to 0.05% in the lower part of the hydrous melting zone, moderately low 230Th excesses (5–10%) are likely to result, whereas higher 230Th excesses may arise for lower values of Φ.

Description: U-series disequilibria are presented for Holocene samples from the Canary Islands and interpreted with special emphasis on the separate roles of plume vs. lithospheric melting processes. We report Th and U concentrations and (238U)/(232Th), (230Th)/(232Th), (230Th)/(238U) and (234U)/(238U) for 43 samples, most of which are minimally differentiated, along with (226Ra)/(230Th) and (231Pa)/(235U) for a subset of these samples, measured by thermal ionization mass spectrometry (TIMS). Th and U concentrations range between 2 and 20 ppm and 0.5 and 6 ppm, respectively. Initial (230Th)/(238U) ranges from 1.1 to 1.6. (226Ra)/(230Th)o ranges between 0.9 and 1.8 while (231Pa)/(235U)o ranges between 1.0 and 2.0. Our interpretation of results is based on a three-fold division of samples as a function of incompatible element ratio, such as Nb/U. The majority of samples have Nb/U = 47 ± 10, similar to most MORB and OIB. Higher ratios are found exclusively in alkali basalts and tholeiites from the eastern Canary Islands whereas lower ratios are exclusively found in differentiated rocks from the western Canary Islands. Those with ordinary Nb/U ratios are attributed to melting within the slowly ascending HIMU-dominated Canary plume. Higher Nb/U, generally found in more silica rich basalts from the eastern islands, is attributed to lithospheric contamination. Based on their trace element characteristics, two possible contaminants are amphibole veins (± other minerals) crystallized in the mantle from previous plume-derived basanite or re-melted plume-derived intrusive rocks. The high Nb/U signature of these materials is imparted on a melt of the lithosphere created either by the diffusive infiltration of alkalis or by direct reaction between basanites and peridotite. Mixing between plume-derived basanite and lithospheric melt accounts for the U-series systematics of most eastern island magmas including the well-known Timanfaya eruption. Lower Nb/U ratios in differentiated rocks from the western islands are attributed to fractional crystallization of amphibole ± phlogopite ± sphene from basanite during its ascent through the lithosphere. Based on changes in disequilibria, phonolites and tephrites are interpreted to result from rapid differentiation of primitive parents within millennia.